Abstract
A combination of physicochemical methods (dynamic light scattering, nanoparticle tracking analysis, conductometry, tensiometry, and ESR spectroscopy) revealed that dilute solutions (1•10–3, 1.0•10–4, 1.0•10–7, and 1.0•10–9 mol L–1) of surfactant (cetyltrimethylammonium bromide) in a temperature range of 25—45 °C are self-organized dispersed systems. As the temperature increases, the systems undergo rearrangements specific for each studied concentration, which is reflected as nonmonotonic temperature dependences of the parameters of domains (1•10–3 and 1.0•10–4 mol L–1) and nanoassociates (1.0•10–7 and 1.0•10–9 mol L–1) and also as interrelated dependences of the conductivity of solutions with extremes at 30, 37, and 40 °C. The ESR experiments show a nonmonotonic decrease in the rotational diffusion correlation time (τcor) of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) in the temperature dependences of τcor with the temperature increase from 25 to 45 °C and the appearance of two to three plateaus, one of which (in a range of 36—40 °C) is observed in the temperature dependences for all studied concentrations.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
G. N. Zacepina, Physical Properties and Water Structure, Izd. Mos. Univ., Moscow, 1998, 136 pp.
Yu. P. Rassadkin, Voda obyknovennaya i neobyknovennaya [Usual and Unusual Water], Galereya STO, Moscow, 2008, 840 pp. (in Russian).
V. I. Lobyshev, Ros. Khim. Zh., 2007, 51, 107 [Mendeleev Chem. J. (Engl. Transl.), 2007, 51].
R. Roy, W. A. Tiller, I. Bell, M. R. Hoover, Mater. Res. Innovations Online, 2005, 9, 577.
D. Eisenberg, W. Kauzmann, The Structure and Properties of Water, Oxford Univ. Press, New York, 1969.
P. Ball, H 2 O: A Biography of Water, Phoenix Press, London, 2000.
P. Ball, Chem. Rev., 2008, 108, 74.
V. Bardik, V. Gotsulskii, E. Pavlov, N. Malomuzh, D. Nerukh, I. Yanchuk, S. Lavoryk, J. Mol. Liq., 2012, 176, 60.
D. Hagmeyer, J. Ruesing, T. Fenske, H.-W. Klein, C. Schmuck, W. Schrader, M. E. M. da Piedade, M. Epple, RSC Adv., 2012, 2, 4690.
P. Bharmoria, H. Gupta, V. P. Mohandas, P. K. Ghosh, A. Kumar, J. Phys. Chem. B, 2012, 116, 11712.
M. Sedlák, J. Phys. Chem. B, 2006, 110, 4329.
M. Sedlák, J. Phys. Chem. B, 2006, 110, 4339.
M. Sedlák, J. Phys. Chem. B, 2006, 110, 13976.
M. Sedlák, D. Rak, J. Phys. Chem. B, 2013, 117, 2495.
A. I. Konovalov, I. S. Ryzhkina, Russ. Chem. Bull. (Int. Ed.), 2014, 63, 1 [Izv. Akad. Nauk, Ser. Khim., 2014, 1].
K. Holmberg, B. Jonsson, B. Kronberg, B. Lindman, Surfactants and Polymers in Aqueous Solutions, 2nd ed., J. Wiley and Sons, 2003, 545 pp.
S. B. Savvin, R. K. Chernova, S. N. Shtykov, Poverkhnostno-aktivnye veshchestva [Surfactants], Nauka, Moscow, 1991, 251 pp. (in Russian).
V. V. Shkarin, M. Sh. Shafeev, Dezinfektologiya: Rukovodstvo dlya studentov meditsinskikh vuzov i vrachei [Desinfectology: Manual for Students of Medical Higher Educational Institutions and Physicians], Izd-vo Nizhegorod. Gos. Med. Akad., Nizhni Novgorod, 2003, 368 pp. (in Russian).
L. Chalmers, Domestic and Industrial Chemical Specialties, Leonard Hill, London, 1966.
E. F. Gale, E. Cundliffe, P. E. Reynolds, M. H. Richmond, M. Waring, The Molecular Basis of Antibiotic Action, Wiley-Intersci. Publ., J. Wiley and Sons, New York—London, 1972.
A. I. Rusanov, Mitselloobrazovanie v rastvorakh poverkhnostno-aktivnykh veshchestv [Micelle Formation in Solutions of Surfactants], Khimiya, St. Petersburg, 1992, 280 pp. (in Russian).
I. S. Ryzhkina, T. N. Pashirova, Ya. A. Filippova, Zhidkie kristally i ikh prakticheskoe ispol´zovanie [Liquid Crystals and Their Practical Use], 2003, 1, 76 (in Russian).
