Abstract
Studies have claimed that road dust and roadside soil are potential banks of pollutants generally in urban areas. Thus, quantifying the concentrations of metals in an urban area is a prerequisite for assessing pollution and their health effects. Hence, this study reports the concentration of the metals, such as Cd, Co, Cr, Ni, Cu, Pb, Zn, and Fe, in the road dust and the roadside soil of Suva City. A total number of 45 road dust and 36 roadside soil samples were collected at 18 different locations around Suva City with potential traffic influence and analysed. The respective metals concentration in the road dust and roadside soil samples of Suva City were Cd (3.7 and 3.1 mg/kg), Co (35.0 and 33.2 mg/kg), Cr (40.0 and 34.0 mg/kg), Ni (54.3 and 32.4 mg/kg), Cu (172.3 and 265.7 mg/kg), Pb (71.0 and 59.3 mg/kg), Zn (685.0 and 507.0 mg/kg), and Fe (41,010.4 and 39,525.5 mg/kg) and showed the decreasing order as Fe > Zn > Cu > Pb > Ni > Cr > Co > Cd and Fe > Zn > Cu > Pb > Cr > Co > Ni > Cd for road dust and roadside soil, respectively. Furthermore, the mean values of the metals surpassed their background levels, except for Fe, whereas the mean values of Cd, Ni, Cu, and Zn have exceeded their permissible limits in road dust. Similarly, Cd, Cu, and Zn have exceeded their permissible limit in roadside soil except for Ni. The geo-accumulation index (Igeo) assessment of Suva City road dust thus indicated nonpolluted to moderate pollution by Ni and Cu and moderate pollution by Zn. The Igeo assessment of the roadside soil showed moderately polluted by Cu and Zn but no pollution from the remaining studied metals. Overall, the study indicated that the sampling locations at an industrial site of Suva City is highly predominated with almost all of the studied metals and is a concern to the general public who live and work within the vicinity of Walu Bay industrial area.
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In the recent global collective against environmental pollution, road dust and roadside soil have been useful indicators of metals pollution in metropolitan cities and urban areas (Ferreira-Baptista and De-Miguel 2005; Shi et al. 2008; Johansson et al. 2009; Li et al. 2016; Chang et al. 2009; Benhaddya et al. 2016; Eqani et al. 2018). The metals occur naturally in the earth’s crust, but as a result of anthropogenic activities, their natural levels have exceeded over many years of development in cities and urban areas (Malkoc et al. 2010). Furthermore, due to their inorganic nature, the metals are nonbiodegradable, and their accumulation in the environment becomes a significant concern. Even in trace levels, toxicity can be acute or severely detrimental to human health and the environment (Duruibe et al. 2007; Li et al. 2013). Due to their bioaccumulation, the metals pollution brought huge implications to roadside venders who sold goods and even foods and vegetables roadside, which are eventually consumed by people. Thus, the determination and the monitoring of such inorganic substances in the roadside soil and the road dust has become important to ascertain the level of threat posed to the urban dwellers by traffic, industries, and commercial activities. Therefore, the soil and road dust samples have regularly been analysed for different metals that could lead to pollution and affect human health (Li et al. 2016; Benhaddya et al. 2016; Eqani et al. 2018). Some studies and reviews have been reported on the metal pollution in road dust and roadside soil. Results have shown the increasing presence of metals, such as Cd, Cr, Co, Cu, Zn, and Fe in urban areas, except Pb, which has been banned in fuels since the 1970s (Khairy et al. 2011; Addo et al. 2012; Carrero et al. 2013; Wei et al. 2010; Loganathan et al. 2013). Such exponential increase of metal pollution has been coupled strongly with urbanization and industrial activities (Azeez et al. 2013), and Fiji has been no exception (Chandra et al. 2015).
With the world’s ongoing economic race, the development also has been a major focus for Fiji, whereas the consequences need to be controlled for health and environmental protection. Thus, along the roads of the Suva City area, metals pollution may be on the rise through traffic, commercial, and industrial activities, such as food processing, battery, paint manufacturing plants, petroleum gas station, and municipal waste dump, all of which also are located within the Suva City parameter. Due to an unmonitored discharge of wastes and pollutants from these sources over many years, Suva has been studied for metals pollution. Results have confirmed a substantial level of pollution near point sources where elevated concentrations of metals, such as Cu, Pb, Zn, and Fe, were reported in sediments and soils adjacent to major urban dump and near industrial areas in Suva Harbour, Lami dumpsite, and the coastal area (Morrison et al. 2001; Naidu and Morrison 1994; Gangaiya et al. 2001; Maata and Singh 2008; Chandra et al. 2015). Despite these works, there is no published literature found as yet on the metals assessment of the road dust and roadside soil of the Suva City area. Thus, the present work was designed to supplement the literature by addressing this paucity of information by determining the concentrations of Cd, Cr, Co, Cu, Pb, Zn, Ni, and Fe in the road dust and roadside soil along the roadway of Suva City.
