Abstract
The work is devoted to study the influence of damaged surface layer on mechanical properties of metal structures. Comparative studies of acoustic anisotropy distributions and dissolved hydrogen concentrations measured according to the vacuum heating method were carried out. The correlation of distributions in rolled steel and aluminum specimens after elasto-plastic and fatigue destruction was revealed. The obtained results indicate the possibility of using the acoustoelasticity method for detecting localized plastic deformations, surface microcracking, and zones with increased concentrations of dissolved hydrogen in metal. It can be used to develop new nondestructive ultrasonic approaches in technical diagnostics of metal structures.
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Keywords
- Acoustic birefringence
- Dissolved hydrogen
- Elasto-plastic deformation
- Nondestructive ultrasonic testing
- Vacuum heating method
3.1 Inroduction
The acoustoelasticity method is an ultrasonic nondestructive testing method used to estimate mechanical stresses in solids [1,2,3,4,5,6,7]. It is based on phenomenon of acoustic birefringence observed in elastically stressed materials with a crystalline structure. This phenomenon is also called the acoustoelastic effect. It consists in splitting elastic shear waves into components \( V_1 \), \( V_2 \) polarized along axes of principal stresses \( \sigma _1\), \(\sigma _2 \) in case of plane stress state. The acoustoelastic effect was theoretically predicted in 1930s and 1940s by Biot [8], Birch [9], Lazarus [10], and others.
The modern technology of acoustoelastic measurements is based on the theory of wave propagation in a nonlinearly elastic stressed medium. It was obtained after the research was carried out by Hughes and Kelly [11], Toupin and Bernstein [12], Truesdell [13], Tokuoka and Saito [14], Iwashimizu and Kubomura [15], Okada [16, 17], Clark [18] and others. Generalization of results obtained for more than fifty years was carried out by Fukuoka in [19, 20].
The essence of results proposed in [11,12,13,14,15,16,17] is contained in relation (3.1) obtained by Hirao and Pao in [21, 22] for a weakly anisotropic material:
where \( \Delta a = (V_1-V_2)/V_0 \) is non-dimensional parameter of total acoustic anisotropy of material, \(\mu \) is the second-order Lame constant, n is the third-order Murnaghan constant [23], \( C_{44} \) and \( C_{55} \) are elastic constants in Voigt’s notation, \( \alpha _1 \) is the experimentally determined constant according to Hirao and Pao [21, 22], \( \sigma _1 \), \( \sigma _2 \) are the principal biaxial stresses, \( \varepsilon ^p_1 \), \( \varepsilon ^p_2 \) are the principal plastic deformations. Nondestructive testing methods based on estimating value of acoustic birefringence widely use the acoustic anisotropy parameter \( \Delta a \).
Classical acoustoelasticity is limited by the use of first two components in relation (3.1). The first component \( \alpha _0 = (C_{55}-C_{44})/2\mu \) is related with intrinsic anisotropy caused by microstructure and anisotropic texture of material. The second component \( ((4\mu +n)/8\mu ^2)(\sigma _1-\sigma _2) \) is related with the acoustoelastic effect in case of an elastically stressed medium. The experimental results of linear acoustoelasticity were obtained by Benson and Raelson [24], Smith [25], Crecraft [26, 27], Hsu [28], Papadakis [29], Blinka and Sachse [30], Egle and Bray [31, 32], Kino [33], King [34], Janssen [35] and others.
Hirao and Pao [21, 22] proposed to expand application of the acoustoelasticity method [24] by including component \( \alpha _1(\varepsilon ^p_1-\varepsilon ^p_2) \) linearly related to plastic deformations (3.1). It was experimentally verified in the case of four-point bending of annealed prismatic beams at plastic deformations of 1% order [21]. The study of small plastic deformations according to relation (3.1) was also carried out in [36].
More than 30 years have passed since the appearance of [21, 22] results. Recent studies indicate a significant influence of damage accumulated during monotonic [37] and cyclic loading [38] on acoustic anisotropy of industrial structures. In addition, influence of hydrogen embrittlement on ultrasonic measurements was found during standard hydrogen-induced corrosion tests (HIC) [39].
