Abstract
Hydrolysis kinetics of soda lime silicate glass (SLS) with 75 mol% SiO2 in different pH solutions was investigated. Fourier Transform Infrared (FTIR) spectroscopy was used to monitor and confirm the proposed corrosion mechanisms on the surfaces of prepared undoped (SLS) glass together with samples doped with one of the first 3d-transition metal oxides (TMO) (TiO2→CuO) when exposed to an aqueous solution for a short time period. The traditional proposed mechanism of silicate glass corrosion through ion exchange is analyzed in correlation with infrared reflectance vibrational spectra to confirm the suggested mechanism. The effects of transition metal oxides are followed and interpreted.
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References
Holland L (1994) The properties of glass surfaces, 2nd edn. Reinhold, New York
Morey GW (1954) The properties of glass. Rainbold publishing, New York
Paul A (1990) Chemistry of glasses, 2nd edn. Chapman & Hall, New York
Zhang Y, Stolper EM, Wasserburg GJ (1991) Geochim Cosmo Acta 55:441
Zhang Y, Stolper EM, Ihinger PD (1995) Am Mineral 80:593
Grambow B (1992) In: Clark DE, Zoitos BK (eds) Corrosion of glass, ceramics and ceramic superconductors. Noyes Publications, Park Ridge, p 125
Doremus RH (1994) Glass science, 2nd edn. Wiley, New York
Mitchell JW, Devries RC, Roberts RW, Cannon P (eds) (1969) Reactivity of solids. Wiley, New York, p 667
Doremus RH (1995) J Mater Res 10:2379
Bunker BC (1994) J Non-Cryst Solids 179:300
Newton RG (1985) Glass Technol 26(1):21
Khedr AA, El-Batal HA (1996) J Am Ceram Soc 79:733
Azooz MA, El-Batal HA, ElBadry KHM, Abd ElMoneim M, ElAshry SM (2006) Glass Techn: Eur J Glass Sci Technol Part A 47:164
Wong J, Angell CA (1976) Glass structure by spectroscopy. Marcel Dekker, New York
Robinet L, Eremin K, Coupry C, Hall C, Lacome N (2007) J Non Cryst Solids 353(16–17):1546
Dilmore MF, Clark DE, Hench LL (1978) J Am Ceram Soc 61:439
Isard JO, Priestly D (1985) Phys Chem Glasses 26:221
Vilarigues M, Da Silva RC (2009) J Non Cryst Solids 355:1630
Rahimi RA, Raisali G, Sadrnezhaad SK, Alipour A (2009) J Nucl Mater 385(3):527
Doremus RH (1983) J Non Cryst Solids 55:143
Husung RD, Doremus RH (1990) J Mater Res 5(10):2209
Tomozawa H, Tomozawa M (1989) J Non Cryst Solids 109:311
Dunken H, Doremus RH (1987) J Non Cryst Solids 92:61
Hench LL (1975) Non Cryst Solids 19:27
Rahimi RA, Sadrnezhaad SK, Raisali G (2009) J Non Cryst Sol 355(3):169
Tournié A, Ricciardi P, Colomban Ph (2008) Solid State Ionics 179(38):2142
Cailleteau C, Weigel C, Ledieu A, Barboux P, Devreux F (2008) J Non Cryst Solids 354(2–9):117
Matthew EL, Diane CF, David EC (2007) J Non Cryst Solids 353(17):2667
Abo-Naf SM, El-Batal FH, Azooz MA (2003) Mater Chem Phys 77:846
Khalil EMA, El-Batal FH, Hamdy YM, Zidan HM, Aziz MS, Abdelghany MA (2010) Physica B: Condensed Matter 405:1294
Khalil EMA, Abdelghany MA, Ghoneim ME (2010) 2nd International Conference on Advanced Materials and their applications and its workshop on New Trends in Nano-science and laser Physics, Physics Division, NRC, EGYPT
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El-Batal, F.H., Khalil, E.M., Hamdy, Y.M. et al. FTIR Spectral Analysis of Corrosion Mechanisms in Soda Lime Silica Glasses Doped with Transition Metal Oxides. Silicon 2, 41–47 (2010). https://doi.org/10.1007/s12633-010-9037-8
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DOI: https://doi.org/10.1007/s12633-010-9037-8