Abstract
Li-rich layered oxide cathode materials have drawn great attention due to their high specific capacity and relatively low cost. However, their implementation is hindered by capacity and discharge voltage decay as well as poor rate performance. Herein, by combining the concepts of geometrical and atomic structure design, hollow multishelled structural Li-rich cathode material doped with aluminum element(Li-rich HoMS-Al) is developed to solve the above challenges. Li-rich HoMS-Al is synthesized through a facile sequential templating approach with the shell number, element molar ratio and Al doping amount accurately controlled. HoMS can effectively buffer the stress/strain during cycling, as well as shorten the ion and electron diffusion path, while Al doping can inhibit the phase transition of the material and reduce the surface oxygen precipitation. As a result, it achieved a high specific capacity, stable voltage and capacity during cycling, exhibiting an initial discharge specific capacity up to 300.6 mA·h·g−1 at 0.1 C(1 C=300 mA/g) and maintaining 246.3 mA·h·g−1 after 100 cycles.
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Park G.-T., Namkoong B., Kim S.-B., Liu J., Yoon C. S., Sun Y.-K., Nat Energy, 2022, 7, 946
Yang S., Ai F., Li Z., Zhao G., Bi Y., Chem. Res. Chinese Universities, 2021, 38(2), 603
Bi Y. J., Tao J., Wu Y., Li L., Xu Y., Hu E., Wu B., Hu J., Wang C., Zhang J.-G., Qi Y., Xiao J., Science, 2020, 370, 1313
Hou W., Ou Y., Liu K., Chem. Res. Chinese Universities, 2022, 38(3), 735
Chen W., Xia H., Guo K., Jin W., Du Y., Yan W., Qu G., Zhang J., Chem. Res. Chinese Universities, 2022, 38(5), 1232
Yin W., Grimaud A., Rousse G., Abakumov A. M., Senyshyn A., Zhang L., Trabesinger S., Iadecola A., Foix D., Giaume D., Tarascon J M., Nat. Commun., 2020, 11(1), 1252
House R. A., Maitra U., Perez-Osorio M. A., Lozano J. G., Jin L., Somerville J. W., Duda L. C., Nag A., Walters A., Zhou K. J., Roberts M. R., Bruce P. G., Nature, 2020, 577(7791), 502
Li Q., Yao Z., Lee E., Xu Y., Thackeray M. M., Wolverton C., Dravid V. P., Wu J., Nat. Commun., 2019, 10(1), 1692
Assat G., Tarascon J. M., Nat. Energy, 2018, 3(5), 373
Seo D. H., Lee J., Urban A., Malik R., Kang S., Ceder G., Nat. Chem., 2016, 8(7), 692
Ma Q., Chen Z., Zhong S., Meng J., Lai F., Li Z., Cheng C., Zhang L., Liu T., Nano Energy, 2021, 81, 105622
Li Q., Li G., Fu C., Luo D., Fan J., Li L., ACS Appl. Mater. Interfaces, 2014, 6(13), 10330
Choi A., Lim J., Kim H. J., Jung S. C., Lim H. W., Kim H., Kwon M. S., Han Y. K., Oh S. M., Lee K. T., Adv. Energy Mater., 2018, 8(11), 1702514
Wang E., Xiao D., Wu T., Liu X., Zhou Y., Wang B., Lin T., Zhang X., Yu H., Adv. Funct. Mater., 2022, 1616, 2201744
Luo D., Ding X., Hao X., Xie H., Cui J., Liu P., Yang X., Zhang Z., Guo J., Sun S., Lin Z., ACS Energy Lett., 2021, 6(8), 2755
Li Z., Li Y., Zhang M., Yin Z W., Yin L., Xu S., Zuo C., Qi R., Xue H., Hu J., Cao B., Chu M., Zhao W., Ren Y., Xie L., Ren G., Pan F., Adv. Energy Mater., 2021, 11(37), 2101962
Wang T., Zhang C., Li S., Shen X., Zhou L., Huang Q., Liang C., Wang Z., Wang X., Wei W., ACS Appl. Mater. Interfaces, 2021, 13(10), 12159
Yan H., Li B., Yu Z., Chu W., Xia D., J. Phys. Chem. C, 2017, 121(13), 7155
Wang M. J., Yu F. D., Sun G., Wang J., Zhou J. G., Gu D. M., Wang Z. B., J. Mater. Chem. A, 2019, 7(14), 8302
