1 Introduction

A solid sphere on an inclined surface rolls down under the action of gravity. A rectangular object however is more likely to slide down. The choice of sliding vs. rolling motion is determined by the shape and weight of the body and the frictional forces at the supporting surface. On the other hand, a liquid drop of a given volume on an inclined surface can attain a variety of shapes. The static shape depends on the equilibrium contact angle, solid surface characteristics including the pinning location, interfacial tension between the substrates, gravity and plate inclination, while a moving drop has to contend in addition, with viscous and inertial stresses [1]. Moreover, the reaction forces and moments provided by the supporting surface are distributed and depend strongly on the shape, see e.g., [2,3]. These differences between a solid and a liquid make the study of the latter complex, but pose an interesting question, viz., whether a liquid drop sitting on an inclined solid surface will roll, slide, or do both.

Understanding the kinematics is not just a curiosity but has practical relevance too. For example, rolling droplets play an important role in self-cleaning devices. As they roll, they pick up and remove dirt as observed on hydrophobic surfaces [4]. Hence it is desirable to know under what situations one can maximize the rolling motion inside the drop.

Motion of a drop on solid surfaces has been investigated theoretically and experimentally and such studies have mostly concentrated on the two limiting cases of complete wetting and zero wetting. In the limit of complete wetting, the lubrication approximation of the Navier–Stokes equation has been widely used to study the dynamics of drops [5]. Drops mostly slide in this case and thus the assumption of parabolic velocity profile of lubrication approximation remain consistent, at least in the leading-order calculations. Sliding drops exhibit interesting instabilities of the receding front and have received much attention theoretically and experimentally (see e.g., [6,7]). In contrast, in case of hydrophobic surfaces, the contact angle approaches 180. Such drops are expected to roll on an inclined surface under the action of gravity [8]. The shape of these droplets as they roll down has been studied in [9]. Scaling arguments in [10] of these rolling drops have been experimentally verified on superhydrophobic surfaces [11]. While these two limits are well studied, intermediate contact angles are studied much less. They are harder to analyse as they do not lend themselves to simplifying approximations. While analytical solutions are practically impossible, numerical solutions pose considerable challenges due to the presence of multiple length scales and the coupling between the evolving field and the interface shape [12]. In this study, the entire spectrum of shapes for two-dimensional drops, for a range of relevant non-dimensional parameters are analysed. A splitting of the motion into sliding, shear and rolling leads to a better understanding of the dynamics.

The competition between the rolling and sliding motions of droplets on hydrophobic surfaces has been investigated experimentally [13,14]. In these studies the effect of surface coating and roughness on the internal fluidity of the droplet was of primary concern. The velocity inside the droplet was obtained by particle image velocimetry, and the contribution to slip vs. to roll was evaluated for an accelerating drop on an inclined surface. Rolling motion is clearly observed in molecular dynamics [15], and lattice Boltzmann simulations [16] on cylindrical drops. However, such studies have concentrated on the total velocity of the droplet and its dependence on the driving force and the contact angle. With a somewhat different goal, we investigate in this study the motion of cylindrical drops of various contact angles on smooth surfaces, where the effect of fluid properties like density and viscosity, and also of slip are evaluated.

The idea of splitting the motion into shear and roll is standard in fluid mechanics. However, the standard splitting does not distinguish global rotation from local rotation of the fluid element. Such distinction is necessary to understand the global dynamics of a drop. So we distinguish between these, in the manner introduced by Kolar [17] in a different context. The splitting of the velocity field in a drop into slip and roll was done recently by Mognetti et al [18], although in a manner different from the method done here. This study is valid for drop sizes smaller than the capillary length, and so large deformations from the circular shape were not under consideration, while the present approach has no such restriction. We show that the shape, and hence the size, is very important in determining the amount of rolling inside the drop.

Movement of the contact line, by slipping or otherwise, is imperative for a moving drop unless the contact angle is exactly 180 [10]. Though the exact mechanism of contact line movement is not understood [19], it is generally believed that the macroscopic behaviour of the drop is independent of the assumptions at the contact line. However, it is clear that even a small amount of global rotation can manifest itself as tank-treading [20] near the contact line, which means that contact line behaviour is not local in nature, and must be consistent with the macroscopic motion. We demonstrate this using the diffuse interface (DI) model. Most earlier studies have concentrated on the rolling motion near the contact line [21,22] while we look at the rolling motion in the bulk of the drop. The association between the two, if any, implies the nonlocal hydrodynamic effects of the contact line movement [12].

In the following, we first look at sessile drops to understand the shapes of drops. We then briefly review the rolling and sliding motions of drops from the literature. Results from the simulations are presented next and then we end our discussion with a summary.

