Abstract
Metal organic frameworks (MOFs) are considered as very promising candidates to build electrodes for electrochemical energy storage devices such as lithium ion batteries, fuel cells and supercapacitors, due to their diverse structure, adjustable aperture, large specific surface area and abundant active sites. Supercapacitor has been widely investigated in the past decades. Of critical importance in these devices is the electrode active materials, and this application has been intensively studied with the development of novel nanomaterials. In this review we summarize recent reports on MOFs as electrode materials for supercapacitors. Specifically, the synthesis of MOF materials for supercapacitor electrodes and their performance in electrochemical energy storage are discussed. We aim to include supercapacitor electrode materials related to MOFs, such as carbon, metal and composite materials. It is proposed that MOFs play an important role in the development of a new generation of supercapacitor electrode materials. Finally, we discuss the current challenges in the field of supercapacitors, with a view towards how to address these challenges with the future development of MOFs and their derivatives.
摘要
金属有机骨架材料具有结构多样、孔径可调、比表面积大及化学反应活性位点丰富等优点, 因此有望成为广泛应用于电化学储能 器件的电极材料, 如锂离子电池、燃料电池及超级电容器等. 近十年来金属有机骨架材料及其衍生物材料引起了广泛的研究与应用. 同 时, 金属有机骨架材料及其衍生的纳米材料作为电化学储能器件中的关键电极也受到了广泛的研究. 本文主要综述了近期金属有机骨架 材料及其衍生物在超级电容器中的研究进展, 讨论了金属有机骨架材料制备超级电容器电极材料的方法及其在电化学储能领域体现出的 优异性能及特殊性质, 同时也总结了近期金属有机骨架材料的衍生物如碳材料、金属材料及复合物在超级电容器中的研究进展, 结果说 明金属有机骨架材料在发展新一代超级电容器电极材料领域具有重要的作用. 最后讨论了金属有机骨架材料及其衍生物目前在超级电容 器领域存在的问题以及未来可能的发展方向.
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Ozkan S, Nguyen NT, Hwang I, et al. Highly conducting spaced TiO2 nanotubes enable defined conformal coating with nanocrystalline Nb2O5 and high performance supercapacitor applications. Small, 2017, 13: 1603821
Shi P, Li L, Hua L, et al. Design of amorphous manganese oxide@ multiwalled carbon nanotube fiber for robust solid-state supercapacitor. ACS Nano, 2017, 11: 444–452
Wang S, Liu N, Su J, et al. Highly stretchable and self-healable supercapacitor with reduced graphene oxide based fiber springs. ACS Nano, 2017, 11: 2066–2074
González-Gaitán C, Ruiz-Rosas R, Nishihara H, et al. Successful functionalization of superporous zeolite templated carbon using aminobenzene acids and electrochemical methods. Carbon, 2016, 99: 157–166
Li X, Zhao Y, Bai Y, et al. A non-woven network of porous nitrogen-doping carbon nanofibers as a binder-free electrode for supercapacitors. Electrochim Acta, 2017, 230: 445–453
Dong L, Xu C, Li Y, et al. Flexible electrodes and supercapacitors for wearable energy storage: a review by category. J Mater Chem A, 2016, 4: 4659–4685
Huang C, Zhang J, Young NP, et al. Solid-state supercapacitors with rationally designed heterogeneous electrodes fabricated by large area spray processing for wearable energy storage applications. Sci Rep, 2016, 6: 25684
Wang Y, Shi Z, Huang Y, et al. Supercapacitor devices based on graphene materials. J Phys Chem C, 2009, 113: 13103–13107
Deka BK, Hazarika A, Kim J, et al. Recent development and challenges of multifunctional structural supercapacitors for automotive industries. Int J Energy Res, 2017, 41: 1397–1411
González A, Goikolea E, Barrena JA, et al. Review on supercapacitors: technologies and materials. Renew Sustain Energy Rev, 2016, 58: 1189–1206
