Abstract
The process of condensation of dimethyldiethoxysilane in the active medium in a presence of acetyl chloride, trifluoroacetic acid, and sulfocationites has been investigated. Their impact on the rate and selectivity of the process has been estimated. The prospects of the application of sulfocationites for the polycondensation of dimethyldiethoxysilane in anhydrous acetic acid with an 99% yield have been demonstrated.
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Based on the materials of the XIII Andrianov Conference "Organosilicon Compounds: Synthesis, Properties, and Application" (June 28—July 1, 2015, Moscow).
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 1013—1019, April, 2016.
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Kalinina, A.A., Talalaeva, E.V., Demchenko, A.I. et al. Synthesis of dimethylcyclosiloxanes in the active medium. Russ Chem Bull 65, 1013–1019 (2016). https://doi.org/10.1007/s11172-016-1405-0
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DOI: https://doi.org/10.1007/s11172-016-1405-0