Abstract
Disasters caused by water inrush during production affect many coal mines in China. To rapidly and accurately prevent further water inrush, a comprehensive identification model combining hydrochemistry analysis, water source detection, and water channel exploration is proposed. The Schukalev classification method (SCM) is used to distinguish the concentration distribution of the main ion between the water inrush source and other aquifers, and hierarchical cluster analysis (HCA) is adopted to classify the water samples in the hydrochemistry analysis stage. Water channel exploration and water source detection are combined to test and verify the conclusion in the third stage. The comprehensive discrimination model is applied to the water inrush of the Buliangou coal mine. Hydrochemistry analysis shows that the percentages of the main ions (Na+, Ca2+, Mg2+, HCO3−, and Cl−) are greater than 30% (excluding SO42−), which is in agreement with the case of a sandstone aquifer. In the second stage, water source detection based on the transient electromagnetic method (TEM) and drilling technique indicates that not much water is present in the anomaly area around the water inrush location. The limited water recharge contradicts the phenomenon of water inrush. Water channel exploration is carried out, and an area with massive fissures that have water storage capacity is revealed. The conclusion is that the water conserved in the fissures flows out over a short time without the occurrence of stable recharge. The comprehensive discrimination model has complementary advantages and improves the water inrush prediction efficiency.
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Introduction
Water inrush is of paramount concern to the mining industry (Wu et al. 2017; Hu et al. 2011; Yang et al. 2018). Water inrush has various causes and consequences, including catastrophic failure, substantial economic losses, and the loss of lives (Zhang 2005; Yang et al. 2017). Therefore, identifying sources of water inrush is of vital importance for progressing safety surveillance and maintenance. Hydrogeological and structural conditions, along with the corresponding water level, temperature, and hydrochemistry, are commonly used in the literature to comprehensively analyze and determine a water source. The hydrochemistry method originated from a simple water quality analysis and developed to isotope technology (Dou et al. 2011; Ma et al. 2015; Yao et al. 2016; Bo et al. 2015). Nonlinear analysis methods, including Grey system theory (Qiu et al. 2016; Xiao et al. 2013), fuzzy mathematics (Xiao et al. 2016; Peng et al. 2015), artificial neural networking (Wang et al. 2012), geographic information systems, and the support vector machine (Zhang et al. 2006), have also been studied and applied. The hydrochemistry method eventually evolved into multivariate statistical methods, which include cluster analysis (Sun 2014; Wang et al. 2011; Areerachakul and Sanguansintukul 2010) and discriminant analyses (Panagopoulos et al. 2016; Singaraja et al. 2014; Güler et al. 2002).
In the past few decades, hydrochemistry analysis, water source detection, and water channel exploration were proposed to analyze the source of water inrush individually. Each has its own shortcomings leading to misjudgments. Hierarchical cluster analysis (HCA) is typically performed to determine the source of water inrush in coal mines (Helstrup et al. 2007; Li et al. 2014). However, it is difficult to satisfy the requirements of safety in mining via hydrochemistry analysis due to water mixture and the severe threat of disaster. The aim of this paper is to analyze the reliability of the hydrochemistry method and then to propose a comprehensive identification model that is useful for preventing mine water hazards.
Study area
Buliangou coal mine
The Buliangou coal mine is located in the Dalu Township of the Inner Mongolia autonomous region. The study area is part of the Yellow River basins, and the rivers in this area drain into the Yellow River seasonally. The land slopes gently towards the northeast. In addition, the ground level is generally between 1127 and 1346 m above sea level (Fig. 1).
The Buliangou coal mine has a temperate continental monsoonal climate and a mean annual temperature of 7.8 °C. The climate is arid; the average annual precipitation was 389.80 mm from 1961 to 2014. The average annual evaporation is 1964.8 mm. The study area is dominated by descending precipitation, and precipitation deficit may further worsen the shortage of water resources. The extreme precipitation events in this area have followed an increasing trend, which has been more noticeable over the past decade. In addition, a higher risk of drought can be expected in summer, and the amount of precipitation in winter and spring has been increasing. The coal mine is influenced by seasonal precipitation according to the relation curve of the mine water inflow (Huang et al. 2015).
Geological conditions of panel F6204
The Buliangou coal mine is located in the northern Zhungeer coalfield. Panel F6204 is in the northwest region of the coal mine and is the first panel affected by the Ordovician limestone with confined water pressure. The strike length of the panel is 1330 m, while the inclination length is 240 m. The panel is geologically located in a monoclinal structure with five small faults and two large faults, namely, DF28 and DF30 (Fig. 2). The main water channels of panel F6204 might be these faults, the water flowing fractured zones, fissures, and an improperly sealed drill hole (Y0808). The water channels may cause a hydraulic interaction between the confined Ordovician limestone aquifers and the panels (Wu and Wang 2006; Xu and Gong 2011; Sun et al. 2008).