Materials and Methods
Study Area
The Republic of Fiji, comprised of 332 islands, has 2 major islands called Viti Levu and Vanua Levu, which comprise a greater land mass and population. The present study focused on Fiji’s capital, Suva City, which is densely populated compared with elsewhere in the country and is located in the southeast of the largest island, Viti Levu (Morrison et al. 2001). The map of Suva City with different sampling sites is shown in Fig. 1 in which 18 sampling sites are designated as: (1) Albert Park; (2) Albert Park (Victoria Parade Rd); (3) Sukuna Park (Stinson Parade Rd); (4) Post Fiji (Edward Street Rd); (5) Suva Market (Usher Street Rd); (6) Suva Port (Harris Rd); (7) Home Maker (Rodwell Rd); (8) Suva Bus stand I; (9) Suva Bus Terminal II; (10) Fiji Foods (Foster Rd); (11) Motibhai (Foster Rd); (12) Walu Bay (Foster Rd); (13) FNU-Samabula (Princess Rd); (14) Nabua Bus Stand (Ratu Mara Rd); (15) Achee Gas Station (Karsanji Street Rd); (16) Sadar (Grantham Rd); (17) USP-Laucala (Laucala Bay Rd); and (18) Flag staff (Rewa Street).
Sampling Strategy
Eighteen sampling sites were selected from the roadways area in potential busy traffic in Suva City where a total number of 45 road dust and 36 roadside soil samples were collected. At each selected site, six samples were collected during fine weather in the month of May 2015. The road dust samples were collected at the roadside in polyethylene bags using a brush and dust pan made of plastic material. The surface layer (5-cm depth) of soil samples were collected by a wooden hand spade into polyethylene bags, 1 meter away at the corresponding location to where road dust samples were collected. At each sampling location, three dust and three soil samples were collected. The distance between each sampling location was kept at 10 meters. From each site, the three samples collected combined a homogenate of one sample for each matrix. For some of the sites, especially in mid-city locations, soil samples were not available within the sampling parameter, and thus only the road dust samples were collected, whereas for other few sites, dust samples were not available.
For the assessment of metals accumulation in road dust and roadside soil, background soil samples also were collected at 20-cm depth and 50–100 meters away from the roadside at remote locations from traffic and other possible influences, such as industry and commerce. At each sampling site, an approximate 0.5 kg each, the roadside soil, and the road dust samples were collected and labelled with the sample number and name of the site. The samples were brought to the laboratory on the same day of collection and transferred to watch glasses for air drying under room temperature. The samples were weighed on a top pan balance on the first day and through consecutive days until their constant mass was obtained.
Reagents
Analytical reagent (AR) grade (HCl and HNO3) were utilized to prepare aqua-regia. Deionized distilled water (DDW) was used to prepare all solutions. AR grade metallic salts (Cr2O3, 3CdSO4·8H2O, CoCl2·6H2O, FeCl3·6H2O, and Pb(NO3)2) were used to prepare 1000 mg/L of standard stock solution of each metal and the pure solid forms of Cu, Ni, and Zn were used to prepare their 1000 mg/L of standard solutions by dissolving in either HCI or HNO3 with distilled water.
Sample Preparation and Quality Control
The road dust or the roadside soil samples (1.0 g) were transferred onto 50-mL conical flasks, and 10 mL of aqua-regia (HCl:HNO3; 3:1) was added to each sample. The samples were then digested on a hot plate for 2 h at 90 °C in a fume cupboard until the evolution of brown fumes ceased, by when, the digest was reduced to an approximate volume of 5 mL or close to dryness. The samples were then allowed to cool under room temperature and filtered through Whatman filter paper of 5C 110-mm diameter (Pore size: 11 µm) into a 50-mL volumetric flask.
For quality-control purposes, Millipore DDW was used to dilute all the sample solutions to the 50-mL mark. A method blank also was prepared and digested simultaneously, using similar procedure. For percentage recovery by the method as part of the quality control, a duplicate of standard reference material (SRM2711a) was prepared and digested at the same time and in the same manner as the samples.
