Abstract
Generally, organic frameworks are an emerging class of crystalline frameworks with regular porosity and a complex molecular structure with active functional groups. Covalent organic frameworks and metal-organic frameworks are the most popular in framework material chemistry. Due to their fascinating physical and chemical properties, they have been used in a wide range of applications including adsorption, separation, catalysis, membranes, energy storage devices, and pharmaceuticals. The foregoing makes developing nanocomposites based on these organic frameworks with diverse supporting elements such as nanoparticles, graphene, carbon nanotubes, cellulose, and other components more appealing. Among them, cellulose-based nanocarrier materials are more interesting, due to their cost-effectiveness and abundant availability. Therefore, in this chapter, we focus on composites which were made by the combinations of organic frameworks with cellulosic materials. The reasons for developing these kinds of composites are to improve the stability of organic frameworks and reduce cost for wide range of industrial applications. Since, COFs and MOFs are relatively less stable, their crystallinity and molecular structures would be readily lost in harsh conditions as well as expensive. Therefore, the stable supporting materials are required to enhance their stability for a long time to sustain in harsh circumstance while doing different applications. Particularly, in this chapter, we are going to discuss much more about the synthesis of various COF-/MOF-based cellulosic composites and their wide range of applications. Compared with COFs, MOF-based cellulosic composites have been reported more in recent years. Generally, MOFs have effective interactions with cellulose molecules due to their metal coordination and, also, they have shown excellent performance in their applications. Particularly, these classes of composites were used as a membrane for nanofiltration, adsorbent in wastewater treatment, extraction and removal of toxic ions, biomedical and metal applications.
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Acknowledgments
The authors are grateful to the Natural Science Foundation of Hainan Province (2019RC166, 2019RC110 and 2019RC250) and National Natural Science Foundation of China (21965011) for financial support. Dr Vasanthakumar acknowledges the Postdoctoral Funding from Hainan Province, China.
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Arumugam, V., Gao, Y. (2022). Synthesis and Applications of Organic Framework-Based Cellulosic Nanocomposites. In: Barhoum, A. (eds) Handbook of Nanocelluloses. Springer, Cham. https://doi.org/10.1007/978-3-030-89621-8_26
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