Abstract
Metal oxide nanoparticles are the subject of current interest because of their unusual optical, electronic, and magnetic properties. In this work, cobalt zinc ferrite (\( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \)) nanoparticles have been synthesized successfully through redox chemical reaction in aqueous solution. The synthesized \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticles have been used for the preparation of homogenous polyvinyl acetate-based nanocomposite (\( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \)) via in situ emulsion polymerization method. Structural, morphological and magnetic properties of the products were determined and characterized in detail by X-ray powder diffractometry (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and vibrating sample magnetometer (VSM). The XRD patterns of the \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) confirmed that the formed nanoparticles are single crystalline. According to TEM micrographs, the synthesized \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticles had nano-needle morphology with an average particle size of 20 nm. The calculated coefficient of variation (CV) of nanoparticles diameters obtained by TEM micrographs was 16.77. The \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticles were dispersed almost uniformly in the polymer matrix as was proved by SEM technique. The magnetic parameters of the samples, such as saturation magnetization (M s) and coercivity (H c) were measured, as well. Magnetization measurements indicated that the saturation magnetization of synthesized \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposites was markedly less than that of \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) magnetic nanoparticles. However, the nanocompoites exhibited super-paramagnetic behavior at room temperature under an applied magnetic field.
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Introduction
Due to their unique physicochemical properties, magnetic nanoparticles have been intensively studied in recent years. Magnetic nanoparticles are being actively used for different applications, such as magnetic resonance imaging contrast enhancement, detoxification of biological fluids, drug delivery, and cell separation techniques [1]. For different applications, magnetic nanoparticles are used for preparing polymer-based nanocomposites [2, 3]. Polymers and copolymers with a wide variety of compositions, structures, and properties are available, which make them ideal components for use in nanocomposite materials. Main feature of polymeric nanocomposite, in contrast to conventional composites, is due to their enhanced thermal, mechanical and magnetic properties. However, the structure and properties of polymer-based nanocomposites especially magnetic nanocomposites are significantly affected by quantitative and qualitative specifications of nanoparticles as well as local chemistry, chain mobility, chain conformation, and crystallinity of the polymer matrix. Nevertheless, in magnetic polymer-based nanocomposites, controlled dispersion of magnetic nanoparticles inside the polymer matrix is critical and often challenging. Owing to the non-perfect dispersion of magnetic nanoparticles in the polymer matrix, clusters which are influenced by particle–particle and particle–matrix interactions may be formed. Therefore, to achieve excellent dispersion, the magnetic nanoparticles should be prevented from the formation of larger agglomerates in polymer nanocomposites.
Spinel nanoparticles with general formula “AB2O4” (“A” refers to cations in tetrahedral sites and “B” refers to cations in the octahedral positions) have been used in various technological applications. They show various magnetic properties depending on the composition and cation distribution. Various cations can be placed in A and B sites to tune their magnetic properties. Depending on A and B sites cations, spinel nanoparticles can exhibit ferrimagnetic, antiferromagnetic, spin (cluster) glass, and paramagnetic behavior.
Among these materials, nanoscale spinel ferrites (AFe2O4) exhibit super-paramagnetic characteristic which is fundamental to biomedical applications such as magnetic contrast resonance imaging (MRI). The fabrication of ferrite nanoparticles has been intensively investigated in recent years due to their unique physical and chemical properties. Introducing of metal ions such as Zn, Co, and Mn into the tetrahedral sites of spinel ferrites offers an opportunity to prepare different grades of magnetic nanoparticles [4].
Physical properties of the Co–Zn spinel ferrites (\( {\text{Co}}_{\text{x}} {\text{Zn}}_{{1 - {\text{x}}}} {\text{Fe}}_{2} {\text{O}}_{4} \)) nanoparticles are very sensitive to the amount of metal ions and the method of preparation. Considering the ferrimagnetic, antiferromagnetic, and paramagnetic applicabilities of the Co–Zn ferrites nanoparticles, various synthesis process methods such as coprecipitation, reverse micelle method, sol–gel method, ultrasound irradiation, freeze drying, thermal decomposition of organometallic and coordination compounds, hydrothermal and microwave assisted methods have been used [5–8].