At the same time, uneven accumulation of plastic deformation and damage is usually observed. The periodic structure of plastic deformation waves called “chessboard” is observed in polycrystalline materials [40,41,42]. Microcracks localized in a thin surface layer have a significant influence on the degradation of mechanical properties of metal [43, 44]. Therefore, the use of relation (3.1) obtained for specially prepared isotropic specimens may be incorrect for real structures.
The aim of this work is to carry out comparative studies of acoustic anisotropy and high-precision measurements of hydrogen concentrations in rolled specimens from steel and aluminum alloys.
3.2 Experiments
3.2.1 Methods
Three stages of experimental research were carried out. At the first stage, metal specimens cut from rolled sheet were subjected to uniaxial loading. Thus, the Hirao–Pao relationship (3.1) was tested in a wide range of loads and deformations.
At the second stage, ultrasonic measurements were carried out using the Benson–Raelson approach [24] with calculation of total acoustic anisotropy \( \Delta a \) according to relation (3.2):
where denominator \( (V_1+V_2)/2 \) is used instead of shear wave velocity \( V_0 \) for an unstressed isotropic material.
Ultrasonic measurements were carried out using a standard sensor with 5 MHz acoustic signal frequency. Wave packets were emitted and received by 12 \(\times \) 12 mm piezoelectric transducers. The ultrasonic sensor was controlled by an acoustic anisotropy analyzer [5]. This device allowed one to obtain average time delays \( t_1, t_2 \) between multiple reflected pulses. The velocities \( V_1, V_2 \) were obtained after direct micrometric measurement of specimen thickness \( h \). Shear waves were polarized along and perpendicular to direction of uniaxial loading.
At the third stage, hydrogen concentrations were measured by the vacuum heating method [45, 46]. It is based on use of hydrogen diffusion during heating of analyzed metal. The specimen extraction curves contain dependence of extracted hydrogen flux on heating time in vacuum.
Dissolved hydrogen measurements were carried out using high-precision industrial analyzer. Small prismatic specimens with 8 mm-size were tested. The experimental technique for determining hydrogen concentrations is described in [47].
3.2.2 Acoustoelastic Effect in Case of Uniaxial Elasto-Plastic Deformation
The total acoustic anisotropy \( \Delta a \) and velocities of ultrasonic shear waves \( V_1, V_2 \) in the case of uniaxial elasto-plastic tension were investigated. Cold-rolled 500 \(\times \) 70 \(\times \) 15 mm specimens from AMts aluminum alloy were tested. Uniaxial rigid loading was carried out with 5 mm step on INSTRON-8806 hydraulic tensile testing machine.
One of the specimens after destruction and unloading is shown in Fig. 3.1. It was subjected to 19 loading stages. Acoustic measurements were carried out at 10 points located along the specimen axis (in Fig. 3.2). The total axial deformation \( \varepsilon \) up to specimen destruction was equal to 26.70%. The initial distribution of acoustic anisotropy \( \Delta a \) obtained along specimen axis turned out to be close to uniform and was equal to \( a_0 = 0.50 \pm 0.03 \% \).
Measurement points No. 1, 4, 7, and 10 were located at 45, 90, 135- and 180-mm distance from destruction zone. The results of acoustic anisotropy measurements at each loading stage are shown in Fig. 3.3.
3.2.3 Comparative Studies of Acoustic Anisotropy and Hydrogen Concentrations
Comparative studies of acoustic anisotropy distributions \( \Delta a, \% \) and hydrogen concentrations \( CH, \) ppm were carried out at \( n=10 \) points located along specimen axis (see Fig. 3.2). The hydrogen concentrations were investigated including surface layer and inside the aluminum specimen at 2 mm depth from its surface. The obtained results are shown in Figs. 3.4 and 3.5.
Also, studies on rolled COR-TEN steel specimen (in Fig. 3.6) were carried out. The specimen was subjected to 380 kN cyclic load and destroyed after \( n=5 \times 10^6 \) loading cycles (in Fig. 3.7).
Similar studies of acoustic anisotropy \( \Delta a, \% \) and dissolved hydrogen concentrations \( CH, \) ppm were carried out at \( n=10 \) points located along steel specimen axis. The results obtained near fatigue destruction zone are shown in Figs. 3.8 and 3.9.
