Abstract
Activated carbon/CuFe2O4 composite was made using a hydrothermal process. X-ray diffraction (XRD), transmission electron microscopy (TEM), nitrogen adsorption isotherms, vibrating sample magnetometer (VSM), UV–visible diffuse reflectance spectra (DRS), and Fourier transform infrared (FT-IR) spectroscopy were used to characterise the CuFe2O4/AC composites that were synthesised using the previously mentioned method. Each phase’s existence is confirmed by XRD, and TEM revealed the spherically shaped nanoparticles. The Fe–O, Cu–O, and AC vibration modes in the composite are validated by the infrared spectra. Under 60 min of visible light irradiation, the 10%-CuFe2O4/AC composite, which has a bandgap of 2.19 eV and soft-ferromagnetic characteristics, demonstrated strong photocatalytic activity in decomposing MB (50 ppm, 30 mL) up to 99.5%. Through preservation of its high percentage of dye degradation, the 10%-CuFe2O4/AC composite may be used again. The results of the radical trapping experiments indicate that the primary active species involved in the photocatalytic degradation process are superoxide (O2−) and hydroxyl (OH*). Five cycles of the photocatalyst’s recyclability were investigated, and the results showed that the replicated catalysts showed very little rate variations. An effective photocatalyst for the breakdown of wastewater dye is CuFe2O4/AC.
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The data that support the findings of this study are available from the corresponding author, upon reasonable request.
References
S. Asadzadeh-Khaneghah, A. Habibi-Yangjeh, K. Yubuta, Novel g-C3N4 nanosheets/CDs/BiOCl photocatalysts with exceptional activity under visible light. Am. Ceram Soc. 102, 1435–1453 (2019)
Y. Subba Reddy, C. Maria Magdalane, K. Kaviyarasu, Genene Tessema Mola, J. Kennedy, M. Maaza, Equilibrium and kinetic studies of the adsorption of acid blue 9 and Safranin O from aqueous solutions by MgO decked FLG coated Fuller’s earth. J. Phys. Chem. Solids 123(43), 51 (2018)
Mousavi Mitra, Habibi-Yangjeh. Aziz, Shima Rahim Pouran, Review on magnetically separable graphitic carbon nitride-based nanocomposites as promising visible-light driven photocatalysts. J. Mater. Sci. Mater. Electron. 29, 1719–1747 (2018)
Mahsa Pirhashemia, Aziz Habibi-Yangjeha, Shima Rahim Pouranb, Review on the criteria anticipated for the fabrication of highly efficient ZnO-based visible-light driven photocatalysts. J. Ind. Eng. Chem. 62, 1–25 (2018)
D. Chen, K. Wang, T. Ren, H. Dinga, Y. Zhu, Synthesis and characterization of the ZnO/mpg-C3N4 heterojunction photocatalyst with enhanced visible light photoactivity. Dalton Trans. 13, 13105–13114 (2014)
M. Shekofteh-Gohari, A. Habibi-Yangjeh, M. Abitorabi, A. Rouhi, Magnetically separable nanocomposites based on ZnO and their applications in photocatalytic processes: a review. Crit. Rev. Environ. Sci. Technol. 48, 806–857 (2018)
M. Mitra, A. Habibi-Yangjeh, Decoration of Fe3O4 and CoWO4 nanoparticles over graphitic carbon nitride: novel visible-light-responsive photocatalysts with exceptional photocatalytic performances. Mater. Res. Bull. 105, 159 (2018)
C. Maria Magdalane, K. Kaviyarasu, N. Matinise, N. Mayedwa, N. Mongwaketsi, G.T. Letsholathebe Douglas, Naif AbdullahAl-Dhabi. Mola, Mariadhas Valan Arasu, M. Henini, J. Kennedy, M. Maaza, B. Jeyaraj, Evaluation on La2O3 garlanded ceria heterostructured binary metal oxide nanoplates for UV/Visible light induced removal of organic dye from urban wastewater. S. Afr. J. Chem. Eng. 26, 49–60 (2018)
H.-T. Ren, S.-Y. Jia, Wu. Yan, Wu. Song-Hai, XuTian-HeX. ZhangHan, Improved photochemical reactivities of Ag2O/g-C3N4 in phenol degradation under UV and visible light. Ind. Eng. Chem. Res. 53, 17645–17653 (2014)