Liu J., Wang S., Ding Z., Zhou R., Xia Q., Zhang J., Chen L., Wei W., Wang P., ACS Appl. Mater. Interfaces, 2016, 8(28), 18008
Wang P., Zhang Z., Song N., An X., Liu J., Feng J., Xi B., Xiong S., CCS Chem., 2023, 5(2), 397
Zhao X. Y., Lu Y., Qian Z F., Wang R. H., Guo Z. P., Ecomat, 2020, 2(3), e12038
Shen L., Song Y. W., Wang J., Zhao C. X., Bi C. X., Sun S. Y., Zhang X. Q., Li B. Q., Zhang Q., Small Struct., 2022, 7, 2200205
Wang W., Zhu X., Fu L., CCS Chem., 2021, 3(1), 686
Wang Z. S., Wang H. P., Qi S. A., Wu D. X., Huang J. D., Li X., Wang C. Y., Ma J. M., Ecomat, 2022, 4(2), e12200
Wang J., Cui Y., Wang D., Adv. Mater., 2019, 31(38), e1801993
Wang J., Cui Y., Wang D., Nanoscale Horiz., 2020, 5(9), 1287
Wang J., Tang H., Ren H., Yu R., Qi J., Mao D., Zhao H., Wang D., Adv. Sci., 2014, 1(1), 1400011
Wang L., Wan J., Wang J., Wang D., Small Struct., 2020, 2(1), 2000041
Li B., Bi R., Yang M., Gao W., Wang J., Appl. Surf. Sci., 2022, 56(3), 586
Ma Y., Bi R., Yang M., Wei P., Qi J., Wang J., Yu R., Wang D., J. Nanopart. Res., 2023, 25(1), 14
Wang J., Wang Z., Mao D., Wang D., Sci. China Chem., 2021, 65(1), 7
Zhao J., Yang M., Yang N., Wang J., Wang D., Chem. Res. Chinese Universities, 2020, 36(3), 313
Zhao J. L., Wang J. Y., Bi R. Y., Yang M., Wan J. W., Jiang H. Y., Gu L., Wang D., Angew. Chem. Int. Ed., 2021, 60(49), 25719
Wei Y., Wan J., Wang J., Zhang X., Yu R., Yang N., Wang D., Small, 2021, 17(22), e2005345
Wang J., Wan J., Yang N., Li Q., Wang D., Nat. Rev. Chem., 2020, 4(3), 159
Bi R., Mao D., Wang J., Yu R., Wang D., Acta Chim. Sinica, 2020, 78(11), 1200
Wang J., Tang H., Wang H., Yu R., Wang D., Mater. Chem. Front., 2017, 1(3), 414
Wang J., Tang H., Ren H., Yu R., Qi J., Mao D., Zhao H., Wang D., Adv. Sci., 2014, 1(1), 1400011
Wei Y., Wang J., Yu R., Wan J., Wang D., Angew. Chem. Int. Ed., 2019, 58(5), 1422
Wei Y., Yang N., Huang K., Wan J., You F., Yu R., Feng S., Wang D., Adv. Mater., 2020, 32(44), e2002556
Li B., Wang J., Bi R., Yang N., Wan J., Jiang H., Gu L., Du J., Cao A., Gao W., Wang D., Adv. Mater., 2022, e2200206
Wang J. Y., Yang M., Wang D., Chin. J. Chem., 2022, 40, 1190
Nayak P. K., Ginblat J., Levi M., Levi E., Kim S., Choi J. W., Aurbach D., Adv. Energy Mater., 2016, 6, 1502398
Acknowledgements
This work was supported by the National Key R&D Program of China (Nos.2021YFC2902503, 2022YFA1504101), the National Natural Science Foundation of China(Nos.21820102002, 21931012, 52261160573, 51972305), the Cooperation Fund of the Institute of Clean Energy Innovation, Chinese Academy of Sciences(No.DNL202020), the Zhongke-Yuneng Joint R&D Center Program, China(No.ZKYN2022008), and the IPE Project for Frontier Basic Research, China(No.QYJC-2022-008).
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WANG Dan is an editorial board member for Chemical Research in Chinese Universities and was not involved in the editorial review or the decision to publish this article. The authors declare no conflicts of interest.
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Zhao, X., Yang, M., Wang, J. et al. Hollow Multishelled Structural Li-rich Cathode with Al Doping Enabling Capacity and Voltage Stabled Li-ion Batteries. Chem. Res. Chin. Univ. 39, 630–635 (2023). https://doi.org/10.1007/s40242-023-3128-8
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DOI: https://doi.org/10.1007/s40242-023-3128-8