2 Static drops

Our main finding from the following sections is that rolling motion in a drop is dominantly determined by the shape. While inertial and viscous forces play their role in determining the shape, it is illustrative to look at the static drops where a competition between gravity and surface tension decides the shape of the drop.

In a static drop, variation in hydrostatic pressure inside a drop is balanced by a Laplace pressure arising from surface tension by the drop surface adopting a suitable curvature. For a two-dimensional drop, force balance along the vertical (y) direction therefore gives

$$ \frac{\sigma}{R} + y \rho g = \sigma \left[ \frac{\mathrm{d}^{2}y/\mathrm{d}x^{2}}{\left[1+\left(\mathrm{d}y/\mathrm{d}x\right)^{2}\right]^{3/2}}\right], $$
(1)

where x is the horizontal coordinate at which y is the vertical location of the interface. The term in the square bracket on the right-hand side is the inverse of the radius of curvature at y, whereas R is the radius of curvature at y=0 (tip of the drop). ρ,g and σ, respectively stand for density, gravitational constant and surface tension between drop and the surrounding fluid.

As gravity is the deforming force it is often quantified as a Bond number, Bo=A ρ g/σ, the ratio of gravity to surface tension. Here A is the area of the two-dimensional drop. As we vary the equilibrium contact angle (𝜃 e) or Bo the drop shape changes as shown in figure 1. We can define a shape parameter to characterize the shape of the drop which will be used at later sections. The isoperimetric quotient, q, given as

$$ q = \frac{4 \pi \times \text{Area}}{\text{Perimeter}^{2}} $$
(2)

describes the closeness of the geometry to the circle. It is exactly unity for a circle. The larger the deviations from the circle, the smaller and farther away it is from unity.

Figure 1
figure 1

A balance between gravity and surface tension forces determines the shape of sessile drops. Change in the shape and hence the isoperimetric quotient are illustrated for (a) change in the contact angle (for Bo=0.1) and (b) change in Bo (for 𝜃 e=180).

3 The two limits: Rolling and sliding

Before discussing results from our simulation we briefly review the two limits which have been studied in the literature. Unlike other parts of this paper, here we consider fully three-dimensional drops.

3.1 Near-perfect rolling motion of drops

The work of Mahadevan and Pomeau [10] considered a small (drop radius < capillary length) non-wetting drop under the action of a weak gravitational field (Bo≪1). Drops are assumed to be almost spherical. Assuming Huygens motion, i.e., instantaneous rotation of the drop about the point of contact, the dissipation is assumed to have occurred only near the surface. Everywhere else the motion is assumed to be the same as that of a rigid body rotation. The solid body rotation makes sense in the context of small Reynolds (Re) number flows where the energy of dissipation is expected to be minimum. Considering a balance between viscous dissipation in the layers contacting the surface and the rate of decrease of gravitational potential energy (Re is assumed to be small) the steady-state velocity of drops is obtained as

$$ U \sim \frac{\sigma \text{Bo}^{-1/2} \sin{\alpha}}{\mu}, $$
(3)

where α is the plate inclination. This expression suggests that smaller drops move faster. This counterintuitive result is attributed to the fact that even though the driving force increases with increase in size, the dissipation assumed to be over the contact disk increases much more with increase in size. These calculations have been verified in [9,11] where droplet motion on superhydrophobic surfaces has been studied. The rolling motion inside such drops is evident on tracking a tracer particle as illustrated in figure 2.

Figure 2
figure 2

Trajectory of a tracer particle measured in a glycerol drop running down a superhydrophobic surface. The continuous line is a cycloid and the points are data from the experiments (adapted from [11] with permission).

3.2 Sliding motion of drops

On the other hand, sliding motion of the drops is found in the following cases: (i) if the contract angle of the drop is very small so that it forms a thin film on the surface, (ii) very large drops (Bo≫1) on hydrophobic surfaces which form puddles.

In the first case we can estimate the viscous force as η U l/𝜃 where l is the radius of the solid–liquid contact area. Balancing it with gravity and in the limit of small contact angles, we get [9]

$$ U \sim \alpha \frac{\rho g R^{2}}{\eta}\theta_{\mathrm{e}}^{2/3} $$
(4)

suggesting a direct correlation between the driving and the dissipating forces.

In the second case, drops are larger than the capillary length and therefore the puddles have thickness twice that of the capillary length [1]. In this case, the terminal viscosity is again given by a balance between viscous dissipation in the drop and gravity. For small tilting angles (α≪1), we get [9]

$$ U \sim \frac{\sigma}{\eta}\alpha $$
(5)

suggesting that the velocity does not depend on the driving force gravity because the shape or puddle thickness is determined by gravity. As gravity changes, this thickness and hence viscous dissipation also changes making the terminal velocity independent of gravity.