3.3 Discussion
3.3.1 Nonlinear Dependence of Acoustic Anisotropy During Elasto-Plastic Deformation
Several important conclusions follow from results presented in Fig. 3.3. The contribution of elastic deformations to the value of acoustic anisotropy averaged 0.54%. It is comparable to initial acoustic anisotropy due to influence of anisotropic texture. Thus, the contribution of component \( a_0 \) must be studied during acoustoelastic measurements in cold-rolled structures.
The dependence of acoustic anisotropy is nonlinear with increasing deformations (see Fig. 3.3). All experimental curves have non-monotonic region at deformations equal to \( \varepsilon = 1.42 \div 2.82\% \). It is observed with the beginning of plastic flow process.
Two other non-monotonic regions are observed for points No. 1 and 4 after deformations equal to \( \varepsilon = 19.20\% \). Significant changes in acoustic anisotropy value are related with the specimen surface curvature due to plastic neck formation. Semenov [37, 43] obtained relation (3.3) for a small deviation \( \alpha \) angle from the surface normal. In this case, acoustic anisotropy \( \Delta a \) is calculated as
where \( \lambda , \mu \) are the Lame constants, \( r=4\mu ^2/(H'+3\mu ) \), \(H'\) is inclination angle of stress–strain diagram [37, 43].
The actual dependence of acoustic anisotropy on plastic deformations has a nonlinear nonmonotonic character (see Fig. 3.3) and cannot be described by linear dependence \(\alpha _1(\varepsilon ^p_1-\varepsilon ^p_2)\) from relation (3.1). It differs from previously published results obtained on basis of the Murnaghan’s theory of finite deformations [23]. Alternative mathematical models [37] should be used to describe propagation of shear waves at large plastic deformations of material.
3.3.2 Skin Effect of Acoustic Anisotropy and Hydrogen Concentrations
The formation of metal defects in atmosphere not subject to drying or filling with inert gases is related to an increase in hydrogen concentrations. Hydrogen is an indicator of structural changes in metals such as cracking, loosening, pore formation, and others. It also leads to formation of new defects under external loading.
The diffusion of hydrogen has a great influence on processes of corrosion, cracking, and brittle fracture of metals. The mechanism of hydrogen embrittlement was explained by Gorsky [48]. He found that deformations of crystalline matrix caused by mechanical stresses have an influence on hydrogen diffusion in solids.
Comparative studies of hydrogen concentrations and acoustic anisotropy distributions revealed their correlation both on aluminum (in Figs. 3.4 and 3.5) and steel specimens (in Figs. 3.8 and 3.9). This effect cannot be due to residual stresses or influence of crystal structure. The observed macroscopic distributions significantly exceed the effects related with plastic flow, such as formation of Luders bands or the Portevin-Le Chatelier effect [49]. It is similar to the phenomenon of propagation of plastic flow autowaves discovered by Zuev [50].
At the same time, the qualitative coincidence of ultrasonic and hydrogen results can be due to influence of microcracks leading to material loosening under monotonic or cyclic load. The uniform distribution of hydrogen inside the specimen (in Fig. 3.5) indicates the surface effect of hydrogen accumulation [44]. It also indirectly indicates the surface effect of acoustic anisotropy predicted earlier in [43].
3.4 Conclusions
Experimental studies have revealed nonlinear non-monotonic character of the acoustic anisotropy dependence on elasto-plastic deformations for orthotropic specimens. This effect is related with the beginning of different stages of deformation process. It cannot be described using generally accepted acoustoelasticity relations postulating linear dependence on plastic deformations. Thus, the influence of large plastic deformations on shear wave velocities should be described using alternative models not based on Murnaghan’s theory of finite deformations.
The revealed correlation between acoustic anisotropy distributions and dissolved hydrogen concentrations can be explained only by formation of microcracks systems localized in a thin surface layer of metal. The results of comparative ultrasonic and hydrogen studies indicate the possibility of detecting metal saturation with hydrogen using acoustic anisotropy measurements.
The obtained results allow one to apply the acoustoelasticity method to nondestructive testing of plastic deformations and microcracking of metal structures at any stage of their operation.