Equipment
The analysis was performed on a Perkin-Elmer AAS 400 flame atomic absorption spectrometry (FAAS). Before analysis, FAAS was calibrated using standard solutions (Fisher Scientific, UK). The results were obtained from Win Lab 32 software with enabled features of setting up standard calibrations, samples, replicates, and other quality-control functions. Also, to assess instrument drift, standards solutions were analysed at an interval of every five samples. Between each sample, DDW was continuously aspirated until blue flame was achieved to avoid carry-over contamination from previous samples.
Pollution Assessment of Metals
The geo-accumulation index (Igeo) method was used for evaluating the pollution status of the environment (Carrero et al. 2013; Benhaddya et al. 2016). Thus, the metals pollution in Suva City was estimated based on the formula: Igeo = log2(Cn/1.5Bn), where Cn is a measured concentration of metal and Bn is the background concentration while 1.5 is a constant (Wei and Yang 2010).
Result and Discussion
Metals in Road Dust and Roadside Soil
The concentrations of the studied metals in the road dust and the roadside soil in Suva City were determined under the standardized method of analysis. As indicated in the quality-control measures, the recovery of the metals in the standard reference material (SRM SRM2711a) was studied; the results were in the range of 86–114%. The elemental composition of the road dust revealed Fe as the most abundant with the mean concentration of 41,010.4 mg/kg, whereas Cd was the least with the mean value of 3.7 mg/kg. Intermediate in this range were Zn, Cu, Pb, Ni, Cr, and Co with their mean concentrations of 685.0, 172.3, 71.0, 54.3, 40.0, and 35.0 mg/kg, respectively. Hence, the metals composition in the road dust was apparently followed a decreasing order as Fe > Zn > Cu > Pb > Ni > Cr > Co > Cd. The background level as well as the acceptable concentration of the metals in soil as recommended by World Health Organisation (WHO) also is presented in Table 1 for comparison. In comparison with their background levels in Table 1, the mean concentrations of Cd, Cr, Ni, Cu, Pb, and Zn are much higher with an exception of Fe, which falls below its background level. In addition, the mean concentrations of the studied metals were higher in the road dust samples compared with the roadside soil samples with the exception of Cu (Table 1).
Table 1 shows the concentration range and the mean values, along with the background levels and the acceptable limits of the studied metals. The mean concentrations in the roadside soil were 3.1, 33.2, 34.0, 32.4, 265.7, 59.3, 507.0, and 39,525.5 mg/kg for Cd, Co, Cr, Ni, Cu, Pb, Zn, and Fe, respectively, and reflected a decreasing trend in concentration as Fe > Zn > Cu > Pb > Cr > Co > Ni > Cd. This relative distribution indicated a very high concentration of Fe compared with the rest of the studied metals, which may be attributed to its high natural abundance in soil, including the anthropogenic contributions from traffic and other sources.
The dissemination behaviour of the metals in the dust and soil often is controlled by natural processes, such as wind, precipitation, erosion, industrial activities, and traffic as the anthropogenic mode (Wei and Yang 2010; Carrero et al. 2013; Li et al. 2016; Duong and Lee 2011). Such high deposit of Cu in the roadside soil may be associated with precipitation, deposition, or geological weathering in soils, but it could be reduced in road dust due to water runoff and wind dispersion as has been reported in the literature by other researchers (Wei et al. 2010; Zhang et al. 2013; Qiao et al. 2014; Chen et al. 2014; Singh 2011).
Metals Distribution Across the Sampling Sites
Figures 2 and 3 show the patterns of individual metal distribution along the Suva City roadways at different study sites denoted by Sn and Dn: where S and D denote the roadside soil and the road dust samples while n denotes the site number. Various studies of the metals in the road dust and the road side soils are presented in Tables 2 and 3, respectively, for comparison and are discussed in the following sections.
Cadmium
While Cd has been the focus of studies in many countries, it has usually been found to prevail at a lower concentration range among the studied metals, often attributed to the natural environment and traffic influences (Malkoc et al. 2010). Figure 2a shows that the highest Cd concentration (6.2 mg/kg) in the roadside soil sample is from the USP-Laucala site (S17) while the lowest (2 mg/kg) is from the site FNU-Samabula (S13). In the same figure, the maximum amount of Cd (12.2 mg/kg) in the road dust was at the Motibhai site (D11), whereas the minimum value (2.4 mg/kg) also was from the FNU-Samabula site (D13) as in the roadside soil sample. Along with the maximum concentrations for Cd in the road dust and roadside soil in the present study, the mean concentrations are higher than the acceptable limit for Cd (3 mg/kg). Such elevated amount of Cd in USP-Laucala area could be attributed to the hillside location where the vehicular emission is high and lots of rocks are present as source of Cd on the sites. A much higher level of Cd in (D11) Motibhai (Foster Rd) is attributed to heavy vehicular activities as well as industrial influence on the sampling site area.
