Abstract
New (co)polyimides possessing good thermal and physicomechanical characteristics, high hydrolytic stability, and transparency at the best world level were synthesized. It was shown that, depending on the natures of diamine and dianhydride used in the synthesis, the optical properties of polymers also change. These properties of (co)polyimide films correlate with the ΔE value, which is defined as the difference between the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) energies of the polyimide repeating unit. It was shown that the use of 1,2-dichlorobenzene makes it possible to obtain high-molecular-weight (co)polyimides with a set of enhanced performance characteristics.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
M. I. Bessonov, M. M. Koton, V. V. Kudryavtsev, L. A. Laius, Poliimidy — klass termostoikikh polimerov [Polyimides as a Class of Thermally Stable Polymers], Leningrad, Nauka, 1983, 328 pp. (in Russian).
K. L. Mittal, Polyimides and Other High Temperature Polymers: Synthesis, Characterization and Applications, CRC Press, 2007, 2–4, p. 425.
J. M. Abadie, High Performance Polymers, 2012, p. 244; DOI: https://doi.org/10.5772/2834.
V. Mittal, High Performance Polymers and Engineering Plastics, Scrivener Publishing LLC, 2011, p. 430.
K. S. Levchenko, K. A. Chudov, D. Yu. Demin, G. E. Adamov, N. O. Poroshin, P. S. Shmelin, E. P. Grebennikov, S. N. Chvalun, V. P. Zubova, Russ. Chem. Bull., 2019, 68, 1321.
B. V. Kotov, T. A. Gordina, V. S. Voishchcv, O. V. Kolninov, A. N. Pravednikov, Polym. Sci. USSR, Ser. A, 1977, 614.
US Pat. 201603; Chem. Abstrs., 2016, 43, 19076A1.
K. I. Fukukawa, M. Okazaki, Y. Sakata, T. Urakami, W. Yamashita, S. Tamai, Polymer, 2013, 54, 1053.
M. Hasegawa, M. Fujii, J. Ishii, S. Yamaguchi, E. Takezawa, T. Kagayama, Polymer, 2014, 55, 4693.
D. A. Sapozhnikov, B. A. Bayminov, A. V. Chuchalov, O. N. Zabegaeva, Y. S. Vygodskii, S. L. Semjonov, A. F. Kosolapov, Polymer Sci., Ser. B, 2020, 62, 39.
I. A. Novakov, B. S. Orlinson, N. N. Mamutova, E. N. Savelyev, E. A. Potaenkova, L. A. Pyntya, M. A. Nakhod, Russ. J. Gen. Chem., 2016, 1255.
I. A. Novakov, B. S. Orlinson, N. N. Mamutova, E. N. Savelyev, E. A. Potaenkova, Russ. J. Gen. Chem., 2015, 1602.
I. A. Novakov, B. S. Orlinson, D. V. Zavyalov, V. I. Porkhun, E. N. Savelyev, E. A. Potaenkova, O. V. Vostrikova, M. A. Nakhod, A. V. Kireeva, A. M. Pichugin, Russ. Chem. Bull., 2020, 69, 1096.
J. Y. Park, Polymer, 1995, 207.
S. V. Vinogradova, V. A. Vasnev, Polikondensatsionnye protsessy i polimery [Polycondensation Processes and Polymers], Moscow, Nauka, 2000, 373 pp. (in Russia).
Shinji Ando, Tohru Matsuura, Shigekuni Sasaki, Polymer J., 1997, 69.
I. A. Novakov, B. S. Orlinson, Polimery na osnove proizvodnykh adamantana: sintez, svoistva, napravleniya prakticheskogo ispol’zovaniya [Polymers based on Adamantane Derivatives: Synthesis, Properties, and Practical Applications], Volgograd, Politekhnik, 2005, 93 pp. (in Russian).
Author information
Authors and Affiliations
Corresponding author
Additional information
Dedicated to Academician of the Russian Academy of Sciences V. N. Charushin on the occasion of his 70th birthday.
Published in Russian in Izyestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1141–1148, June, 2021.
The study was carried out using using equipment of the Center for Collective Use “Physicochemical Investigation Methods” of the Volgograd State Technical University.
The study was financially supported by the Russian Foundation for Basic Research (Project No. 19-33-90119-19).
This paper does not contain descriptions of studies on animals or humans.
The authors declare no competing interests.
Rights and permissions
About this article
Cite this article
Novakov, I.A., Orlinson, B.S., Zav’yalov, D.V. et al. Synthesis and properties of new transparent (co)polyimides based on adamantane-containing diamines and aromatic tetracarboxylic dianhydrides. Russ Chem Bull 70, 1141–1148 (2021). https://doi.org/10.1007/s11172-021-3196-1
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11172-021-3196-1