I. S. Ryzhkina, T. N. Pashirova, Ya. A. Filippova, L. A. Kudryavtseva, A. P. Timosheva, V. P. Arkhipov, Z. Sh. Idiyatullin, E. V. Popova, A. R. Burilov, A. I. Konovalov, Russ. Chem. Bull. (Int. Ed.), 2004, 53, 1520 [Izv. Akad. Nauk, Ser. Khim., 2004, 1462].
E. P. Tishkova, L. A. Kudryavtseva, Russ. Chem. Bull. (Int. Ed.), 1996, 45, 301 [Izv. Akad. Nauk, Ser. Khim., 1996, 298].
V. G. Granik, Russ. Chem. Bull. (Int. Ed.), 2001, 50, 1356 [Izv. Akad. Nauk, Ser. Khim., 2001, 1291].
A. Dasgupta, P.K. Das, J. Phys. Chem. B, 2007, 111, 8502.
A. Lattes, I. Rico-Lattes, E. Perez, V. I. Krutikov, B. Hamada, Bull. Soc. Chim., 2007, 51, 36.
I. S. Ryzhkina, Yu. V. Kiseleva, L. I. Murtazina, Yu. N. Valitova, S. E. Solov´eva, L. M. Pilishkina, A. I. Konovalov, Russ. Chem. Bull. (Int. Ed.), 2010, 59, 1327 [Izv. Akad. Nauk, Ser. Khim., 2010, 1297].
I. S. Ryzhkina, O. A. Mishina, A. P. Timosheva, Yu. V. Kiseleva, A. D. Voloshina, N. V. Kulik, A. I. Konovalov, Dokl. Phys. Chem. (Engl. Transl.), 2014, 459, 166 [Dokl. Akad. Nauk, 2014, 459, 51].
B. V. Deryagin, N. V. Churaev, F. D. Ovcharenko, Voda v dispersnykh sistemakh [Water in Dispersed Systems], Khimiya, Moscow, 1989, 288 pp. (in Russian).
S. M. Melnikov, V. G. Sergeyev, K. Yoshikawa, J. Am. Chem. Soc., 1995, 117, 2401.
ASTM Standard E2834, 2012, Standard Guide for Measurement of Particle Size Distribution of Nanomaterials in Suspension by Nanoparticle Tracking Analysis (NTA), ASTM International, West Conshohocken (PA), 2012, DOI: 10.1520/E2834-12.
L. N. Gall, Physical Principles of Functioning of a Live Organism Matter, Izd. Politech. Univ., St. Petersburg, 2014.
I. V. Lunev, A. A. Khamzin, I. I. Popov, M. N. Ovchinnikov, I. S. Ryzhkina, O. M. Mishina, Yu. V. Kiseleva, A. I. Konovalov, Dokl. Phys. Chem. (Engl. Transl.), 2014, 455, 56 [Dokl. Akad. Nauk, 2014, 455, 656].
I. S. Ryzhkina, Yu. V. Kiseleva, A. P. Timosheva, R. A. Safiullin, M. K. Kadirov, Yu. N. Valitova, A. I. Konovalov, Dokl. Phys. Chem. (Engl. Transl.), 2013, 453, 65 [Dokl. Akad. Nauk, 2012, 447, 56].
A. N. Kuznetsov, Metod spinovogo zonda [Spin Probe Method], Nauka, Moscow, 1976 (in Russian).
A. I. Litvinov, V. I. Morozov, M. K. Kadirov, Vestn. KTU [Bulletin of Kazan Technical University], 2012, 11, 28 (in Russian).
I. S. Ryzhkina, Yu. V. Kiseleva, A. I. Konovalov, Abstr. of 6th Intern. Symp. "Supramolecular Systems in Chemistry and Biology" (Strasbourg, France, September 5—8, 2012), Strasbourg, 106.
Yu. V. Kiseleva, I. S. Ryzhkina, A. I. Konovalov, Abstr. of 8th Annu. Conf. on the Physics, Chemistry and Biology of Water (Borovets, Bulgaria, October 22—25, 2013), Borovets; www.waterconf.org/site/YuliaKiseleva_abstract.pdf.
Author information
Authors and Affiliations
Corresponding author
Additional information
Dedicated to Academician of the Russian Academy of Sciences V. I. Minkin on the occasion of his 80th birthday.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0579—0589, March, 2015.
Rights and permissions
About this article
Cite this article
Ryzhkina, I.S., Kiseleva, Y.V., Mishina, O.A. et al. Self-organization and properties of dilute aqueous solutions of cetyltrimethylammonium bromide in a range of physiologically important temperatures. Russ Chem Bull 64, 579–589 (2015). https://doi.org/10.1007/s11172-015-0903-9
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11172-015-0903-9