Shaomang Wanga, Dinglong Lib, Suna Cheng, Shaogui Yang, Guan Yuan, Huan He, Synthesis and characterization of g-C3N4/Ag3VO4 composites with significantly enhanced visible-light photocatalytic activity for triphenylmethane dye degradation. Appl. Catal B 144, 885–892 (2014)
Jinzhu Ma, Caixia Wang, He. Hong, Synthesis and characterization of g-C3N4/Ag3VO4 composites with significantly enhanced visible-light photocatalytic activity for triphenylmethane dye degradation. Appl. Catal B 184, 28–34 (2016)
Li. Liu, Y. Qi, Lu. Jinrong, S. Lin, W. An, Y. Liang, W. Cui, A stable Ag3PO4@g-C3N4 hybrid core@shell composite with enhanced visible light photocatalytic degradation. Appl. Catl. B. 183, 133–141 (2016)
A. Mobeen Amanulla, S.K. Jasmine Shahina, R. Sundaram, C. Maria Magdalane, K. Kaviyarasu, S.B. Letsholathebe Douglas, J. Mohamed, M. Maaza. Kennedy, Antibacterial, magnetic, optical and humidity sensor studies of β-CoMoO4 - Co3O4 nanocomposites and its synthesis and characterization. J. Photochem. Photobiol. B 183, 233–241 (2018)
K. Kombaiah, J. Judith Vijaya, L. John Kennedy, M. Bououdina, K. Kaviyarasu, R. Jothi Ramalingam, Hamad A. Al-Lohedan, Murugan A. Munusamy, A Green approach: synthesis, characterization and opto-magnetic properties of MgxMn1−xFe2O4 spinel nanoparticles. J. Mater. Sci. Mater. Electron. 28, 10321–10329 (2018)
T. Santos Kumar, Bharat Kumar Surender, Arabinda Baruah, Vishnu Shanker, Synthesis of magnetically separable and recyclable g-C3N4−Fe3O4 hybrid nanocomposites with enhanced photocatalytic performance under visible-light irradiation. J. Phy. Che C. 117, 26135–26143 (2013)
R.C. Wu, J.H. Qu, H. He, Removal of azo-dye Acid Red B(ARB) by adsorption and combustion using magnetic CuFe2O4 powder. Appl. Catal. B 48, 49–56 (2004)
Y. Liu, Y. Song, Y. You, Fu. Xiaojing, J. Wen, X. Zheng, NiFe2O4/g-C3N4 heterojunction composite with enhanced visible-light photocatalytic activity. J. Saudi Chem. Soc. 22, 439–448 (2017)
H. Ji, X. Jing, Xu. Yuanguo, Y. Jia, H. Li, Y. Li, L. Huang, Qi. Zhang, Xu. Hui, H. Li, Magnetic g-C3N4/NiFe2O4 hybrids with enhanced photocatalytic activity. RSC Adv. 5, 57960–57967 (2015)
J. Zeng, T. Song, M. Lv, T. Wang, J. Qin, H. Zeng, Plasmonic photocatalysts Au/g-C3N4/NiFe2O4 nanocomposites for enhanced visible-light-driven photocatalytic hydrogen evolution. RSC Adv. 6, 54964–54975 (2016)
Y. Yao, Y. Cai, Lu. Fang, J. Qin, F. Wei, Xu. Chuan, S. Wang, Magnetic ZnFe2O4−C3N4 hybrid for photocatalytic degradation of aqueous organic pollutants by visible light. Ind. Eng. Chem. Res. 53, 17294–17302 (2014)
Yunjin Yao, Wu. Guodong, Lu. Fang, Shaobin Wang, Hu. Yi, Jie Zhang, Wanzheng Huang, Fengyu Wei, Enhanced photo-Fenton-like process over Z-scheme CoFe2O4/g-C3N4 Heterostructures under natural indoor light. Environ. Sci. Pollut. Res. 23(21833), 21845 (2016)
Yunjin Yao, Lu. Fang, Hao Chen, Fengyu Wei Xueting, Chao Lian Liu, Shaobin Wang, Magnetic core-shell CuFe2O4@C3N4 hybrids for visible light photocatalysis of orange II. J. Hazard Mater. 297, 224–233 (2015)
Ao. Ren, C. Liu, Y. Hong, W. Shi, S. Lin, P. Li, Enhanced visible-light-driven photocatalytic activity for antibiotic degradation using magnetic NiFe2O4/Bi2O3 heterostructures. Chem. Eng. J. 258, 301–308 (2014)
X. Pan, Fu. Yongsheng, L. Wang, X. Wang, Multi-walled carbon nanotubes supported nickel ferrite: a magnetically recyclable photocatalyst with high photocatalytic activity on the degradation of phenols. Chem. Eng. J. 195–196, 149–157 (2012)
Y. Toyama, K. Miyake, Y. Shu, K. Moroto, J. Ma, T. Zheng et al., Solvent-free synthesis of Fe/N doped hierarchal porous carbon as an ideal electrocatalyst for oxygen reduction reaction. Mater. Today Energy 17, 100444 (2020)
