Abstract
The use of aluminium based composite is becoming widespread in the industries where enhanced mechanical and improved corrosion resistance properties are required. Microstructural analysis, hardness and corrosion properties of aluminium based composites reinforced with particles of silicon carbide (SiC) and ferrotitanium (TiFe) were investigated. The composites were produced using stir casting technique, with the dispersion of different weight percentages of single and dual reinforced particles within the aluminium matrix. The microstructural evolution, microhardness and nanohardness properties of the as-cast specimens were investigated. Electrochemical testing of specimens was carried out using potentiodynamic polarization and potentiostatic techniques in 3.5 wt.% sodium chloride (NaCl) solution. The microstructural examinations conducted showed a homogeneous dispersion of the SiC and TiFe reinforcements within the aluminium matrix. The hardness (micro and nano) properties of the reinforced specimens were enhanced due factors which include effective load transfer mechanism between the reinforcements and matrix, and an impediment to dislocation movement within the composite. The specimens reinforced with particles of 5% SiC +2% TiFe and 5% SiC exhibited the most improved corrosion resistance from the potentiodynamic polarization and potentiostatic tests conducted. This was confirmed by the surface analysis of corroded specimens carried out using a field emission scanning electron microscope (FE-SEM). The formation of filiform structure on the surface of the unreinforced aluminium alloy and several pits on the surface of the composites was attributed to the aggressive effect of the chloride ions present in the test electrolyte.
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References
Akinwamide SO, Tshabalala N, Falodun OE, Oke SR, Akinribide OJ, Abe BT et al (2019) Microstructural and corrosion resistance study of sintered Al-tin in sodium chloride solution. Materials Today: Proceedings 18:2881–2886
Ahamed AR, Asokan P, Aravindan S, Prakash M (2010) Drilling of hybrid Al-5% SiC p-5% B 4 C p metal matrix composites. Int J Adv Manuf Technol 49:871–877
Adams FV, Akinwamide SO, Obadele B, Olubambi PA (2020) Comparison study on the corrosion behavior of aluminum alloys in different acidic media. Proceedings, Materials Today
Kalaiselvan K, Murugan N, Parameswaran S (2011) Production and characterization of AA6061–B4C stir cast composite. Mater Des 32:4004–4009
Akinribide OJ, Akinwamide SO, Ajibola OO, Obadele BA, Olusunle SO o, Olubambi PA (2019) Corrosion behavior of ductile and austempered ductile cast iron in 0.01 M and 0.05 M NaCl Environments. Procedia Manufacturing 30:167–172
Singh MK, Gautam RK (2017) Synthesis of copper metal matrix hybrid composites using stir casting technique and its mechanical, optical and electrical behaviours. Trans Indian Inst Metals 70:2415–2428
Kumar BP, Birru AK (2017) Microstructure and mechanical properties of aluminium metal matrix composites with addition of bamboo leaf ash by stir casting method. Trans Nonferrous Metals Soc China 27:2555–2572
Alaneme KK, Bamike BJ (2018) Characterization of mechanical and wear properties of aluminium based composites reinforced with quarry dust and silicon carbide. Ain Shams Engineering Journal 9:2815–2821
Fei T, Kun Y, Jie L, Fang H-j, Shi C-l, Dai Y-l et al (2016) Microstructures and properties of Al–50% SiC composites for electronic packaging applications. Trans Nonferrous Metals Soc China 26:2647–2652
Zhang L, Xu H, Wang Z, Li Q, Wu J (2016) Mechanical properties and corrosion behavior of Al/SiC composites. J Alloys Compd 678:23–30
Akinwamide SO, Lemika SM, Obadele BA, Akinribide OJ, Abe BT, Olubambi PA (2019) Characterization and mechanical response of novel Al-(mg–TiFe–SiC) metal matrix composites developed by stir casting technique. J Compos Mater 53:3929–3938
Li G, Jin X, Wang D, Chen GZ (2009) Affordable electrolytic ferrotitanium alloys with marine engineering potentials. J Alloys Compd 482:320–327
Akinwamide SO, Lemika SM, Obadele BJ, Akinribide OJ, Falodun OE, Olubambi PA, et al. (2019) A nanoindentation study on Al (TiFe-Mg-SiC) composites fabricated via stir casting," in Key Engineering Materials, pp. 81–88