Cobalt
As illustrated in Fig. 2b, the highest level of Co in the roadside soil was from the Suva Port (Harris Rd) site (S6), whereas the lowest was from Suva Bus station I (S8). Figure 2b also demonstrates the maximum concentration in the road dust Co at the Motibhai site (D11), whereas the minimum amount was found at the FNU-Samabula site (D13). The maximum concentration of Co in the D11 sample at Motibhai (Foster Rd) highlights the heavy traffic and industrial influences. With reference to the background value and the acceptable limit for Co in Table 1, results have indicated that the mean and the maximum concentrations for both the road dust and the roadside soil have exceeded their background values, implying anthropogenic influence. However, the maximum and mean values of Co in either matrix have not exceeded the acceptable limit (50 mg/kg), which indicated that Co is still at the safe level in Suva City. The elevated amount of Co in the roadside soil from Harris Rd (Suva Port) could be related to the heavy machineries and vehicle wear from the ports area. The other relatively high concentrations were from S12 and S13, which are from the Walu Bay industrial area and FNU-Samabula, which has heavy vehicle influence.
Chromium
Chromium presents naturally in the soil, but its accumulation in the roadside soil and the road dust could be related to traffic influence, especially from vehicle wears (Al-Khashman 2004a, b; Ferreira-Baptista and De-Miguel 2005). Figure 2c shows that the highest amount of Cr in the roadside soil was from Albert Park (S1) and the lowest from the Suva Port site (S6). According to Fig. 2c, the maximum concentration of Cr in the road dust was from the Motibhai site (D11), and the minimum was at the Achee gas station site (D15). While Cr may present naturally in the soil, its accumulation in the roadside soil could be related to traffic influence, especially from vehicle wears (Al-Khashman 2004a, b; Ferreira-Baptista and De-Miguel 2005). However, the maximum concentration of Cr in the Motibhai (Foster Rd) area could be associated with heavy traffic and industrial activities. Furthermore, despite exceeding the background level, the maximum and mean concentrations of Cr in road dust and roadsides soil are well below the acceptable limit (100 mg/kg) in Table 1.
Nickel
Figure 2d marked the highest concentration of Ni in the roadside soil from the FNU-Samabula site (S13), whereas the lowest concentration was found at Sukuna Park (S3) and the Suva Port site (S6). In a similar distribution as the other metals in road dust samples, the maximum concentration of Ni is at the Motibhai site (D11). However, the minimum value of Ni was from the Achee gas station site (D15), Karshanji street Rd. As mentioned for other metals, a high amount of Ni in the road dust at the Motibhai site (D11) is due to industrial activities and heavy vehicle movement in that particular site. The maximum concentration of Ni in the roadside soil at the FNU-Samabula site (S13) could be attributed to vehicle wears and exhaust emissions from vehicles uphill from vehicles. As shown in Table 1, the range and mean concentrations encountered in the road dust and roadside soil in Suva City are higher than the background values of the study. In addition, the maximum and mean values of Ni in road dust have exceeded the acceptable limit (50 mg/kg), whereas for the roadside soil, its mean value is below the acceptable limit.
Copper
According to Cu distribution over various sites, the roadside soil samples in Fig. 3a showed the highest level of Cu at the Walu Bay slipway site (S12), whereas the lowest concentration of Cu was at the Albert Park site (S1). On the other hand, Cu in the road dust was the highest in Suva Port sample (D6), whereas the lowest is in sample from Motibhai site sample (D11), as shown in Fig. 3a. The highest concentration of Cu at Walu Bay site (S12) signifies the influence of industrial activities as well as dense traffic around the sampling site where the Suva major bus terminal is situated. Thus, due to daily traffic congestion around that area, the Cu level could be accumulated from brake wear of the passing vehicles and the neighbouring influence of the bus station and heavy machineries used in the Suva port area. Compared with its background value, the range and the mean value of the roadside soil in this study have higher concentrations of Cu. Similarly, the road dust also has higher concentrations for the site with the maximum concentration and for its mean value, whereas the site with the least amount of Cu is below its background level (Table 1). Furthermore, all range and mean values of Cu in the road dust and roadside soil have exceeded the acceptable limit (50 mg/kg), indicating a potential threat of metal pollution.