Ma W, Chen S, Yang S, et al. Hierarchical MnO2 nanowire/graphene hybrid fibers with excellent electrochemical performance for flexible solid-state supercapacitors. J Power Sources, 2016, 306: 481–488
Wang D, Fang G, Xue T, et al. A melt route for the synthesis of activated carbon derived from carton box for high performance symmetric supercapacitor applications. J Power Sources, 2016, 307: 401–409
Wu S, Zhu Y. Highly densified carbon electrode materials towards practical supercapacitor devices. Sci China Mater, 2017, 60: 25–38
Zheng M, Xiao X, Li L, et al. Hierarchically nanostructured transition metal oxides for supercapacitors. Sci China Mater, 2017
Zhang Y, Zhen Z, Zhang Z, et al. In-situ synthesis of carbon nanotube/graphene composite sponge and its application as compressible supercapacitor electrode. Electrochim Acta, 2015, 157: 134–141
Sahu V, Shekhar S, Sharma RK, et al. Ultrahigh performance supercapacitor from lacey reduced graphene oxide nanoribbons. ACS Appl Mater Interfaces, 2015, 7: 3110–3116
Wang JG, Kang F, Wei B. Engineering of MnO2-based nanocomposites for high-performance supercapacitors. Prog Mater Sci, 2015, 74: 51–124
Li L, Song H, Zhang Q, et al. Effect of compounding process on the structure and electrochemical properties of ordered mesoporous carbon/polyaniline composites as electrodes for supercapacitors. J Power Sources, 2009, 187: 268–274
Liu M, Du Y, Miao YE, et al. Anisotropic conductive films based on highly aligned polyimide fibers containing hybrid materials of graphene nanoribbons and carbon nanotubes. Nanoscale, 2015, 7: 1037–1046
Wang K, Zhang X, Sun X, et al. Conducting polymer hydrogel materials for high-performance flexible solid-state supercapacitors. Sci China Mater, 2016, 59: 412–420
Belin T, Epron F. Characterization methods of carbon nanotubes: a review. Mater Sci Eng-B, 2005, 119: 105–118
He S, Chen W. Application of biomass-derived flexible carbon cloth coated with MnO2 nanosheets in supercapacitors. J Power Sources, 2015, 294: 150–158
Dhawale DS, Kim S, Park DH, et al. Hierarchically ordered porous CoOOH thin-film electrodes for high-performance supercapacitors. ChemElectroChem, 2015, 2: 497–502
Wu Q, Xu Y, Yao Z, et al. Supercapacitors based on flexible graphene/polyaniline nanofiber composite films. ACS Nano, 2010, 4: 1963–1970
Li ZF, Zhang H, Liu Q, et al. Fabrication of high-surface-area graphene/polyaniline nanocomposites and their application in supercapacitors. ACS Appl Mater Interfaces, 2013, 5: 2685–2691
Wang T, Zhang SL, Wang HX. Binary NiCu layered double hydroxide nanosheets for enhanced energy storage performance as supercapacitor electrode. Sci China Mater, 2017, doi: 10.1007/s40843-017-9131-7
Nie Z, Wang Y, Zhang Y, et al. Multi-shelled a-Fe2O3 microspheres for high-rate supercapacitors. Sci China Mater, 2016, 59: 247–253
Wang R, Luo Y, Chen Z, et al. The effect of loading density of nickel-cobalt sulfide arrays on their cyclic stability and rate performance for supercapacitors. Sci China Mater, 2016, 59: 629–638
Tran C, Kalra V. Co-continuous nanoscale assembly of nafionpolyacrylonitrile blends within nanofibers: a facile route to fabrication of porous nanofibers. Soft Matter, 2013, 9: 846–852
Choi KM, Jeong HM, Park JH, et al. Supercapacitors of nanocrystalline metal-organic frameworks. ACS Nano, 2014, 8: 7451–7457
Sun L, Campbell MG, Dinca M. Electrically conductive porous metal-organic frameworks. Angew Chem Int Ed, 2016, 55: 3566–3579
