Abstract
Supramolecular hybrid inorganic nanocomposites, as a burgeoning type of hybrid nanomaterials, have been prepared by anchoring macrocyclic organic molecules and supramolecules onto inorganic nanoscaffolds. Macrocyclic organic molecules, such as crown ethers, cryptands, calixarenes, cucurbiturils, pillararene, and cyclodextrins, have frequently been used as building blocks for supramolecular hybrid inorganic materials. These macrocyclic molecules anchoring onto the surface of inorganic nanomaterials particularly act as the valid host molecules that one or more “guest” molecules can bind to a “host” cavity reversibly. Among the various macrocyclic molecules, native and modified cyclodextrins (CDs) have long been recognized as the host molecules with inherent hydrophobic internal cavity and hydrophilic external surface in host-guest chemistry ; therefore, much attention of CDs has attracted in the construction of supramolecular hybrid inorganic nanomaterials.
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Liang, W., Shuang, S. (2019). Cyclodextrin Hybrid Inorganic Nanocomposites for Molecular Recognition, Selective Adsorption, and Drug Delivery. In: Liu, Y., Chen, Y., Zhang, HY. (eds) Handbook of Macrocyclic Supramolecular Assembly . Springer, Singapore. https://doi.org/10.1007/978-981-13-1744-6_17-1
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