Lead
Having a similar distribution as Cu, Fig. 3b shows the highest level of Pb in the roadside soil samples at Walu Bay site (S12) and the lowest from Albert Park site (S1) sample. As shown in Fig. 3b, for the road dust samples, Pb is the maximum at the Motibhai site (D11) and the minimum at the Suva Market site (D5). The maximum concentrations of Pb in S12 and D11 are due to industrial activities, which engage heavy machineries and vehicles on daily basis. As indicated in Table 1, the maximum and the mean concentration of Pb in the road dust and the roadside soil have exceeded their background level, indicating anthropogenic influence. On the other hand, the mean values are still below the acceptable limit (100 mg/kg), whereas the maximum levels of Pb in the road dust and roadside soil in this study exceeded the acceptable limit, which indicates a threat to those specific sites with higher values.
Zinc
As shown in Fig. 3c, the highest Zn concentration in the roadside soil sample is from the Walu Bay site (S12), and the lowest is from the sample of Suva Port site (S6). For the road dust samples, the maximum concentration of Zn is at the Motibhai site (D11) as seen for other elements, whereas the minimum value for Zn has been observed for Sadar (Grantham Rd) site (D16). Similar to Cu and Pb, the maximum value of Zn in the roadside soil may be associated with heavy vehicular and industrial activities involved in the sampling site. According to the literature, Zn in the road dust and soil is mainly associated with tire wear (Carrero et al. 2013; Thorpe and Harrison 2008; Johansson et al. 2009; Khairy et al. 2011). Thus, the maximum amounts of Zn in the road dust as well as in the roadside soil samples from Motibhai (D11) and Walu Bay (S12) respectively are related to the industrial activities and high intensity of vehicle loads, which cause friction of tires at the rougher texture of roads.
The range and the mean concentrations of Zn in the road dust samples in the present study are above the background level and the acceptable limit of Zn in Table 1. Similarly, for the roadside soil, the maximum and mean value of Zn exceeds its background level and the acceptable limit, which offers a great concern to human health and the environment in Suva City.
Iron
Iron is the one metal whose concentrations at all studied sites has been extremely high (Table 1; Fig. 3d). The highest level of Fe in the roadside soil samples was found at the Albert Park site (S1), whereas the lowest level of Fe was at the Suva Bus station I (S8) (Fig. 3d). In addition, the maximum amount of Fe in the road dust was at the Motibhai site (D11), whereas the lowest was at the FNU-Samabula site (D13). Such elevated amount of Fe in the Albert Park site (S1) may be due to the historic practice of that area, which has been the venue for regular festive activities in Suva involving movement of vehicles, use of machinery, for example ferry wheels in play stations, and construction of temporary stalls and stages, which involve Fe frames. The maximum concentration of Fe in the road dust at Motibhai (Foster Rd) reflects the use of heavy vehicles and machineries in industrial operations on the sampling site (D11).
Fe is naturally abundant in soil, but such high levels of Fe have resulted from anthropogenic activities. As illustrated in Table 1, the mean values of road dust and the roadside soil are below the background level as well as the acceptable limit for Fe. However, its highest values in the road dust and roadside soil have exceeded the acceptable limit of 50,000 mg/kg, which could be a concern to those specific sites within the Suva City environment.
Comparison of Metals Concentration in Road Dust at Global Level
The metals concentration observed in the present study were compared with the literature reported values in urban road dust from the different cities in Asia, Africa, United States, and Europe (Table 2). The most studied metals are Pb, Cu, Zn, Cd, and Ni whose concentration range were 7.2–1131.0, 21.0–350.0, 41.0–1839.0, 0.12–11.20, and 2.9–115.0 mg/kg, respectively in urban road dust (Table 3). The concentrations range of metals determined in the road dust samples of Suva city are: Cd (2.4–12.2 mg/kg), Co (27.1–57.7 mg/kg), Cr (21.1–81.9 mg/kg), Ni (32.1–109.8 mg/kg), Cu (59.3–328.3 mg/kg), Pb (33.6–234.5 mg/kg), Zn (146.2–3262.6 mg/kg), and Fe (26,091.8–104,807.4 mg/kg). Figures 2 and 3 clearly show that the concentrations vary across all sampling sites. Except for Fe, the mean concentrations of the studied metals in the road dust are higher compared with their background concentrations (Table 1). The ratio of the sample/background values has been utilized to evaluate the degree of anthropogenic influence on the natural level of the metals (Chang et al. 2009; Malkoc et al. 2010; Manta et al. 2002; Li et al. 2001; El-Hasan et al. 2006). Therefore, with exception of Fe in the present work, the accumulation of the metals above their background concentrations imply anthropogenic influence, such as traffic, industrial emission, fuel combustion, and the disposal of commercial waste within the Suva City area, which has happened over many years.