Zhang YZ, Cheng T, Wang Y, et al. A simple approach to boost capacitance: flexible supercapacitors based on manganese oxides@ MOFs via chemically induced in situ self-transformation. Adv Mater, 2016, 28: 5242–5248
Stallinga P. Electronic transport in organic materials: comparison of band theory with percolation/(variable range) hopping theory. Adv Mater, 2011, 23: 3356–3362
Zhang Z, Yoshikawa H, Awaga K. Discovery of a “bipolar charging” mechanism in the solid-state electrochemical process of a flexible metal-organic framework. Chem Mater, 2016, 28: 1298–1303
Wei T, Zhang M, Wu P, et al. POM-based metal-organic framework/reduced graphene oxide nanocomposites with hybrid behavior of battery-supercapacitor for superior lithium storage. Nano Energy, 2017, 34: 205–214
Guan C, Zhao W, Hu Y, et al. Cobalt oxide and N-doped carbon nanosheets derived from a single two-dimensional metal-organic framework precursor and their application in flexible asymmetric supercapacitors. Nanoscale Horiz, 2017, 2: 99–105
Wang H, Gao Q, Hu J. Asymmetric capacitor based on superior porous Ni–Zn–Co oxide/hydroxide and carbon electrodes. J Power Sources, 2010, 195: 3017–3024
Yan X, Li X, Yan Z, et al. Porous carbons prepared by direct carbonization of MOFs for supercapacitors. Appl Surf Sci, 2014, 308: 306–310
Ding B, Wang J, Chang Z, et al. Self-sacrificial template-directed synthesis of metal-organic framework-derived porous carbon for energy-storage devices. ChemElectroChem, 2016, 3: 668–674
Mao ML, Sun LX, Xu F. Metal-organic frameworks/carboxyl graphene derived porous carbon as a promising supercapacitor electrode material. Key Eng Mater, 2017, 727: 756–763
Yi H, Wang H, Jing Y, et al. Asymmetric supercapacitors based on carbon nanotubes@NiO ultrathin nanosheets core-shell composites and MOF-derived porous carbon polyhedrons with super-long cycle life. J Power Sources, 2015, 285: 281–290
Meng JP, Gong Y, Lin Q, et al. Metal-organic frameworks based on rigid ligands as separator membranes in supercapacitor. Dalton Trans, 2015, 44: 5407–5416
Park SS, Hontz ER, Sun L, et al. Cation-dependent intrinsic electrical conductivity in isostructural tetrathiafulvalene-based microporous metal-organic frameworks. J Am Chem Soc, 2015, 137: 1774–1777
Ye G, Gong Y, Keyshar K, et al. 3D reduced graphene oxide coated V2O5 nanoribbon scaffolds for high-capacity supercapacitor electrodes. Part Part Syst Charact, 2015, 32: 817–821
Lee DY, Yoon SJ, Shrestha NK, et al. Unusual energy storage and charge retention in Co-based metal-organic-frameworks. Micropor Mesopor Mater, 2012, 153: 163–165
Kandalkar SG, Dhawale DS, Kim CK, et al. Chemical synthesis of cobalt oxide thin film electrode for supercapacitor application. Synth Met, 2010, 160: 1299–1302
Zhang F, Hao L, Zhang LJ, et al. Solid-state thermolysis preparation of Co3O4 nano/micro superstructures from metal-organic framework for supercapacitors. Int J Electrochem Sci, 2011, 6: 2943–2954
Lee DY, Shinde DV, Kim EK, et al. Supercapacitive property of metal-organic-frameworks with different pore dimensions and morphology. Micropor Mesopor Mater, 2013, 171: 53–57
Miles DO, Jiang D, Burrows AD, et al. Conformal transformation of [Co(bdc)(DMF)] (Co-MOF-71, bdc =1,4-benzenedicarboxylate, DMF=N,N-dimethylformamide) into porous electrochemically active cobalt hydroxide. Electrochem Commun, 2013, 27: 9–13