Mo R, Yin X, Ye F, Liu X, Ma X, Li Q, Zhang L, Cheng L (2019) Electromagnetic wave absorption and mechanical properties of silicon carbide fibers reinforced silicon nitride matrix composites. J Eur Ceram Soc 39:743–754
Kiourtsidis GE, Skolianos SM (2007) Pitting corrosion of artificially aged T6 AA2024/SiCp composites in 3.5 wt.% NaCl aqueous solution. Corros Sci 49:2711–2725
Kiourtsidis G, Skolianos SM (1998) Corrosion behavior of squeeze-cast silicon carbide-2024 composites in aerated 3.5 wt.% sodium chloride. Mater Sci Eng A 248:165–172
Rodriguez EL (1987) Corrosion of glass fibres. J Mater Sci Lett 6:718–720
Alaneme KK, Bodunrin MO, Awe AA (2018) Microstructure, mechanical and fracture properties of groundnut shell ash and silicon carbide dispersion strengthened aluminium matrix composites. Journal of King Saud University-Engineering Sciences 30:96–103
Sambathkumar M, Navaneethakrishnan P, Ponappa K, Sasikumar K (2017) Mechanical and corrosion behavior of Al7075 (hybrid) metal matrix composites by two step stir casting process. Latin american journal of solids and structures 14:243–255
Tokariev O, Schnetter L, Beck T, Malzbender J (2013) Grain size effect on the mechanical properties of transparent spinel ceramics. J Eur Ceram Soc 33:749–757
Ourdjini A, Chew K, Khoo B (2001) Settling of silicon carbide particles in cast metal matrix composites. J Mater Process Technol 116:72–76
Izhevskyi V, Genova L, Bressiani J, Bressiani A (2000) "review article: silicon carbide," Structure, properties and processing. Cerâmica 46:4–13
Shah SJ, Henein H, Ivey DG (2013) Microstructural characterization of ferrotitanium and ferroniobium. Mater Charact 78:96–107
Akinwamide SO, Akinribide OJ, Olubambi PA (2020) Microstructural evolution, mechanical and nanoindentation studies of stir cast binary and ternary aluminium based composites. Journal of Alloys and Compounds, p. 156586
Sánchez-Martín R, Pérez-Prado M, Segurado J, Bohlen J, Gutiérrez-Urrutia I, Llorca J et al (2014) Measuring the critical resolved shear stresses in mg alloys by instrumented nanoindentation. Acta Mater 71:283–292
Loto RT, Babalola P (2017) Corrosion polarization behavior and microstructural analysis of AA1070 aluminium silicon carbide matrix composites in acid chloride concentrations. Cogent Engineering 4:1422229
Akinwamide SO, Abe BT, Akinribide OJ, Obadele BA, Olubambi PA (2020) Characterization of microstructure, mechanical properties and corrosion response of aluminium-based composites fabricated via casting—a review. Int J Adv Manuf Technol:1–17
Lin G, Zhang H-W, Li H-Z, Guan L-N, Huang L-J (2010) Effects of Mg content on microstructure and mechanical properties of SiCp/Al-Mg composites fabricated by semi-solid stirring technique. Trans Nonferrous Metals Soc China 20:1851–1855
Akinwamide SO, Akinribide OJ, Phumlani M, Ayodele OO, Mophoso KL, Abe BT et al (2020) Influence of heat treatment on microstructural and mechanical behavior of stir cast Al-(TiFe-SiC) composites. Proceedings, Materials Today
Urena A, Martınez E, Rodrigo P, Gil L (2004) Oxidation treatments for SiC particles used as reinforcement in aluminium matrix composites. Compos Sci Technol 64:1843–1854
Wang M, Zhao Y, Wang L-D, Zhu Y-P, Wang X-J, Sheng J, Yang ZY, Shi HL, Shi ZD, Fei WD (2018) Achieving high strength and ductility in graphene/magnesium composite via an in-situ reaction wetting process. Carbon 139:954–963
Albiter A, Contreras A, Bedolla E, Perez R (2003) Structural and chemical characterization of precipitates in Al-2024/TiC composites. Compos A: Appl Sci Manuf 34:17–24
Zhang Z, Chen D (2006) Consideration of Orowan strengthening effect in particulate-reinforced metal matrix nanocomposites: a model for predicting their yield strength. Scr Mater 54:1321–1326
Casati R, Vedani M (2014) Metal matrix composites reinforced by nano-particles—a review. Metals 4:65–83
Chen A-L, Arai Y, Tsuchida E (2005) An experimental study on effect of thermal cycling on monotonic and cyclic response of cast aluminium alloy-SiC particulate composites. Compos Part B 36:319–330
Zimmerman A, Palumbo G, Aust K, Erb U (2002) Mechanical properties of nickel silicon carbide nanocomposites. Mater Sci Eng A 328:137–146