4 Results and discussion

Having seen the two limits under which drops behave differently, it would be interesting to see the contribution of rolling motion in drops where none of these limits can be directly used. A detailed description of such a study can be found in [23]. We return to two-dimensional drops now. Details of theory and simulation methods are explained in Appendix A. Again taking a balance between gravity and viscous dissipation, one may obtain [6,24] the capillary number Ca=η U/σ as

$$ \text{Ca} \sim \text{Bo} - {\Delta}_{\theta}, $$
(6)

where Δ 𝜃 = cos𝜃 r − cos𝜃 a . This quantity is generally small in our simulations. Figure 3 shows a plot of Ca vs. Bo showing the validity of the above scaling. The small deviations seen are due to inertial effects not accounted for in eq. (6), as well as by the intercept.

Figure 3
figure 3

The linear relationship between Ca and Bo is illustrated for the data given in figure 5. These data consist of different contact angles, plate inclinations, gravity and surface tension values.

Rotational motion of drops on hydrophobic surfaces has been studied earlier using a diffuse interface model [18]. In this work, based on the velocity profile at the centre of the drop, drop velocity was split into a superposition of rotation and sliding. They found that the contribution of rolling is dependent on several parameters in the simulation. In this study we quantify rotation based on the entire area of the drop and show that it is dependent only on the geometry of the shape provided the viscosity and slip length are constant.

The steady-state drop shape and streamline patterns, total and residual vorticity and angular velocity of a drop moving on an inclined surface are illustrated in figure 4 in the centre-of-mass frame of the drop. A description about residual vorticity and the method to calculate it is explained in Appendix B. Vorticity and residual vorticity along various streamlines are also plotted as a function of azimuthal angle providing the vorticity field distribution inside the drop. For a rolling solid body, the residual vorticity plot will have concentric circles. Any deviation from it shows the presence of sliding motion in the drop. Angular velocity based on residual vorticity, v res=r ω res, where r is also plotted as a function of azimuthal angle. At small Bond number, for circular drops the streamlines look almost concentric except near the contact line. As the drop gets elongated due to larger driving force, larger deviations occur. For example, in the illustrated plot, resemblance to solid body rotation is observed only at the centre of the drop. Though deformations in the drop increases the total vorticity inside the drop, this is a result of increase in shear vorticity. Calculating residual vorticity helps to identify the right amount of rotation in such systems.

Figure 4
figure 4

The shape, streamline patterns, vorticity (ω), residual vorticity (ω res) and residual angular velocity (v res) are illustrated for a moving drop in a coordinate frame moving with the centre of mass of the drop. A streamline of a given colour in (a) is shown in the same colour in the three polar plots of (b) ω, (c) ω res and (d) v res. The azimuthal angle, measured from a line parallel to the solid plate, corresponds to that of the streamline, and the radial location at a given polar angle indicates the magnitude of the respective quantities. The magenta lines represent ψ=0.9,0 and −0.9, showing the thick interface. The drop is moving on a surface inclined to the horizontal, and the black dashed line indicates the direction of gravity. The red dashed line is normal to it. For this simulation, Bo=0.38,% R=28.7,η r =10,𝜃 e=152,Re=124, Ca=10−2.

We may calculate the amount of roll, percentage rotation, denoted by % R, based on the total translational velocity U of the drop, as

$$ \%R=U_{\text{rolling}}/U \times 100, $$
(7)

where we define

$$ U_{\text{rolling}} = \frac{\text{Average}(\omega_{\text{res}})}{2} \times \frac{\text{Height of the drop}}{2}. $$
(8)

Here the radius of the drop is taken as half of the height of the drop. It may be helpful to remember that angular velocity of a rolling solid body is half that of the constant vorticity.

An important property that determines the motion of a drop is its geometrical characteristics. Needless to say, the geometry is in turn determined by the volume, the contact angle, the gravitational force and the plate inclination, apart from the viscosity and density ratios. The effect of equilibrium contact angle is intuitive. At small contact angles any contribution of rotation to the total forward velocity is very small. As the equilibrium contact angle increases, the %R also increases. As the tilt of the plate is changed, the component of gravity parallel and perpendicular to the plate changes resulting in a variety of shapes. This has consequence on the amount of rolling in a drop. In general, the normal component of gravity decreases with increase in plate inclination from a horizontal, making the drop more circular. This helps in increasing the rolling motion. The presence of corners and deformed parts of the drop always increase the shear vorticity locally.

The isoperimetric quotient for drops is calculated from all our simulations and shown in figure 5. One may see that the %R increases as q increases to unity. However, interestingly, all data points collapse to a single curve irrespective of the equilibrium contact angle, gravity and plate inclination which determines the shape and the deformation. The viscosity ratio and mobility are kept fixed in these simulations. This universal curve gets shifted on changing the viscosity ratio or mobility in the simulations.

