Abstract
Nitration of N,N′-bis(trimethylsilyl)carbodiimide with N2O5 or (NO2)2SiF6 afforded N-nitro-N´-(trimethylsilyl)carbodiimide, the first representative of N-nitro carbodiimides. Its further nitration led to the release of CO2, which is presumably formed in the course of N,N´-dinitrocarbodiimide decomposition. The reactions of N-nitro-N´-(trimethylsilyl)carbodiimide with nucleophiles take place both at the tri methylsilyl group (for example, with NH3) to give nitrocyanamide salts and at the carbodiimide C atom (for example, with Et2NH) to give the corresponding nitroguan idines.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 0991—0994, June, 2017.
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Churakov, A.M., Ioffe, S.L., Voronin, A.A. et al. Synthesis of N-nitro-N′-(trimethylsilyl)carbodiimide. Russ Chem Bull 66, 991–994 (2017). https://doi.org/10.1007/s11172-017-1844-2
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DOI: https://doi.org/10.1007/s11172-017-1844-2