References
Mishakin, V.V., Serebryany, V.N.: Application of the acoustoelastic effect in the precise evaluation of the plastic strain value. Acoustics letters. 17(7), 123–128 (1994)
Santos Jr., A.A., Bray, D.E.: Comparison of acoustoelastic methods to evaluate stresses in steel plates and bars. J. Press. Vessel Technol. 124(3), 354–358 (2002). https://doi.org/10.1115/1.1484114
Erofeev, V.I., Zaznobin, V.A., Samokhvalov, R.V.: Determination of mechanical stresses in solids by an acoustic method. Acoust. Phys. 53(5), 546–552 (2007). https://doi.org/10.1134/S1063771007050028
Kobayashi, H., Vanderby, R.: Acoustoelastic analysis of reflected waves in nearly incompressible, hyper-elastic materials: forward and inverse problems. J. Acoust. Soc. Am. 121(62), 879–887 (2007). https://doi.org/10.1121/1.2427112
Kamyshev, A.V., Nikitina, N.E., Smirnov, V.A.: Measurement of the residual stresses in the treads of railway wheels by the acoustoelasticity method. Russ. J. Nondestruct. Test. 46(3), 189–193 (2010). https://doi.org/10.1134/S106183091003006X
Castellano, A., Foti, P., Fraddosio, A., Marzano, S., Paparella, F., Piccioni, M.D.: Monitoring applied and residual stress in materials and structures by non-destructive acoustoelastic techniques. IEEE 1–5 (2016). https://doi.org/10.1109/EESMS.2016.7504830
Ivanova, Y., Partalin, T., Pashkuleva, D.: Acoustic investigations of the steel samples deformation during the tensile. Russ. J. Nondestruct. Test. 53(1), 39–50 (2017). https://doi.org/10.1134/S1061830917010077
Biot, M.A.: XLIII. Non-linear theory of elasticity and the linearized case for a body under initial stress. Philos. Mag. 217(7), 468–489 (1939). https://doi.org/10.1080/14786443908562246
Birch, F., Bancroft, D.: The effect of pressure on the rigidity of rocks. I. J. Geol. 46(1), 59–87 (1938)
Lazarus, D.: The variation of the adiabatic elastic constants of KCl, NaCl, CuZn, Cu, and Al with pressure to 10,000 bars. Phys. Rev. 76(4), 545–553 (1949). https://doi.org/10.1103/PhysRev.76.545
Hughes, D.S., Kelly, J.L.: Second-order elastic deformation of solids. Phys. Rev. 92(5), 1145–1149 (1953). https://doi.org/10.1103/PhysRev.92.1145
Toupin, R.A., Bernstein, B.: Sound waves in deformed perfectly elastic materials. Acoustoelastic effect. J. Acoust. Soc. Am. 33(2), 216–225 (1961). https://doi.org/10.1121/1.1908623
Truesdell, C.: General and exact theory of waves in finite elastic strain. Arch. Ration Mech. Anal. 8(1), 263–296 (1961). https://doi.org/10.1007/BF00277444
Tokuoka, T., Saito, M.: Elastic wave propagations and acoustical birefringence in stressed crystals. J. Acoust. Soc. Am. 45(5), 1241–1246 (1969). https://doi.org/10.1121/1.1911595
Iwashimizu, Y., Kubomura, K.: Stress-induced rotation of polarization directions of elastic waves in slightly anisotropic materials. Int. J. Solids Struct. 9(1), 99–114 (1973). https://doi.org/10.1016/0020-7683(73)90035-8
Okada, K.: Stress-acoustic relations for stress measurement by ultrasonic technique. J. Acoust. Soc. Jpn (e) 1(3), 193–200 (1980). https://doi.org/10.1250/ast.1.193
Okada, K.: Acoustoelastic determination of stress in slightly orthotropic materials. Exp. Mech. 21(12), 461–466 (1981). https://doi.org/10.1007/BF02327418
Clark, A.V., Mignogna, R.B.: A comparison of two theories of acoustoelasticity. Ultrasonics 21(5), 217–225 (1983). https://doi.org/10.1016/0041-624X(83)90045-8