Yang J, Xiong P, Zheng C, et al. Metal-organic frameworks: a new promising class of materials for a high performance supercapacitor electrode. J Mater Chem A, 2014, 2: 16640–16644
Yan Y, Gu P, Zheng S, et al. Facile synthesis of an accordion-like Ni-MOF superstructure for high-performance flexible supercapacitors. J Mater Chem A, 2016, 4: 19078–19085
Lai F, Huang Y, Miao YE, et al. Controllable preparation of multidimensional hybrid materials of nickel-cobalt layered double hydroxide nanorods/nanosheets on electrospun carbon nanofibers for high-performance supercapacitors. Electrochim Acta, 2015, 174: 456–463
Jiao Y, Pei J, Yan C, et al. Layered nickel metal-organic framework for high performance alkaline battery-supercapacitor hybrid devices. J Mater Chem A, 2016, 4: 13344–13351
Xu J, Yang C, Xue Y, et al. Facile synthesis of novel metal-organic nickel hydroxide nanorods for high performance supercapacitor. Electrochim Acta, 2016, 211: 595–602
Worrall SD, Mann H, Rogers A, et al. Electrochemical deposition of zeolitic imidazolate framework electrode coatings for supercapacitor electrodes. Electrochim Acta, 2016, 197: 228–240
Yang J, Ma Z, Gao W, et al. Layered structural Co-based MOF with conductive network frames as a new supercapacitor electrode. Chem Eur J, 2017, 23: 631–636
Sheberla D, Bachman JC, Elias JS, et al. Conductive MOF electrodes for stable supercapacitors with high areal capacitance. Nat Mater, 2016, 16: 220–224
Pilon L, Wang H, d’Entremont A. Recent advances in continuum modeling of interfacial and transport phenomena in electric double layer capacitors. J Electrochem Soc, 2015, 162: A5158–A5178
Jeon JW, Sharma R, Meduri P, et al. In situ one-step synthesis of hierarchical nitrogen-doped porous carbon for high-performance supercapacitors. ACS Appl Mater Interfaces, 2014, 6: 7214–7222
Hao F, Li L, Zhang X, et al. Synthesis and electrochemical capacitive properties of nitrogen-doped porous carbon micropolyhedra by direct carbonization of zeolitic imidazolate framework-11. Mater Res Bull, 2015, 66: 88–95
Yang Y, Hao S, Zhao H, et al. Hierarchically porous carbons derived from nonporous metal-organic frameworks: synthesis and influence of struts. Electrochim Acta, 2015, 180: 651–657
Yu M, Zhang L, He X, et al. 3D interconnected porous carbons from MOF-5 for supercapacitors. Mater Lett, 2016, 172: 81–84
Xia W, Qiu B, Xia D, et al. Facile preparation of hierarchically porous carbons from metal-organic gels and their application in energy storage. Sci Rep, 2013, 3: 1935
Mahmood A, Zou R, Wang Q, et al. Nanostructured electrode materials derived from metal-organic framework xerogels for high-energy-density asymmetric supercapacitor. ACS Appl Mater Interfaces, 2016, 8: 2148–2157
Tran C, Kalra V. Fabrication of porous carbon nanofibers with adjustable pore sizes as electrodes for supercapacitors. J Power Sources, 2013, 235: 289–296
Liu B, Shioyama H, Jiang H, et al. Metal-organic framework (MOF) as a template for syntheses of nanoporous carbons as electrode materials for supercapacitor. Carbon, 2010, 48: 456–463
Jin S, Deng H, Zhan L, et al. Synthesis of 3D hierarchical porous carbon as electrode material for electric double layer capacitors. New Carbon Mater, 2012, 27: 87–92
Lei Y, Gan M, Ma L, et al. Synthesis of nitrogen-doped porous carbon from zeolitic imidazolate framework-67 and phenolic resin for high performance supercapacitors. Ceram Int, 2017, 43: 6502–6510
