Abstract
The main objective of the current research work is to explore the effect of nanosilica particles on the compound EPDM/SBR-SiO2 (ethylene-propylene-diene monomer/styrene-butadiene rubber-nanosilica). The composite EPDM/SBR with and without silane coupling agent was processed using an open mill mixer. The nanosilica particles are prepared in the laboratory and were used as the reinforcing material in EPDM/SBR rubber composites. The cure characteristics, mechanical properties, hardness, rebound resilience, swelling resistance, abrasion resistance and compression set of the composites are completely analyzed and studied. Nanosilica particles are produced in the laboratory and used as reinforcement material in EPDM/SBR rubber compounds. Fully analyzed and examined are the cure characteristics, mechanical properties, hardness, rebound resilience, swelling resistance, abrasion resistance and compression collection of the composites. It was also evident from the result that with the inclusion of nanosilica particles in the EPDM/SBR rubber composites, the mechanical properties, swelling resistance, hardness, abrasion resistance and compression set properties improved.
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References
Monfared A, Jalali-Arani A, Mohammadi N (2014) The effect of epoxidized natural rubber and two kinds of organoclay upon molecular interaction, structure and mechanical properties of (styrene–butadiene rubber/acrylonitrile-butadiene rubber/organoclay) nanocomposites. Journal of Macromolecular Science Part B 53(5):918–930
Dubey KA, Bhardwaj YK, Chaudhari CV, Bhattacharya S, Gupta SK, Sabharwal S (2006) Radiation effects on SBR–EPDM blends: a correlation with blend morphology. J Polym Sci B Polym Phys 44(12):1676–1689
Zanchet A, Carli LN, Giovanela M, Brandalise RN, Crespo JS (2012) Use of styrene butadiene rubber industrial waste devulcanized by microwave in rubber composites for automotive application. Mater Des 39:437–443
Muraleedharan Nair T, Kumaran MG, Unnikrishnan G (2004) Mechanical and aging properties of cross-linked ethylene propylene diene rubber / styrene butadiene rubber blends. J Appl Polym Sci 93:2606–2621
Mark JE, Erman B, Roland M (eds) (2013) The science and Technology of Rubber. Academic Press, United States
Senthilvel K, Vishvanathperumal S, Prabu B, John Baruch L (2016) Studies on the morphology, cure characteristics and mechanical properties of acrylonitrile butadiene rubber with hybrid filler (carbon black/silica) composite. Polym Polym Compos 24(7):473–480
Vishvanathperumal S, Gopalakannan S (2016) Reinforcement of ethylene vinyl acetate with carbon black/silica hybrid filler composites. Appl Mech Mater 852:16–22
Cago L (2017) 10 largest Rice producing countries, World Atlas, viewed 16 December 2019, <https://www.worldatlas.com/articles/the-countries-producing-the-most-rice-in-the-world.html/>
Chen XG, Lv SS, Zhang PP, Zhang L, Ye Y (2011) Thermal destruction of rice hull in air and nitrogen. J Therm Anal Calorim 104:1055–1062
Johar N, Ahmad I, Dufresne A (2012) Extraction: preparation and characterization of cellulose fibres and nanocrystals from rice husk. Ind Crop Prod 37:93–99
Vaibhav V, Vijayalakshmi U, Mohana Roopan S (2015) Agricultural waste as a source for the production of silica nanoparticles. Spectrochim Acta A Mol Biomol Spectrosc 139:515–520
Le VH, Thuc CNH, Thuc HH (2013) Synthesis of silica nanoparticles fromVietnamese rice husk by sol–gel method. Nanoscale Res Lett 8:1–10
Ding Y, Su D (2012) Purifying native in-situ mastoid SiO2 from rice husk. Energy Procedia: Part B 16:1269–1274
Ma Y, Zhao X, Zhang H, Wang Z (2011) Comprehensive utilization of the hydrolyzed productions from rice hull. Ind Crop Prod 33:403–408
Vishvanathperumal S, Navaneethakrishnan V, Gopalakannan S (2018) The effect of Nanoclay and hybrid filler on curing characteristics, mechanical properties and swelling resistance of ethylene-vinyl acetate/styrene butadiene rubber blend composite. J Adv Microsc Res 13(4):469–476
Qu L, Yu G, Xie X, Wang L, Li J, Zhao Q (2013) Effect of silane coupling agent on filler and rubber interaction of silica reinforced solution styrene butadiene rubber. Polym Compos 34(10):1575–1582
Li Y, Han B, Wen S, Lu Y, Yang H, Zhang L, Liu L (2014) Effect of the temperature on surface modification of silica and properties of modified silica filled rubber composites. Compos A: Appl Sci Manuf 62:52–59
Gauthier C, Reynaud E, Vassoille R, Stelandre LL (2004) Analysis of the non-linear viscoelastic behaviour of silica filled styrene butadiene rubber. Polymer 45(8):2761–2771
Wolff S (1996) Chemical aspects of rubber reinforcement by fillers. Rubber Chem Technol 69:325–345
Vishvanathperumal S, Gopalakannan S (2019) Effects of the Nanoclay and crosslinking systems on the mechanical properties of ethylene-propylene-diene monomer/styrene butadiene rubber blends Nanocomposite. Silicon 11(1):117–135