Previous research has shown that the aquifers that primarily affect the no. 6 coal seam include the sandstone aquifers of the Shanxi group (A1), those of the Taiyuan group (A2), and the karstic limestone aquifers of the Ordovician (A3), as shown in Fig. 3. The mean thickness of A1 is 58.13 m, and the specific capacity is 0.007 L/s m. The thickness of A2 varies from 34.95 to 89.45 m, the water level is 933.00 m, and the specific capacity is 0.008 L/s m. A3 is an indirect water source of the no. 6 coal seam and located approximately 60 m below the floor. Its specific capacity is 1.581 L/s m. The floor elevation of this panel is generally between 822 and 904 m, and the water level of A3 varies from 866.42 to 876.66 m. Panel F6203 is adjacent to panel F6204 on its north side. The accumulated water from panel F6203 could flow into panel F6204.
Water inrush situation
There were two points of water inrush occurred at panel F6204, as shown in Fig. 2. The initial water discharge from the auxiliary transport gateway was 30 m3/h. The water inflow was constant at 5 m3/h after drainage. The water inflow through the main transport gateway was 23 m3/h. It was well known that there was a threat of water inrush in the process of mining the panel. The source of the water inrush, regardless whether it was the water of panel F6203 or the A3 aquifer, was considered to pose a significant threat to mining safety (Li and Zhou 2006).
Methodology
Determining water inrush sources without knowing the water pressure or flow field is difficult (Liu and Cao 2011). In this study, we developed a comprehensive discrimination model to assess water inrush according to the following three steps.
Sampling and preliminary analysis
The hydrochemical characteristics of water samples from the Buliangou coal mine were analyzed and studied. Analysis of the water inrush samples was conducted at the Shanxi Provincial Coal Industry Bureau Testing Center via the following methods: SO42−, Cl−, (Na++K+), Ca2+, and Mg2+ were analyzed by ion chromatography (CIC-200); alkalinity (including HCO3− and CO32−) was analyzed by acid-base titration (Papadopoulou-Vrynioti et al. 2014). Analyses of the ion chromatography were calibrated by the standard curve method, which was constructed based on the standard solution. All of the analyses had a relative standard deviation below 3%, and a hydrochemistry database was constructed (Bathrellos et al. 2008). Then, the Schukalev classification method (SCM) was used to analyzed the concentration distribution of the main ion between the water inrush source and other aquifers (Jiang et al. 2006). Concentrations with anion and cation contents greater than 25% were categorized into 49 hydrochemical types, as shown in Table 1. Each type with a serial number denotes the hydrochemistry of the water sample itself.
Hierarchy clustering analysis
HCA is adopted to classify the water samples. Each water sample that contained m test indexes is defined as a point in m-dimensional space (Anderberg 1973). The diverse distances between two categories result in different clustering results and the development of different clustering methods. The most common clustering methods include the nearest neighbor, the furthest neighbor, the between-group linkage, and Ward’s method. The higher the hydrochemical similarity between water inrush samples and standard water samples, the more accurate the results will be in determining the source of water inrush. Cluster identification by the nearest neighbor method, which was carried out in this paper, is shown to be quite reliable and robust with respect to the highest similarity, with the identified cluster being very consistent with those obtained via the SCM. The entire clustering process can be represented as a cluster graph (tree) image.
Verification process
Water inrush from the aquifer into the coal seam is affected by two factors: the water yield of the aquifer and the distribution of the water channels (Wu et al. 2017). To test and verify the conclusion of the first step, water source detection based on the TEM and drilling technique is used to analyze the water yield condition of the anomaly area. In addition, the radio wave perspective method is adopted to detect the fissure and structures.
Results and discussion
Preliminary analysis
In this study, a total of 11 standard hydrochemical dates, which can represent the characteristic of each aquifer, were collected from 31 samples (Table 2). Sample 1 was taken from a nearby river, while samples 2 and 3 were collected from the roof of panel F6106. Samples 4, 5, 6, and 7 were taken from A2. Sample 10 was taken from A3. Sample 11 was taken from the roof of panel F6208. Samples 12 and 13 were taken from panel F6203. Samples 8 and 9 were collected at the locations of water inrush and sent to a laboratory for analysis of the main ions.