Zhang H, Chen Y, Wang W, et al. Hierarchical Mo-decorated Co3O4 nanowire arrays on Ni foam substrates for advanced electrochemical capacitors. J Mater Chem A, 2013, 1: 8593
Guo Y, Yu L, Wang CY, et al. Hierarchical tubular structures composed of Mn-based mixed metal oxide nanoflakes with enhanced electrochemical properties. Adv Funct Mater, 2015, 25: 5184–5189
Liu X, Shi C, Zhai C, et al. Cobalt-based layered metal-organic framework as an ultrahigh capacity supercapacitor electrode material. ACS Appl Mater Interfaces, 2016, 8: 4585–4591
Yuan C, Wu HB, Xie Y, et al. Mixed transition-metal oxides: design, synthesis, and energy-related applications. Angew Chem Int Ed, 2014, 53: 1488–1504
Yin Z, Chen Y, Zhao Y, et al. Hierarchical nanosheet-based Co-MoO4-NiMoO4 nanotubes for applications in asymmetric supercapacitors and the oxygen evolution reaction. J Mater Chem A, 2015, 3: 22750–22758
Xie L, Hu Z, Lv C, et al. CoxNi1-x double hydroxide nanoparticles with ultrahigh specific capacitances as supercapacitor electrode materials. Electrochim Acta, 2012, 78: 205–211
Liang D, Tian Z, Liu J, et al. MoS2 nanosheets decorated with ultrafine Co3O4 nanoparticles for high-performance electrochemical capacitors. Electrochim Acta, 2015, 182: 376–382
Meng F, Fang Z, Li Z, et al. Porous Co3O4 materials prepared by solid-state thermolysis of a novel Co-MOF crystal and their superior energy storage performances for supercapacitors. J Mater Chem A, 2013, 1: 7235–7241
Maiti S, Pramanik A, Mahanty S. Extraordinarily high pseudocapacitance of metal organic framework derived nanostructured cerium oxide. Chem Commun, 2014, 50: 11717–11720
Liu K, You H, Jia G, et al. Coordination-induced formation of one-dimensional nanostructures of europium benzene-1,3,5-tricarboxylate and its solid-state thermal transformation. Cryst Growth Des, 2009, 9: 3519–3524
Chen S, Xue M, Li Y, et al. Rational design and synthesis of Nix Co3-xO4 nanoparticles derived from multivariate MOF-74 for supercapacitors. J Mater Chem A, 2015, 3: 20145–20152
Salunkhe RR, Tang J, Kamachi Y, et al. Asymmetric supercapacitors using 3D nanoporous carbon and cobalt oxide electrodes synthesized from a single metal-organic framework. ACS Nano, 2015, 9: 6288–6296
Liu S, Tong M, Liu G, et al. S,N-containing Co-MOF derived Co9S8@S,N-doped carbon materials as efficient oxygen electrocatalysts and supercapacitor electrode materials. Inorg Chem Front, 2017, 4: 491–498
Wang DW, Li F, Liu M, et al. 3D aperiodic hierarchical porous graphitic carbon material for high-rate electrochemical capacitive energy storage. Angew Chem Int Ed, 2008, 47: 373–376
Wang Q, Jiao L, Du H, et al. Co3S4 hollow nanospheres grown on graphene as advanced electrode materials for supercapacitors. J Mater Chem, 2012, 22: 21387–21391
Wang Q, Jiao L, Du H, et al. Fe3O4 nanoparticles grown on graphene as advanced electrode materials for supercapacitors. J Power Sources, 2014, 245: 101–106
Liu S, Zhao Q, Tong M, et al. Ultrafine nickel-cobalt alloy nanoparticles incorporated into three-dimensional porous graphitic carbon as an electrode material for supercapacitors. J Mater Chem A, 2016, 4: 17080–17086
Wu Y, Liu S, Zhao K, et al. Chemical deposition of MnO2 nanosheets on graphene-carbon nanofiber paper as free-standing and flexible electrode for supercapacitors. Ionics, 2016, 22: 1185–1195
Zhang Z, Li X, Wang C, et al. Polyacrylonitrile and carbon nanofibers with controllable nanoporous structures by electrospinning. Macromol Mater Eng, 2009, 294: 673–678