Reddy MP, Shakoor R, Parande G, Manakari V, Ubaid F, Mohamed A et al (2017) Enhanced performance of nano-sized SiC reinforced Al metal matrix nanocomposites synthesized through microwave sintering and hot extrusion techniques. Progress in Natural Science: Materials International 27:606–614
Swamy A, Ramesha A, Kumar GV, Prakash J (2011) Effect of particulate reinforcements on the mechanical properties of Al6061-WC and Al6061-gr MMCs. J Miner Mater Charact Eng 10:1141–1152
Guo J, Gougeon P, Chen X-G (2012) Study on laser welding of AA1100-16 vol.% B4C metal–matrix composites. Compos Part B 43:2400–2408
Pityana S, Fedotova T, Popoola O (2011) Quantitative study of the hardness property of laser surface alloyed aluminium AA1200. J South Afr Inst Min Metall 111:335–344
Mohapatra S, Chaubey AK, Mishra DK, Singh SK (2016) Fabrication of Al–TiC composites by hot consolidation technique: its microstructure and mechanical properties. Journal of Materials research and Technology 5:117–122
Pardo A, Merino M, Merino S, Viejo F, Carboneras M, Arrabal R (2005) Influence of reinforcement proportion and matrix composition on pitting corrosion behaviour of cast aluminium matrix composites (A3xx. x/SiCp). Corros Sci 47:1750–1764
Trowsdale A, Noble B, Harris S, Gibbins I, Thompson G, Wood G (1996) The influence of silicon carbide reinforcement on the pitting behaviour of aluminium. Corros Sci 38:177–191
Katkar V, Gunasekaran G, Rao A, Koli P (2011) Effect of the reinforced boron carbide particulate content of AA6061 alloy on formation of the passive film in seawater. Corros Sci 53:2700–2712
Mayyas AT, Hamasha MM, Alrashdan A, Hassan AM, Hayajneh MT (2012) Effect of copper and silicon carbide content on the corrosion resistance of Al-Mg alloys in acidic and alkaline solutions. J Miner Mater Charact Eng 11:335–352
Loto RT, Babalola P (2018) Effect of alumina nano-particle size and weight content on the corrosion resistance of AA1070 aluminum in chloride/sulphate solution. Results in Physics 10:731–737
Gupta R, Sukiman N, Cavanaugh M, Hinton B, Hutchinson C, Birbilis N (2012) Metastable pitting characteristics of aluminium alloys measured using current transients during potentiostatic polarisation. Electrochim Acta 66:245–254
Rivai AK, Takahashi M (2008) Compatibility of surface-coated steels, refractory metals and ceramics to high temperature lead–bismuth eutectic. Prog Nucl Energy 50:560–566
Han Y-M, Chen X (2015) Electrochemical behavior of Al-B4C metal matrix composites in NaCl solution. Materials 8:6455–6470
Sweitzer J, Shiflet G, Scully JR (2003) Localized corrosion of Al90Fe5Gd5 and Al87Ni8. 7Y4. 3 alloys in the amorphous, nanocrystalline and crystalline states: resistance to micrometer-scale pit formation. Electrochim Acta 48:1223–1234
Liu Z, Wu B, Gu M (2007) Effect of hydrolysis of AlN particulates on corrosion behavior of Al/AlNp composite in neutral chloride solution. Compos A: Appl Sci Manuf 38:94–99
Reboul M, Baroux B (2011) Metallurgical aspects of corrosion resistance of aluminium alloys. Mater Corros 62:215–233
Akinwamide SO, Lemika SM, Adams F, Akinribide OJ, Abe BT, Olubambi PA (2019) An investigation on the corrosion behavior of Al (mg-TiFe-SiC) matrix composite in acidic and chloride media. Materials Today: Proceedings 18:3827–3834
Zakaria H (2014) Microstructural and corrosion behavior of Al/SiC metal matrix composites. Ain Shams Engineering Journal 5:831–838
Lindroos V, Talvitie M (1995) Recent advances in metal matrix composites. J Mater Process Technol 53:273–284
Muley AV, Aravindan S, Singh I (2015) Nano and hybrid aluminum based metal matrix composites: an overview. Manufacturing Review 2:15
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The authors are grateful to Global Excellence and Stature of University of Johannesburg and National Research Foundation South Africa for funding.
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Akinwamide, S.O., Akinribide, O.J. & Olubambi, P.A. Influence of Ferrotitanium and Silicon Carbide Addition on Structural Modification, Nanohardness and Corrosion Behaviour of Stir-Cast Aluminium Matrix Composites. Silicon 13, 2221–2232 (2021). https://doi.org/10.1007/s12633-020-00733-6
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DOI: https://doi.org/10.1007/s12633-020-00733-6