Due to their attractive magnetic and electric properties, synthesis and characterization of various magnetic particles were published in literature in recent years [9–11]. Some of the reported types of nanocomposites are magnetic–metal (Fe3O4–Au) [12], magnetic–metallic oxide (Zn, Ni Ferrite–NiO) [13], magnetic–semiconductors (Fe3O4–PbS) [14], magnetic–alloy ((Ni0.5Zn0.5) Fe2O4–FeNi3) [15], magnetic–zeolite [16] and magnetic–polymer [17].
In this work, high-purity grade nanosized \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) particles were synthesized for preparing the stable \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite. By considering the simplicity, low cost, and use of an aqueous-based processing system, a convenient coprecipitation method was used for the synthesis of \( {\text{Co}}_{ 0. 3} {\text{Zn}}_{ 0. 7} {\text{Fe}}_{ 2} {\text{O}}_{ 4} \) nanoparticles. \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) Nanocomposite was synthesized via an in situ polymerization in emulsion system. The obtained results indicated that magnetic \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposites combine the advantageous properties of both \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) and PVAc.
Experimental
Materials
Commercial grade vinyl acetate (VAc, C4H6O2) and poly vinyl alcohol (PVA, (C2H4O)n, degree of hydrolysis 88 % degrees of polymerization 580, M w = 90,000) were supplied from Iran petrochemical Co., Iran and Kuraray Chemical Co., Japan, respectively. Vinyl acetate monomer was distilled under reduced pressure before use. Cobalt chloride hexahydrate (CoCl2.6H2O), zinc chloride (ZnCl2), iron chloride (FeCl3), oleic acid (C18H34O2), ammonia solution (NH3), ammonium persulfate (APS) and sodium bicarbonate (NaHCO3) were purchased from Merck, Germany. Sodium lauryl sulfate (SLS 99 %) was supplied by Fluka, Switzerland. All chemicals were used without further purification. Water was distilled after being ion-exchanged.
Preparation of \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \)
Nanocrystalline \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) particles have been synthesized by a chemical coprecipitation method [6]. AR grades of CoCl2.6H2O, ZnCl2 and FeCl3 were used as precursors. Initially, 1 mmol of CoCl2.6H2O, 2.3 mmol of ZnCl2 and 6.4 mmol of FeCl3 were dissolved in 100 mL distilled water in a 250 mL glass beaker and homogenized at 65 °C. Then, 25 % ammonia solution was added drop wise with constant stirring and the pH of the solution was maintained at 10. The mixture was then heated at 85 °C for about 1 h. A surfactant coating of oleic acid was made to the individual particles to prevent agglomeration into large aggregates. The precipitate was filtered, washed several times with double distilled water, dried at 75 °C and calcined for 5 h at 750 °C.
Synthesis of \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite
\( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite with nanoparticle loading (3 wt %) was prepared by in situ emulsion polymerization of VAc monomer. In the first step, the synthesized \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) powder was poured directly into 50 ml of distilled water overnight under vigorous stirring and then was dispersed by ultrasonication at room temperature to prevent aggregation of nanoparticles. Then, the mixture was poured into a three-neck flask containing a solution of 0.1 g of APS and 0.1 g buffer solution of NaHCO3. A glass reactor was equipped with a reflux condenser, a funnel, a water jacket to maintain a constant temperature (±0.1 °C) and a mechanical stirrer under constant agitation (200–300 rpm). The aqueous emulsified solution containing 2 g PVA and 0.2 g SLS was added to the reaction system. The mixture was stirred at 300 rpm and heated up to 75 °C. Afterward, the monomer was fed into the reactor in separate stream with constant flow rates to maintain the reaction system at 75 °C. Time of feeding was almost 80 min and after monomer addition, the polymerization was carried out under an inert nitrogen atmosphere for 4 h. Afterward, the temperature was maintained at 90 °C for 1 h with constant stirring. The synthesized \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite was dried at 70 °C for 24 h under vacuum.