Furthermore, the mean concentrations of Cd, Cu, and Zn in the road dust of the Suva City area are higher than their acceptable concentrations in soil (Table 1), which indicate that the Suva City environment is at risk by these metals. Although the mean concentrations have been used to represent the whole Suva City area, there are specific sampling sites where the maximum concentrations of the metals are of greater concern for which the public needs to be aware. As shown in Figs. 2 and 3, the Walu Bay area, i.e., Motibhai site (D11), has the maximum concentrations of Cd, Cr, Ni, Pb, Zn, and Fe, which also have exceeded their acceptable concentrations (Table 1), clearly suggesting that the Walu Bay area in Suva City has been polluted with Cd, Co, Cr, Ni, Pb, Zn, and Fe. Because Walu Bay has been one of the major industrial areas in Suva City, it is expected that associated activities would have contributed to overall mean concentrations of the studied metals in the roadside soil and the road dust.
For global comparison, the mean concentration for Cd in Suva City was relatively similar to a study performed by Meza-Figueroa et al. (2007) in the dust from elementary schools in Hermosillo, Sonora, Mexico (Table 2). The mean concentrations for Cr, Ni, Pb, and Zn in Suva City road dust are higher than the concentrations reported for other places, such as Stockholm, Sweden (Johansson et al. 2009). However, the Fe concentrations reported for most global studies (Apeagyei et al. 2011; Khairy et al. 2011; Chang et al. 2009; Ferreira-Baptista and De-Miguel 2005) are much lower than Fe concentration found in the present study, except the concentration reported in Table 2 by De-Miguel et al. (1997). Moreover, the mean concentrations obtained for all metals in this study are within the global ranges shown in Table 2. The highest amount of Co (57.7 mg/kg) in the road dust sample (D10) was from Moti Bhai (Foster Road) site, which is in the vicinity of the Walu Bay industrial area. Generally, the mean value of Co is comparatively higher in the present study than other studies reported in the literature (Faiz et al. 2009; Ferreira-Baptista and De-Miguel 2005; De-Miguel et al. 1997; Al-Khashman 2004a, b). Besides the evidence of dominance by most metals in the Walu Bay industrial area, the highest concentration of Cu (328.3 mg/kg) is from the Suva Port site (Harris Rd), one of the congested roadways that is adjacent to the Suva Municipal Market and the Suva bus terminal. Because this is a busy traffic area, it holds for such abundance of Cu. Unfortunately, even the mean concentration of Cu has exceeded its background concentration as well as the acceptable limit (Table 1), which makes it a significant pollutant in the Suva environment.
Comparison of Metals Concentration in Roadside Soil at Global Level
The global concentration range of Pb, Cu, Zn, Cd, Cr, Ni, and Co in the roadside soil presented in Table 3 are 5.35–571.30, 0.85–445.60, 4.95–2665.00, 0.15–5.95, 16.8–240.3, 3.15–161.53, and 2.2–14.0 mg/kg, respectively. The global range of Fe is again quite high (22.7–10,344.0 mg/kg); however, literature confirms that road dusts seem to have a higher concentration range of metals compared with the roadside soils (Wei and Yang 2010). Same as in the road dust, the most assessed metals in the roadside soil at a global level are Pb, Cu, Zn, Cd, and Ni, whereas less explored ones are Cr, Fe, and Co. The mean concentrations of the metals from the present study were compared with the global reported values, which confirmed that all are within the global range, except Fe and Co (Table 3). Also, the mean concentrations in the present study are mostly less than or comparable to the acceptable concentrations with the exception of Cu and Zn (Table 1). Compared with the mean distribution of metals in the current study, global studies (Table 4) also have reported the predominance of Fe and the least dominance of Cd in the roadside soil (Tuzen 2003; Christoforidis and Stamatis 2009; Lee et al. 2005; Franco-Uría et al. 2009; Wei and Yang 2010; Celik et al. 2005).
The mean concentrations of Fe in the road dust as well as roadside soil in Suva city area is lower than the background concentration found in this study, whereas those of Cd, Co, Cr, Ni, Pb, and Zn were found to be higher in Suva (Table 1) but were comparable to that reported by Lee et al. (2005), Celik et al. (2005), Acosta et al. (2009), and Tuzen (2003) who analysed for the same metals using relatively similar method. The accumulation of metals above the normal levels in a roadway scenario also has been reported in previous studies across Asia and Europe as highly attributed to traffic wear, tears, and emissions (Dao et al. 2010; Li et al. 2008; Acosta et al. 2009). As one of the major elements in soil, Fe exists in a larger concentration range compared with other metals that are usually regarded as trace metals. Despite the lower mean concentration of Fe in the roadside soil samples compared with its normal value, the maximum Fe concentration in the Albert Park site (S1) exceeded the Suva background level (Table 1). Moreover, the mean concentrations of Cd, Cu, and Zn in the roadside soil also exceeded their acceptable limits (Table 2), which raises concern to the environment of Suva City area.