Teng M, Qiao J, Li F, et al. Electrospun mesoporous carbon nanofibers produced from phenolic resin and their use in the adsorption of large dye molecules. Carbon, 2012, 50: 2877–2886
Zhao M, Wang Y, Ma Q, et al. Ultrathin 2D metal-organic framework nanosheets. Adv Mater, 2015, 27: 7372–7378
Meng W, Chen W, Zhao L, et al. Porous Fe3O4/carbon composite electrode material prepared from metal-organic framework template and effect of temperature on its capacitance. Nano Energy, 2014, 8: 133–140
Salunkhe RR, Kamachi Y, Torad NL, et al. Fabrication of symmetric supercapacitors based on MOF-derived nanoporous carbons. J Mater Chem A, 2014, 2: 19848–19854
Cao F, Zhao M, Yu Y, et al. Synthesis of two-dimensional CoS1.097/nitrogen-doped carbon nanocomposites using metal-organic framework nanosheets as precursors for supercapacitor application. J Am Chem Soc, 2016, 138: 6924–6927
Li GC, Liu PF, Liu R, et al. MOF-derived hierarchical doubleshelled NiO/ZnO hollow spheres for high-performance supercapacitors. Dalton Trans, 2016, 45: 13311–13316
Yang J, Zheng C, Xiong P, et al. Zn-doped Ni-MOF material with a high supercapacitive performance. J Mater Chem A, 2014, 2: 19005–19010
Weng Q, Wang X, Wang X, et al. Supercapacitive energy storage performance of molybdenum disulfide nanosheets wrapped with microporous carbons. J Mater Chem A, 2015, 3: 3097–3102
Wang Z, Jia W, Jiang M, et al. Microwave-assisted synthesis of layer-by-layer ultra-large and thin NiAl-LDH/RGO nanocomposites and their excellent performance as electrodes. Sci China Mater, 2015, 58: 944–952
Mahmood N, Tahir M, Mahmood A, et al. Role of anions on structure and pseudocapacitive performance of metal double hydroxides decorated with nitrogen-doped graphene. Sci China Mater, 2015, 58: 114–125
Li X, Hao C, Tang B, et al. Supercapacitor electrode materials with hierarchically structured pores from carbonization of MWCNTs and ZIF-8 composites. Nanoscale, 2017, 9: 2178–2187
Xu X, Wang M, Liu Y, et al. In situ construction of carbon nanotubes/nitrogen-doped carbon polyhedra hybrids for supercapacitors. Energy Storage Mater, 2016, 5: 132–138
Wen P, Gong P, Sun J, et al. Design and synthesis of Ni-MOF/CNT composites and rGO/carbon nitride composites for an asymmetric supercapacitor with high energy and power density. J Mater Chem A, 2015, 3: 13874–13883
Zhang Y, Lin B, Sun Y, et al. Carbon nanotubes@metal-organic frameworks as Mn-based symmetrical supercapacitor electrodes for enhanced charge storage. RSC Adv, 2015, 5: 58100–58106
Zhang Y, Lin B, Wang J, et al. All-solid-state asymmetric supercapacitors based on ZnO quantum dots/carbon/CNT and porous N-doped carbon/CNT electrodes derived from a single ZIF-8/CNT template. J Mater Chem A, 2016, 4: 10282–10293
Kim D, Kim DW, Hong WG, et al. Graphene/ZIF-8 composites with tunable hierarchical porosity and electrical conductivity. J Mater Chem A, 2016, 4: 7710–7717
Zhou Y, Mao Z, Wang W, et al. In-situ fabrication of graphene oxide hybrid Ni-based metal-organic framework (Ni–MOFs@-GO) with ultrahigh capacitance as electrochemical pseudocapacitor materials. ACS Appl Mater Interfaces, 2016, 8: 28904–28916
Yin D, Huang G, Sun Q, et al. RGO/Co3O4 composites prepared using GO-MOFs as precursor for advanced lithium-ion batteries and supercapacitors electrodes. Electrochim Acta, 2016, 215: 410–419