Characterization
Fourier transform infrared (FTIR) spectroscopy was recorded by (Magna 550; Nicolet, USA) in the range of 4000–400 cm−1 using KBr pellets. XRD patterns of the samples were collected on a X-ray diffractometer (Philips X’Pert MPD, The Netherlands) with Cu–Kα radiation (λ = 1.54 Ǻ) at a generator voltage of 40 kV and a generator current of 40 mA. The surface morphology and particle diameters of the synthesized \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticles and \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite specimens were investigated using a scanning electron microscope (SEM, Philips, The Netherlands). Prior to SEM examination; the samples were dried at room temperature and coated with a thin layer of gold, using a coating machine (Jeol ion-sputter, JFC-1100, Japan).
Morphology of \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticles was studied using transmission electron microscope (TEM) operating at an accelerating voltage of 120 kV. Samples were prepared as follows: fine power of \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticles were dispersed in ethanol under ultrasonication at 25 °C for 10 min, and then one drop of the dilute suspension of colloid was suspended and evaporated on a carbon-coated copper grid and placed in the Phillips CM-120 TEM (The Netherlands). The magnetic properties, saturation magnetization, coercivity and retentivity of samples were determined from the magnetic moment versus magnetization curves recorded for various samples with the help of a vibrating sample magnetometer (VSM) device, in the Development Center of Kashan University, Iran, under maximum magnetic field of 10 kOe.
Results and discussion
The FTIR spectrum of the synthesized \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticles and \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite are shown in Fig. 1. Spectrum (a) in Fig. 1 shows the characteristic peaks of tetrahedral and octahedral Fe–O stretching bands at 558 and 420 cm−1, respectively. In addition to these vibrational modes, a broad hump due to water symmetric stretching and antisymmetric stretching with maxima at about 3435 cm−1 and the bending mode of water at 1630 cm−1 are observed in these spectra. In ferrites, the metal ions are situated in two different sub-lattices designated tetrahedral (A sites) and octahedral (B sites) according to the geometrical configuration of the oxygen nearest neighbors.
In the spectrum of the \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite as shown in Fig. 1, spectrum (b), the peak observed at 3440 cm−1 can be attributed to the hydroxyl stretching vibration, the peak at 2941 cm−1 can likely be assigned to the C–H stretching vibration, and the peak found at 1742 cm−1 originates with the C=O stretching vibration. The peak at 1439 cm−1 comes from the C–H bending vibration, the peaks observed at 1242 and 1123 cm−1 are associated with the C–O–C symmetrical stretching vibrations [18]. The absorption peaks at 563 and 429 cm−1 may be attributed to the intrinsic vibration of the tetrahedral and octahedral sites in the \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) particles [19].
Pattern (a) in Fig. 2 shows the XRD powder pattern of the nanoparticles. All XRD peaks are corresponds with the JCPDS cards no. 89-1012 (ZnFe2O4) and 22-1086 (CoFe2O4). Analysis of the diffraction pattern using (111), (220), (311), (222) (400), (422), (511), (440), (620), (533) and (622) reflection planes confirmed the formation of spinel structure of the \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \). The lattice constant (a) for each peak of \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) can be calculated using the following equation:
where, d is the spacing of (hkl) crystal planes. The calculated lattice constant was 8.391 Å for (111) plane. The (311) peak was chosen for calculating the average particle size by using the Debye–Sherrer equation as follows:
where, λ is the wavelength of the radiation, β is the full-width at half-maxima (FWHM), θ is the diffraction angle and D is the particle size of the sample (nm). The calculated average particle size of \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanaoparticles was about 10.9 nm.
XRD pattern of the \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite is shown as pattern (b) in Fig. 2. According to this pattern, the characteristic peaks of both PVAc and \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) confirm the formation of the \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite. Furthermore, diffraction peaks of \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite compared to those of \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticles were broader due to the polymer matrix’s restriction on the nanoparticles [20].
TEM micrograph of synthesized \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticles is given in Fig. 3 and their particle size distribution is presented in Fig. 4. Generally, the particles have nano-needle morphology and their sizes vary from 5 to 30 nm. The average size of the \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticles was 20 nm. The coefficient of variation (CV) of particle diameter was defined using the following equation by counting individual particles from TEM microphotograph:
where, n i is the number of particles with d i diameter. The calculated CV was 16.77 from TEM micrograph.