The maximum concentrations of Cu (847.4 mg/kg), Pb (135.0 mg/kg), and Zn (1617.0 mg/kg) in Suva City roadside soil (Table 1) are from Walu Bay, which is one of the major industrial areas located at the edge of Suva City. These maximum concentrations are absolutely more than the mean values for Cu, Zn, and Pb in several metropolitan cities, such as Hong Kong (Lee et al. 2006), Eskisehir, Turkey (Malkoc et al. 2010), Karak, Jordan (Al-Khashman 2004a), and Galway, Ireland (Dao et al. 2010). Nevertheless, the mean concentrations of Cu, Pb, and Zn in the present study are comparatively less than that of the other studies (Lee et al. 2005; Christoforidis and Stamatis 2009; Celik et al. 2005). Because the maximum values of Cu and Zn are 17 and 5.4 times their acceptable respective limits, the risk to human populace is severe.
The maximum concentrations of Ni (65.5 mg/kg), Co (38.2 mg/kg), and Cd (6.2 mg/kg) in Suva City roadside soils are from the FNU-Samabula site (S13), the Suva Port site (S6), and the USP-Laucala site (S17), respectively. In addition, the mean concentrations of Ni, C, O and Cd in Suva City sites are higher than those reported from Hong Kong (Lee et al. 2006), Palermo, Italy (Manta et al. 2002), and Gilicia, Spain (Franco-Uría et al. 2009). The Suva Port site (S6) sampling location has extremely busy traffic running through its ports area. Hence, high Co concentration may be associated with the influence of traffic plus the heavy-duty machineries at the adjacent port area. Because the sample S13 was collected from a busy road junction FNU-Samabula (Princes Rd) as well as at an elevated site, the high amount of Ni could be linked to brake wear and exhaust emission (Carrero et al. 2013; Thorpe and Harrison 2008; Johansson et al. 2009). A similar scenario existed at the rather steep Laucala Bay Road, the site for S17. Moreover, at these locations (S13 and S17), Ni and Cd were comparatively higher than their acceptable limits, thus suggesting that the FNU-Samabula road intersection and the Laucala Bay road areas are polluted with Ni and Cd.
Statistical Analysis
Principal Component Analysis (PCA)
In many composition analyses, working with a multivariate data is usually complicated. Thus, PCA helps to simplify the dimensions of the multivariate data and provides information on the useful parameters in the whole data set, which can help to isolate and remove insignificant parameters from monitoring stations (Petersen et al. 2001; Singh and Kumar 2017). In the case of roadside soil, two principal components (PCs) obtained explain 58.7% of the total variance of the system where 31.9% and 26.8% of the variance is explained by PC1 and PC2, respectively. Here, the loading for all PCs above ± 0.5 has been considered for explanation. The loading of the PCs of the two components is explained by 58.7% of variance, which has been shown in the Bi-plot (Fig. 4a) and is useful to evaluate the composition and group patterns between the variables, i.e., studied metals. PC1 clearly displayed the dominance of Cd, Cr, Ni, and Zn, which may be associated mainly with traffic emissions and tire and break wear along the road side. The loading of PC2 with Fe, Co, Cu, and Pb with a lesser variance (26.8%) partially indicates some natural influence of Fe from soil along with the other elements (Co, Cu, and Pb) due to traffic and industrial influence.
On the other hand, the PCA study of road dust also comprises two components that explain 85.1% of the total variance in the studied system where 71.3% and 13.8% explains PC1 and PC2, respectively. The loading for all PCs above ± 1 has been considered for explanation in this case. In addition, 85.1% of variance from the two components was displayed in a Bi-plot (Fig. 4b). Thus, PC1 of road dust seemed to be dominated with all the studied metals except Cu. Such strength of variance in PC1 indicates a strong anthropogenic influence which is associated with traffic, commercial, and industrial activities in the studied areas. PC2 loading is only dominated with Cu, which indicates its emergence from an independent dominating source. Therefore, the roadside soil and road dust seems to have a different pattern of PCA distribution of metals in Suva City.