Wang L, Feng X, Ren L, et al. Flexible solid-state supercapacitor based on a metal-organic framework interwoven by electrochemically-deposited PANI. J Am Chem Soc, 2015, 137: 4920–4923
Lu C, Ben T, Xu S, et al. Electrochemical synthesis of a microporous conductive polymer based on a metal-organic framework thin film. Angew Chem Int Ed, 2014, 53: 6454–6458
Guo SN, Zhu Y, Yan YY, et al. (Metal-organic framework)-polyaniline sandwich structure composites as novel hybrid electrode materials for high-performance supercapacitor. J Power Sources, 2016, 316: 176–182
Guo B, Yang Y, Hu Z, et al. Redox-active organic molecules functionalized nitrogen-doped porous carbon derived from metal-organic framework as electrode materials for supercapacitor. Electrochim Acta, 2017, 223: 74–84
Maiti S, Pramanik A, Mahanty S. Influence of imidazolium-based ionic liquid electrolytes on the performance of nano-structured MnO2 hollow spheres as electrochemical supercapacitor. RSC Adv, 2015, 5: 41617–41626
Jiang Z, Li Z, Qin Z, et al. LDH nanocages synthesized with MOF templates and their high performance as supercapacitors. Nanoscale, 2013, 5: 11770–11775
Srimuk P, Luanwuthi S, Krittayavathananon A, et al. Solid-type supercapacitor of reduced graphene oxide-metal organic framework composite coated on carbon fiber paper. Electrochim Acta, 2015, 157: 69–77
Fu D, Li H, Zhang XM, et al. Flexible solid-state supercapacitor fabricated by metal-organic framework/graphene oxide hybrid interconnected with PEDOT. Mater Chem Phys, 2016, 179: 166–173
Banerjee PC, Lobo DE, Middag R, et al. Electrochemical capacitance of Ni-doped metal organic framework and reduced graphene oxide composites: more than the sum of its parts. ACS Appl Mater Interfaces, 2015, 7: 3655–3664
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This work was supported by the Fundamental Research Funds for Central Universities’ through Beihang University and the Queensland Government through the Q-CAS Collaborative Science Fund 2016 “Graphene-Based Thin Film Supercapacitors”.
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Yujie Zhao received her Master’s degree from Chongqing University, China, in 2017. Currently, she is a PhD student at Beihang University, China. Her research interest is focused on functional nanomaterials and related energy applications.
Jinzhang Liu received his PhD degree in Condensed Matter Physics from Lanzhou University in 2006. He then continued his academic career in South Korea (2006–2011) and Australia (2011–2015). Currently, he is an associated professor at the School of Materials Science and Engineering of Beihang University. His research interests include the synthesis of carbon materials and their applications in supercapacitors and solar-powered desalination.
Yan Li is a professor of the School of Materials Science and Engineering of Beihang University. He received his PhD degree form Dalian University of Technology in 2001. His current research interests include shape memory materials, biomedical materials, supercapacitors and battery materials.
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Zhao, Y., Liu, J., Horn, M. et al. Recent advancements in metal organic framework based electrodes for supercapacitors. Sci. China Mater. 61, 159–184 (2018). https://doi.org/10.1007/s40843-017-9153-x
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DOI: https://doi.org/10.1007/s40843-017-9153-x