Fukuoka, H., Toda, H., Naka, H.: Nondestructive residual-stress measurement in a wide-flanged rolled beam by acoustoelasticity. Exp. Mech. 23(1), 120–128 (1983). https://doi.org/10.1007/BF02328690
Fukuoka, H.: Ultrasonic Measurement of Residual Stress. Solid mechanics research for quantitative non-destructive evaluation. Springer, Dordrecht, 275–299 (1987). https://doi.org/10.1007/978-94-009-3523-5_17
Hirao, M., Pao, Y.H.: Dependence of acoustoelastic birefringence on plastic strains in a beam. J. Acoust. Soc. Am. 77(5), 1659–1664 (1985). https://doi.org/10.1121/1.391964
Pao, Y.H.: Theory of acoustoelasticity and acoustoplasticity. Solid mechanics research for quantitative non-destructive evaluation. Springer, Dordrecht, 257–273 (1987). https://doi.org/10.1007/978-94-009-3523-5_16
Murnaghan, F.D.: Finite deformations of an elastic solid. Am. J. Math. 59(2), 235–260 (1937). https://doi.org/10.2307/2371405
Benson, R.W., Raelson, V.J.: Acoustoelasticity. Prod. Eng. 30(29), 56–59 (1959)
Smith, R.T.: Stress-induced anisotropy in solids—the acousto-elastic effect. Ultrasonics 1(3), 135–147 (1963). https://doi.org/10.1016/0041-624X(63)90003-9
Crecraft, D.I.: The use of ultrasonics in stress analysis. Strain 1(4), 4–8 (1965). https://doi.org/10.1111/j.1475-1305.1965.tb00064.x
Crecraft, D.I.: The measurement of applied and residual stresses in metals using ultrasonic waves. J. Sound Vib. 5(1), 173–192 (1967). https://doi.org/10.1016/0022-460X(67)90186-1
Hsu, N.N.: Acoustical birefringence and the use of ultrasonic waves for experimental stress analysis. Exp. Mech. 14(5), 169–176 (1974). https://doi.org/10.1007/BF02323061
Papadakis, E.P.: Ultrasonic phase velocity by the pulse-echo-overlap method incorporating diffraction phase corrections. J. Acoust. Soc. Am. 42(5), 1045–1051 (1967). https://doi.org/10.1121/1.1910688
Blinka, J., Sachse, W.: Application of ultrasonic-pulse-spectroscopy measurements to experimental stress analysis. Exp. Mech. 16(12), 448–453 (1976). https://doi.org/10.1007/BF02324101
Egle, D.M., Bray, D.E.: Measurement of acoustoelastic and third-order elastic constants for rail steel. J. Acoust. Soc. Am. 60(3), 741–744 (1976). https://doi.org/10.1121/1.381146
Bray, D.E., Egle, D.M.: Ultrasonic studies of anisotropy in cold-worked layer of used rail. Metal Science 15(11–12), 574–582 (1981). https://doi.org/10.1179/msc.1981.15.11-12.574
Kino, G.S., Hunter, J.B., Johnson, G.C., Selfridge, A.R., Barnett, D.M., Hermann, G., Steele, C.R.: Acoustoelastic imaging of stress fields. J. Appl. Phys. 50(4), 2607–2613 (1979). https://doi.org/10.1063/1.326268
King, R.B., Herrmann, G., Kino, G.S.: Use of stress measurements with ultrasonics for nondestructive evaluation of the J integral. Eng. Fract. Mech. 15(1–2), 77–86 (1981). https://doi.org/10.1016/0013-7944(81)90107-7
Janssen, M.: Evaluation of an applied plane-stress tensor distribution using ultrasonic shear waves. Exp. Mech. 28(3), 226–231 (1988). https://doi.org/10.1007/BF02329015
Kobayashi, M.: Theoretical study of acoustoelastic effects caused by plastic anisotropy growth. Int. J. Plast. 3(1), 1–20 (1987). https://doi.org/10.1016/0749-6419(87)90014-3
Belyaev, A.K., Lobachev, A.M., Modestov, V.S., Pivkov, A.V., Polyanskiy, V.A., Semenov, A.S., Tretyakov, D.A., Shtukin, L.V.: Estimating the plastic strain with the use of acoustic anisotropy. Mech. Solids 51(5), 606–611 (2016). https://doi.org/10.3103/S0025654416050149