M.T. Izquierdo, B. Rubio, Carbon-enriched coal fly ash as a precursor of activated carbons for SO2 removal. J. Hazard. Mater. 155, 199–205 (2008)
H. Deng, F. Xu, B. Cheng, J. Yu, W. Ho, Photocatalytic CO2 reduction of C/ZnO nanofibers enhanced by an Ni-NiS cocatalyst. Nanoscale 12, 7206–7213 (2020)
Z. Yao, J. Ma, T.K.A. Hoang, Minhui Shi, Akang Sun, high performance biomass derived catalysts for the oxygen reduction reaction with excellent methanol tolerance. Int. J. Hydrogen Energy 45, 27026–27035 (2020)
A. Phuruangrat, B. Kuntalue, S. Thongtem, T. Thongtem, Synthesis of cubic CuFe2O4 nanoparticles by microwave-hydrothermal method and their magnetic properties. Mater. Lett. 167, 65–68 (2016)
M. Doğan, P. Sabaz, Z. Bi̇ci̇l, B.K. Kizilduman, Y. Turhan, Activated carbon synthesis from tangerine peel and its use in hydrogen storage. J. Energy Inst. 93, 2176–2185 (2020)
M. Jayashree, V. Sharmila, K.L. Meganathan, R. BoopathiRaja, M. Parthibavarman, Mohd Shkir, S. AlFaify, Design and fabrication of graphene anchored CeO2 hybrid nanocomposite electrodes for high performance energy storage device applications. Inorg. Chem. Commun. 132, 108838 (2021)
R. BoopathiRaja, M. Parthibavarman, Hetero-structure arrays of MnCo2O4 nanoflakes@ nanowires grown on Ni foam: design, fabrication and applications in electrochemical energy storage. J. Alloy. Compd. 811, 152084 (2019)
R. BoopathiRaja, M. Parthibavarman, A. Nishara Begum, Hydrothermal induced novel CuCo2O4 electrode for high performance supercapacitor applications. Vacuum. 165, 96–104 (2019)
M. Parthibavarman, M. Karthik, S. Prabhakaran, Role of microwave on structural, morphological, optical and visible light photocatalytic performance of WO3 nanostructures. J. Clus. Sci. 30, 495–506 (2019)
M.M. Vosoughifar, Preparation and application of copper ferrite nanoparticles for degradation of methyl orange. J. Mater. Sci. Mater. Electron. 27, 10449–10453 (2016)
M. Rahimi-Nasrabadi, Mohsen Behpour, Ali Sobhani-Nasab, Mansoureh Rangraz Jeddy, Nanocrystalline Ce-doped copper ferrite: synthesis, characterization, and its photocatalyst application. J. Mater. Sci. Mater. Electron. 27, 11691–11697 (2016)
Hamid Ahmadi, Niloofar Shokrollah, Samane Aghaei, Samira Gharishvandi, Mohammad Moazami Goodarzi, Ayat Mohebifar, Nasibeh Tightiz, Nanocrystalline CuFe2−xSmxO4: synthesis, characterization and its photocatalytic degradation of methyl orange. J. Mater. Sci. Mater. Electron. 27, 4689–4693 (2016)
A. Nasiri, M. Nasiri, S. Nouhi, Shahab Khodadadian Nanocrystalline copper ferrite: synthesis of different shapes through a new method and its photocatalyst application. J. Mater. Sci. Mater. Electron. 28, 2401–2406 (2017)
S. Ruby, D. Rani Rosaline, S.S.R. Inbanathan, K. Anand, G. Kavitha, R. Srinivasan, Ahmad Umar et al., Sunlight-driven photocatalytic degradation of methyl orange based on bismuth ferrite (BiFeO3) heterostructures composed of interconnected nanosheets. J. Nanosci. Nanotechnol. 20, 1851–1858 (2020)
Lu. Chuchu, Z. Bao, C. Qin, L. Dai, A. Zhu, Facile fabrication of heterostructured cubic-CuFe2O4/ZnO nanofibers (c-CFZs) with enhanced visible-light photocatalytic activity and magnetic separation. RSC Adv. 6, 110155–110163 (2016)
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The authors extend their appreciation to the Researchers supporting project number (RSP2024R469), King Saud University, Riyadh, Saudi Arabia.
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Hemalatha, J., Senthil, M., Al-Mohaimeed, A.M. et al. Nanosized CuFe2O4/active carbon composite for efficient photocatalytic degradation towards organic dyes. J Mater Sci: Mater Electron 35, 1626 (2024). https://doi.org/10.1007/s10854-024-13249-1
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DOI: https://doi.org/10.1007/s10854-024-13249-1