Abstract
The surfaces of Fe3 O 4 nanoparticles were modified with [3-(2,3 epoxypropoxy)propyl]trimethoxysilane and polyethylenimine (PEI) and then manganese acetate was loaded on Fe3 O 4@PEI and the resultant Fe3 O 4@PEI.Mn nanoparticles applied as a heterogeneous nanocatalyst. The prepared Fe3 O 4@PEI nanoparticles were characterized by FTIR, powder X-ray diffraction, TGA, VSM, SEM and TEM. The EDAX analysis was used to identify the elemental composition of the prepared Fe3 O 4@PEI.Mn nanoparticles. The catalytic activity and selectivity of the Fe3 O 4@PEI.Mn was examined in cyclohexene, ethyl benzene and toluene oxidation reaction with 30 % aqueous H2 O 2 as an oxidant. Furthermore, the effect of reaction parameters such as kinds of solvents,
temperature, oxidant amount and catalyst reusability were investigated. Results show that the original properties of the nanoparticles were well preserved and also good activity and reusability were observed in the oxidation of cyclohexene, ethyl benzene and toluene. Moreover, this heterogeneous catalyst can be recovered with a magnetic field and reused for several times without noticeable loss of catalytic activity.
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Tarasi, R., Ramazani, A., Ghorbanloo, M. et al. Synthesis of Magnetic Fe 3 O 4 @polyethyleneimine.Mn(II) from Fe 3 O 4 , [3-(2,3-Epoxypropoxy)propyl]trimethoxysilane, Polyethyleneimine and Mn(II) Acetate as a Novel Silicon-Containing Polymeric Organic-Inorganic Hybrid Nanomaterial and Its Catalytic Investigation Towards the Oxidation of Cyclohexene, Ethyl Benzene and Toluene in the Presence of H 2 O 2 as an Oxidant. Silicon 10, 257–265 (2018). https://doi.org/10.1007/s12633-016-9436-6
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DOI: https://doi.org/10.1007/s12633-016-9436-6