Tretyakov, D., Belyaev, A., Polyanskiy, V., Stepanov, A., Yakovlev, Yu.: Correlation of acoustoelasticity with hydrogen saturation during destruction. E3S Web of Conferences. 121, 01016-1 – 01016-5 (2019). https://doi.org/10.1051/e3sconf/201912101016
Tretyakov, D.A., Belyaev, A.K., Galyautdinova, A.R., Polyanskiy, V.A., Strekalovskaya, D.A.: Investigation of the corrosion process and destruction of metals by using Acoustodamage method. E3S Web of Conferences 121, 01017-1 – 01017-4 (2019). https://doi.org/10.1051/e3sconf/201912101017
Panin, V.E.: Foundations of Physical Mesomechanics. Phys. Mesomech. 1(1), 5–22 (1998)
Panin, V.E., Panin, A.V., Moiseenko, D.D.: Physical Mesomechanics of a deformed solid as a multilevel system. II. Chessboard-Like Mesoeffect of the Interface in Heterogeneous Media in External Fields. Phys. Mesomech. 10(1-2), 5–14 (2007). https://doi.org/10.1016/j.physme.2007.06.001
Polyanskiy, V.A., Belyaev, A.K., Grishchenko, A.I., Lobachev, A.M., Modestov, V.S., Pivkov, A.V., Tretyakov, D.A., Shtukin, L.V., Semenov, A.S., Yakovlev, Y.A.: Finite element simulation of chessboard strain localization in view of statistical spreads in polycrystal grain parameters. Phys. Mesomech. 22(3), 188–194 (2019). https://doi.org/10.1134/S1029959919030032
Semenov, A.S., Polyanskiy, V.A., Tretyakov, D.A., Shtukin, L.V.: Effect of surface layer damage on acoustic anisotropy. J. Appl. Mech. Tech. Phys. 59(6), 1136–1144 (2018). https://doi.org/10.1134/S0021894418060202
Polyanskiy, V.A., Belyaev, A.K., Alekseeva, E.L., Polyanskiy, A.M., Tretyakov, D.A., Yakovlev, Y.A.: Phenomenon of skin effect in metals due to hydrogen absorption. Contin. Mech. Thermodyn. 31(6), 1961–1975 (2019). https://doi.org/10.1007/s00161-019-00839-2
Konar, J., Banerjee, N.G.: Vacuum heating hydrogen determination in aluminium and aluminium alloys. ML Techn. J. 16(1–2), 18–19 (1974)
Sayi, Y.S., Ramakumar, K.L., Prasad, R., Yadav, C.S., Shankaran, P.S., Chhapru, G.C., Jain, H.C.: Determination of H2 and D2 content in metals and alloys using hot vacuum extraction. J. Radioanal. Nucl. Chem. 230(1–2), 5–9 (1998). https://doi.org/10.1007/BF02387438
Andronov, D.Y., Arseniev, D.G., Polyanskiy, A.M., Polyanskiy, V.A., Yakovlev, Y.A.: Application of multichannel diffusion model to analysis of hydrogen measurements in solid. Int. J. Hydrog. Energy 42(1), 699–710 (2017). https://doi.org/10.1016/j.ijhydene.2016.10.126
Gorsky, W.S.: Theorie der ordnungsprozesse und der diffusion in mischkristallen von CuAu. Sow. Phys. 8, 443–456 (1935)
Le Chatelier, A.: Influence du temps et de latemperature sur les essais au choc. Rev. Met. Paris 6(8), 914–917 (1909). https://doi.org/10.1051/metal/190906080914
Zuev, L.B., Danilov, V.I., Gorbatenko, V.V.: Autowaves of localized plastic deformation. Techn. Phys. 40(5), 456–462 (1995)
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The research is carried out under the financial support by Russian Science Foundation, project 18-19-00413.
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Belyaev, A.K., Galyautdinova, A.R., Polyanskiy, V.A., Tretyakov, D.A. (2021). Skin Effect of Acoustic Anisotropy and Dissolved Hydrogen in Metals. In: Polyanskiy, V.A., Belyaev, A.K. (eds) Advances in Hydrogen Embrittlement Study. Advanced Structured Materials, vol 143. Springer, Cham. https://doi.org/10.1007/978-3-030-66948-5_3
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