Metals Correlation
The Spearman’s rho (rs) (Spearman 1904) and Kendall’s tau_b (t) (Kendall 1938) correlation coefficient tests were performed to determine the inter-elemental relationship of the studied metals in the roadside soil and the road dust of Suva City. The results are shown in Table 4. The Spearman’s rho correlation coefficient (rs) test results indicated a significant positive correlation between Ni/Cr, Cr/Zn, Zn/Ni, Pb/Zn, and Cr/Fe in the roadside soil of Suva City, whereas the Kendall’s tau_b correlation coefficient (t) test results showed a significant positive correlation between Ni/Cd, Cr/Ni, Co/Ni, Cd/Pb, Co/Pb, Pb/Co, Zn/Cr, Ni/Zn, Zn/Pb, Fe/Co, and Fe/Cr for road dust samples. The observed relationship suggests a common source for almost all the studied metals. However, Cu, which indicated a negative correlation with Cd, Co, and Fe and a weak correlation with the other elements, signifies a strong association to a different source from the other metals. Such correlation behaviour also confirms the findings of the PCA analysis described earlier.
Potential Risk Assessment (Geo-accumulation Index)
The geo-accumulation index (Igeo) for Cd, Co, Cr, Ni, Cu, Pb, Zn, and Fe in the road dust and the roadside soil are given in Table 5. For pollution assessment, the Igeo for each metal has been classified as: nonpolluted (Igeo ≤ 0); nonpolluted to moderately polluted (0 < Igeo ≤ 1); moderately polluted (1 < Igeo ≤ 2); moderately to heavily polluted (2 < Igeo ≤ 3); heavily polluted (3 < Igeo ≤ 4); heavily to extremely polluted (4 < Igeo ≤ 5); extremely polluted (Igeo ≥ 5) (Muller 1969). Based on these classifications, the mean Geoaccumlation index (Igeo) for Cd, Co, Cr, Ni, Pb, and Fe due to the roadside soil (Table 5) were all negative values, which indicated a nonpolluted environment, whereas the mean Igeo for Cu and Zn indicated a moderately polluted environment (Muller 1969).
The road dust samples also showed negative Igeo values for Cd, Co, Cr, Pb, and Fe, which indicated a nonpolluted environment by these metals. Cd exceeded its permissible limit in both matrixes but still has the Igeo values negative, because it only slightly surpasses its background value (Table 1). On the other hand, the Igeo values for Ni and Cu positively correspond to a nonpolluted to moderately polluted environment. Furthermore, the mean Igeo value for Zn (1.66) in the road dust is greater than 1, which showed a moderately polluted environment by Zn. Therefore, based on these pollution assessment results for road dust and the roadside soil, the study confirmed that the Cd, Co, Cr, Pb, and Fe were still at the safe levels compared with Ni, Cu, and Zn whose concentrations were at slightly moderate to moderate levels of pollution, which is of concern to the Suva City environment.
Conclusions
Road dust and roadside soil has been an increasing problem for developed as well as developing countries. The present study has proved that the road dust and roadside soil are good indicators of the metals pollution in the Suva City area. The concentrations of Cd, Co, Cr, Ni, Cu, Pb, Zn, and Fe in road dust and roadside soil were determined by using FAAS, and those commonly associated with traffic influence tend to be quite high. Moreover, the analysis has confirmed that the road dust is the highest contributor of the metals pollution compared with roadside soil. However, both have significantly contributed to the metals pollution in the Suva City environment as confirmed by their Igeo estimation. The metals whose concentrations exceeded allowable limits consequently become a threat to human exposure, ecology, and the environment as a whole and are related to anthropogenic influences, including traffic emissions and industrial activities as the dominating sources, whereas the metals that were below the allowable limit are linked to natural sources. Furthermore, there was significant correlation (95–99% confidence limit) between metals that are normally associated with traffic, industries, and commercial locations. Overall, the Igeo assessment values of the metals in the road dust and the roadside soil of the Suva City environment were nonpolluted to moderately polluted by Cr, Ni, Pb, Cu, and Zn.
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Acknowledgements
The authors are extremely grateful to the Solomon Islands Government for awarding the scholarship to Mr. Wilson Maeaba for his Master of Science (M.Sc.) study. The financial support by the Faculty of Science Technology and Environment (FSTE), The University of the South Pacific (USP) for his thesis project research Grant via Vote Code No. 6C396-1311-a/c-00, and the Research Office, USP for Write up Scholarship also is acknowledged.
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Maeaba, W., Prasad, S. & Chandra, S. First Assessment of Metals Contamination in Road Dust and Roadside Soil of Suva City, Fiji. Arch Environ Contam Toxicol 77, 249–262 (2019). https://doi.org/10.1007/s00244-019-00635-8
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DOI: https://doi.org/10.1007/s00244-019-00635-8