Figure 5
figure 5

%R as a function of isoperimetric quotient is plotted for different sets of simulations. Each symbol represents a particular 𝜃 e. Within each set, α varies from 4 to 176 and Bo ranges from 5×10−3 to 1.5. %R of drops for a wide variation in parameters fall on this curve. An exponential curve fitted through all data points is also shown. This is a universal curve giving %R as a function of shape factor for a given slip length and viscosity ratio. In the inset, the same data are plotted in log–log scale to show the consistency with scaling arguments (see text). Here, the constant, K, is chosen as 10 (adapted from [23] with permission).

This universal curve can be understood from an analysis of kinematics. If the total velocity gradient, ∇u=∇u slip+∇u roll, is denoted as a sum of slip and roll, as that resulting from two types of motion, then \(\nabla u \sim U/ \sqrt {A}\), where \(\sqrt {A}\) is the characteristic size of the drop, A being the area. In order to calculate the deviation of the drop from a circle, let us define two different length measures h and l, normal to, and along the solid plate, respectively. Therefore, the shape factor qA/(h+l)2. As lA/h, we may represent q∼(h 2/A)/(1+h 2/A)2 or \(q=q(h/\sqrt {A})\). An estimate of the shear force, as in [10], is just μ U/h because motion is mainly parallel to the plate. Thus, ∇u slipO(U/h). Now ∇u roll is the effective angular velocity of the drop. Then multiplying eq. (7) throughout by \(\sqrt {A}/U\) gives % R∼function(q)−K, where K is a constant resulting from exact evaluation of the above estimates. This suggests that %R is only a function of shape and this functional dependence can be completely specified in terms of isoperimetric quotient q. In the limit of small q, we can write \(\sqrt {q} \sim h/\sqrt {A}\) which gives \(\%R \sim \sqrt {q}\). This is shown in the inset of figure 5. For large q, i.e., when it becomes closer to a circle, the amount of roll increases more rapidly than a square root dependence would predict. It is important to mention that capillary, gravitational or wetting parameters are not used explicitly in determining %R.

One may wonder whether it is possible to predict the isoperimetric quotient of the drops a priori. While it may not be possible to exactly calculate this, a method is provided subsequently to obtain an idea about it. We show in figure 6 that this can be done by analysing the corresponding static drops pinned on inclined surfaces. Minimum energy shapes of static drops can be very different based on the location of pinning [2]. We obtain these shapes with either the front end or the rear end pinned. The isoperimetric quotient of the dynamic drops stays between that of front-pinned and back-pinned drops in most of the cases for small Bond numbers. Such predictions are not correct as Bo increases and one may have carry out a full calculation of the shape to understand the dynamics of moving drops.

Figure 6
figure 6

Isoperimetric quotient of static shapes compared with dynamic drops for the same Bond numbers. The equilibrium contact angle is 90 and three different plate inclinations, 30,90 and 135, are chosen for comparison. In the figure, FP stands for front-pinned, RP stands for rear-pinned and D stands for dynamic cases. The shape factor of a dynamic drop lies in between those corresponding to front-pinned and back-pinned static shapes [2]. This behaviour breaks down at large Bond numbers where inertia is higher. In that case, the moving drop is closer to circular than either static shapes.

It must be mentioned that slip at the solid surface helps in the sliding motion of the drop and reduces the amount of roll. Our simulations in which change in mobility or viscosity changes the slip length are consistent with these expectations. The universal curve gets shifted accordingly. At very small slip lengths, very large %R is observed. Similarly, another important factor that may determine the amount of roll is the viscosity of the surrounding medium. Our simulations show that as the ratio of viscosity of the drop to that of the surroundings increases (such as in air–water) the percentage roll also increases considerably. The changes in the vorticity and residual vorticity fields as a response to change in the viscosity ratio are illustrated in figure 7. One may observe that, despite the geometry remaining similar, the %R increases when the viscosity ratio increases.

Figure 7
figure 7

Change in the velocity and vorticity fields when the external fluid viscosity is changed keeping the drop viscosity the same. Here α=30 and 𝜃 e=138. As the external viscosity increases, it start affecting the dynamics more. (a) Bo=0.19, η r =20,% R=22.0,Re=0.3,Ca=0.01, (b) Bo=0.19,η r =1,% R=12.1,Re=0.1,Ca=0.004.

We summarize that the drop shape, expressed in terms of the isoperimetric quotient, uniquely determines the amount of rolling motion in a moving drop on an inclined surface. The amount to roll can be calculated based on residual vorticity in the flow field. Gravity and surface tension parameters do not appear explicitly, as isoperimetric quotient takes care of these competing forces by describing a shape.