Vishvanathperumal S, Gopalakannan S (2017) Swelling properties, compression set behavior and abrasion resistance of ethylene-propylene-diene rubber/styrene butadiene rubber blend nano composites. Polymer Korea 41(3):433–442
Vaibhav V, Vijayalakshmi U, Mohana Roopan S (2015) Agricultural waste as a source for the production of silica nanoparticles. Spectrochimica Acta Part A: Molecularand Biomolecular Spectroscopy 139:515–520
Manoj KC, Kumari P, Rajesh C, Unnikrishnan G (2010) Aromatic liquid transport through filled EPDM/NBR blends. J Polym Res 17:1–9
Sujith A, Unnikrishnan G (2006) Molecular sorption by heterogeneous natural rubber/poly(ethylene-co-vinyl acetate) blend systems. J Polym Res 13:171–180
Thomas PC, Tomlal JE, Selvin TP, Thomas S, Joseph K (2010) High-performance nanocomposites based on acrylonitrile butadiene rubber with fillers of different particle size: mechanical and morphological studies. Polym Compos 31:1515–1524
Flory PJ, Rehner J, 1943. Statistical Mechanics of Cross-Linked Polymer Networks I Rubberlike Elasticity J Chem Phys, 11, 512
Naseri ASZ, Arani AJ (2015) A comparison between the effects of gamma radiation and sulfur cure system on the microstructure and crosslink network of (styrene butadiene rubber/ethylene propylene diene monomer) blends in presence of nanoclay. Radiat Phys Chem 115:68–74
Noriman NZ, Ismail H (2012) Properties of styrene butadiene rubber (SBR)/recycled acrylonitrile butadiene rubber (NBRr) blends: the effects of carbon black/silica (CB/silica) hybrid filler and silane coupling agent, Si69. J Appl Polym Sci 124:19–27
Zhang C, Tang Z, Guo B, Zhang L (2018) Significantly improved rubber-silica interface via subtly controlling surface chemistry of silica. Compos Sci Technol 156:70–77
Ryu C, Kim SJ, Kim D, Kaang S, Seo G (2016) The effect of surface area of Silicas on their reinforcing performance to styrene-butadiene rubber compounds. Elastomers and Composites 51:128–137
Surya I, Ismail H, Azura AR (2014) The comparison of alkanol amide and silane coupling agent on the properties of silica- filled natural rubber (SMR-L) compounds. Polym Test 40:24–32
Xiao Y, Zhang HZL, Ye X, Han D (2020) Surface modification of silica nanoparticles by a polyoxyethylene sorbitan and silane coupling agent to prepare high-performance rubber composites. Polym Test 81:106195
Peng H, Liu L, Luo Y, Wang X, Jia D (2009) Effect of 3-Propionylthio-1-propyltrimethoxylsilane on structure, mechanical, and dynamic mechanical properties of NR/silica composites. Polym Compos 30:955–961
Dileep P, Narayanankutty SK (2020) Styrenated phenol modified nanosilica for improved thermo-oxidative and mechanical properties of natural rubber. Polym Test In Press
Zhang X, Cui H, Song L, Ren H, Wang R, He A (2018) Elastomer nanocomposites with superior dynamic mechanical properties via trans-1, 4-poly (butadiene-co-isoprene)incorporation. Compos Sci Technol 158:156–163
Kader MA, Bhowmick AK (2003) Thermal ageing, degradation and swelling of acrylate rubber, fluoro rubber and their blends containing poly function alacrylates. Polym Degrad Stab 79:283–295
Alam MM, Mina MF, Akhtar F (2003) Swelling and hydration properties of acrylamide hydrogel in distilled water. Polym-Plast Technol Eng 42:533–542
Gwaily SE, Badawy MM, Hassan HH, Madani M (2003) Influence of thermal ageing on crosslinking density of boron carbide/natural rubber composites. Polym Test 22:3–7
Mostafa A, Kasem AA, Bayoumi MR, El-Sebaie MG (2009) Effect of carbon black loading on the swelling and compression set behavior of SBR and NBR rubber compounds. Mater Des 30:1561–1568
Zhang H, Gao Y, Li F, Zhang Z, Liu Y, Zhao G (2016) Influence of silane coupling agents on vulcanized natural rubber: Dynamic properties and heat buildup. Plast Rubber Compos 45:9–15
Acknowledgments
The author is highly grateful to SA Engineering college, Chennai, India for their kind support in providing the time for research for academic interest. The authors would also like to give appreciation to Dr. Gopalakannan, Professor at Adhiparasakthi Engineering College for his advice and suggestion during preparation of this manuscript.
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1. S. Vishvanathperumal – First Author - Fabricated the samples and conducted the testing as per the ASTM standard and helped in writing the manuscript, both authors read and approved the manuscript.
2. G. Anand – Corresponding Author – Helped in Fabrication of composite samples and conducted the testing as per the ASTM standard and have written the manuscript, both authors read and approved the manuscript.
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Vishvanathperumal, S., Anand, G. Effect of Nanosilica on the Mechanical Properties, Compression Set, Morphology, Abrasion and Swelling Resistance of Sulphur Cured EPDM/SBR Composites. Silicon 14, 3523–3534 (2022). https://doi.org/10.1007/s12633-021-01138-9
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DOI: https://doi.org/10.1007/s12633-021-01138-9