Conclusions
The silylation of methylnitramine with B. S. A. or N,N′-diphenyl-N-trimethylsilylurea, or of its Ag salt with silanes of general formula (CH3)2RSiCl, gives a tautomeric mixture of the corresponding O- and N-derivatives of methylnitramine. The amount of the O-derivative in the tautomeric mixture increases with increase both in the temperature and in R: H < CH3 < CH(CH3)2 ≪ C(CH3)3.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 463–465, February, 1974.
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Ioffe, S.L., Makarenkova, L.M. & Tartakovskii, V.A. Silylation of methylnitramine. Russ Chem Bull 23, 433–435 (1974). https://doi.org/10.1007/BF00924709
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DOI: https://doi.org/10.1007/BF00924709