Abstract
\(\upgamma -\)cyclodextrin (\(\upgamma \)-CD) formed inclusion complexes with poly(dimethylsiloxane)s (PDMS) under sonic energy and the products were crystalline compounds. In this study an inclusion complex between PDMS and \(\upgamma \)-CD was synthesized at room temperature in the presence of light and mixing, in the absence of light and in the absence of mixing. These inclusion complexes (ICs) were characterized by XRD, DSC, 1H NMR, UV–Vis and FT-IR spectroscopy. The findings suggest that the reaction conditions change the crystalline structure and mole ratios of the complexes (monomer unit/\(\upgamma \)-CD) determined by 1H NMR spectroscopy for all of the ICs with \(\upgamma \)-CD; which is 2 at room temperature, 1.5 under sonic energy, 3 without light and mixing. The UV–Vis results indicate an IC between \(\upgamma \)-CD and PDMS.
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References
Yang C, Yang J, Ni X, Li J (2009) Macromolecules 42:3856–3859
Sauvage J-P, Dietrich-Buchecker (1999) Weinheim
Semlyen JA (2000) Kluwer Academic Publisher, Boston
Bender ML, Komiyama M (1978) Springer-Verlag, Berlin
Wenz G, Han BH, Muller A (2006) Chem Rev 106:782–817
Harada A, Kamachi M (1990) Macromolecules 23:2821–2823
Jones RG (2000) Kluwer Academic Publishers, Dordrecht, The Netherlands
Duo Q, Wang C, Cheng C, Han W, Thune PC, Ming W (2006) Macromol Chem Phys 207:2170
Gelsest C, (1967) Reactive Silicones: Forging New Polymer Links, Gelest Inc, Morrisville, Pennsylvania, Available at: www.gelest.com/company/pdfs/reactivesilicones.pdf
Semsarzadeh MA, Abdollahi M (2011) J Appl Polym Sci 4:2423–2430
Miller RD, Michl A (1989) J Chem Rev 89:1359–1410
Trefonas P, Djurovich PI, Zhang X-H, West R, Miller RD, Hofer D (1983) J Polym Sci Polym Lett Ed 21:819–823
Okumura H, Okada M, Kawaguchi Y, Harada A (2003) Macromolecules 36:6422–6429
Araki J, Zhao C, Ito K (2005) Macromolecules 38:7524–7527
Huh KM, Ooya T, Lee WK, Sasaki S, Kwon IC, Jeong SY, Yui N (2001) Macromolecules 34:8657–8662
Silver Stain RM, Bassler GC, Morrill TC (1981) Wiley, New York, NY, p 320
Farcasa A, Jarrouxb N, Farcasc A-M, Harabagiua V, GueganbDigest P (2006) J Nanomater Bios 1:55–60
Brown DA, Price GJ (2001) Polymer 42:4767–4771
Peng H, Cheng S, Fan Z (2004) J Appl Polym Sci 92:532–538
Luo ZH, Yu HJ, He TY (2008) J Appl Polym Sci 108:1201–1208
Clarson SJ, Dodgson K, Semlyen JA (1985) Polymer 26:930–934
SJ, Mark JE, Dodgson K (1988) Polymer Communications 29:208–211
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Semsarzadeh, M.A., Amiri, S. Preparation and Characterization of Inclusion Complexes of Poly(dimethylsiloxane)s with γ-Cyclodextrin Without Utilizing Sonic Energy. Silicon 4, 151–156 (2012). https://doi.org/10.1007/s12633-012-9116-0
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DOI: https://doi.org/10.1007/s12633-012-9116-0