Figure 5 shows the SEM micrograph of the \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticles sample. It provides more structural information about the three-dimensional morphology of the product. According to this figure, the synthesized \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nano-needle particles have very narrow diameter distribution.
Figure 6 shows the SEM micrograph of \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite. According to this figure, the nanosized \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) particles were dispersed almost uniformly in the PVAc matrix. The average particle size of the \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite is about 150–200 nm.
Magnetic property of the as-prepared \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticle was investigated with a vibrating sample magnetometer (VSM) at room temperature. The magnetic hysteresis loop of \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanaoparticles is shown in Fig. 7, loop (a). The obtained magnetic parameters of the samples, such as saturation magnetization (M s) and coercivity (H c) are given in Table 1. According to the obtained results, the M s value of \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticles was 10.82 emu/g. Small value of M s may be due to the oleic acid and formation of a surface layer on \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticles in which magnetic moments do not contribute to the magnetization in the applied field.
For ferromagnetic spinels such as \( {\text{Co}}_{\text{x}} {\text{Zn}}_{{ 1- {\text{x}}}} {\text{Fe}}_{ 2} {\text{O}}_{ 4} \), the changes in magnetic properties such as M s and H c are related to the influence of the cationic stoichiometry and their occupancy in the specific sites. It was shown that for x < 0.5, the magnetization at room temperature shows approximately linear applied field dependence with small s-shaped behavior [21].
Magnetic hysteresis loop of \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite is shown in Fig. 7, loop (b). Saturation magnetization of the \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite depends mainly on the volume fraction of magnetic \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticles. However, due to the non-magnetic PVAc coating contribution and its important role in isolating the magnetic \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticles, the M s of the synthesized \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite is much lower than that for \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticles. In addition, the demagnetic effect of PVAc may reduce the M s of the \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite. Therefore, the magnetization of the \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposites was lower than that of the pure \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticles. According to Table 1, the value of M s for the synthesized \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite was significantly lower compared to that of \( {\text{Co}}_{ 0. 3} {\text{Zn}}_{ 0. 7} {\text{Fe}}_{ 2} {\text{O}}_{ 4} \) nanoparticles.
Conclusion
Considering the extra advantages that could be obtained with combined properties of the inorganic materials (mechanical strength, magnetic and thermal stability) and the organic polymers (flexibility, dielectric, ductility and processability), we first prepared \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticles via a redox chemical reaction in aqueous solution. Then, the synthesized \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticles have been used for preparation of homogenous \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite. The synthesized \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticles and \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite have been analyzed using FTIR, XRD, TEM, SEM and VSM techniques. The average particle size and calculated CV of particle diameter of \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticles were obtained 20 nm and 16.77, respectively, from the TEM micrograph. The results obtained from XRD indicated the formation of a \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite. Due to the non-magnetic PVAc coating contribution, the M s of the synthesized \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite was much lower than that for the \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) magnetic nanoparticles. However, the synthesized \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite presented super-paramagnetic properties. From the magnetic hysteresis loops at room temperature, M s and H c of the \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposite were obtained 10.82 emu/g and 12.24 Oe, respectively. Although, the \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) nanoparticles were dispersed almost uniformly in the polymer matrix as shown in SEM images, the nonzero coercivity value (i.e., 12.24 Oe) probably occur because a small fraction of the particles aggregate to form clusters larger than the super-paramagnetic limit. In general, according to the obtained results, it has been found that in situ emulsion polymerization used here is a suitable method to disperse the \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} \) magnetic nanoparticles in PVAc polymer matrix for preparation of the stable magnetic \( {\text{Co}}_{0.3} {\text{Zn}}_{0.7} {\text{Fe}}_{2} {\text{O}}_{4} /{\text{PVAc}} \) nanocomposites.
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Doulabi, F.S.M., Mohsen-Nia, M. Magnetic cobalt-zinc ferrite/PVAc nanocomposite: synthesis and characterization. Iran Polym J 22, 9–14 (2013). https://doi.org/10.1007/s13726-012-0098-y
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DOI: https://doi.org/10.1007/s13726-012-0098-y