The water samples were classified via Schukalev classification method (SCM). We categorized the water samples into six groups: (1) Sample 1 was taken from the river, and the hydrochemical type was Ca2+ + Mg2+—HCO3−. (2) Samples 2 and 3 were taken from panel F6106, and the hydrochemical type was Ca2+ + Mg2+—HCO3. (3) Samples 4, 5, 6, and 7 were taken from the transport gateway floor on both sides of panel F6204, with sampling locations in the A2 of floor. The hydrochemical types were Na+ + Ca2+ + Mg2+—HCO3− + Cl−. (4) Samples 8 and 9 fell into the same category, possibility originating from the A2 aquifer. (5) Sample 10 was taken from A3, and the hydrochemical type was Na+ + Ca2+ + Mg2+—HCO3− + SO42−. It can represent the characteristics of water from the A3 aquifer. Sample 11 was taken from the A1 aquifer, and the hydrochemical type was Na+ + Ca2+ + Mg2+—HCO3− + SO42−. (6) Samples 12 and 13 were taken from panel F6203, and the hydrochemical type was Na++Ca2+—HCO3− + Cl−. The percentage of Na+ and HCO3− ions in samples 12 and 13 was high, being obtained from the goaf area, which has been contaminated by mining activity.
Hierarchy clustering analysis
Groundwater contains different types and amounts of ions in different locations; hence, ionic components are often used to indicate the chemical characteristics of a water source (Helstrup et al. 2007). In this study, we applied seven common ions, Na+, K+, Ca2+, Mg2+, Cl−, SO42−, and HCO3−, as the indexes for clustering. The HCA model was established to determine the cluster distance (D E ) of water inrush and the different groundwater hydrochemical characteristics. The calculation process is as follows.
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(1)
The primary data of the seven indexes were processed by the standard deviation standardization method.
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(2)
The Euclidean distance was used to measure the distance between 13 sets of water quality data. If the seven-dimensional space of any two samples in terms of the distance was calculated, this could be arranged in the distance similarity matrix as shown in Table 3.
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(3)
The distance between classes was calculated by the nearest neighbor method, and the samples were classified. The samples were divided into three groups, as shown in Fig. 4.
Samples 1, 2, and 3 were placed in group 1. The hydrochemical type of group 1 is Ca2+ + Mg2+—HCO3−. The average contents of Ca2+, Mg2+, and HCO3− were 48.32, 33.05, and 83.08%, respectively. Sample 1 was taken from the river, and the large volume of HCO3− ions (the largest among all samples) shows that samples 2 and 3 had a close hydraulic relationship with the surface water.
Samples 10, 11, 12, and 13 were assigned to group 2. They could be further categorized, with samples 12 and 13 in group 2-1 and samples 10 and 11 in group 2-2. The percentage of Na+ and HCO3− ions is high in group 2-1, which is from the goaf area contaminated by mining activity. Thus, group 2-1 can represent the hydrochemical characteristics of the goaf water. Regarding group 2-2, sample 10 has a lower percentage of Cl− ions, and the percentages of the other ions are greater than 30%, with the SO42− ion content being greater than 50%. Sample 11 was taken from the A1 aquifer, having hydrochemical characteristics similar to those of sample 10 from the A3 aquifer but different from those of sample 4 of the A1 aquifer. The abnormality of sample 11 indicates that it was greatly affected by the recharge of other aquifers; thus, group 2-2 can only represent the hydrochemical characteristics of the A3 aquifer.
Samples 4–9 were classified as group 3. Aside from SO42−, the ion percentages are greater than 30%, which is the characteristic of water from the A2 aquifer. It was obvious that samples of group 3 had a similar occurrence and hydrochemical characteristics to water originating from the A2 aquifer.
The results of HCA can be explained by hydrochemical characteristic analysis. However, it is difficult to satisfy the requirements of safety in mining via hydrochemistry analysis due to water mixture and the severe threat of disaster.
Verification process
The result of SCA was consistent with that of HCA. The main ion characteristics of water samples determine the results of HCA. However, the occurrence and migration conditions of groundwater are the basis for the evolution of the ion characteristics and decide the hydrochemical type fundamentally due to the water-rock interaction, which effect the conclusion of HCA based on the hydrochemical dates. To validate the accuracy of the above results, water source detection (the occurrence conditions) and water channel exploration (the runoff conditions) around the water inrush position are combined to clarify and verify the conclusion in the second stage.
Water source detection
The TEM can provide a strong response for an underground conductive medium and is suitable for evaluating the degree of water in fault areas, detecting collapsed columns and classifying aquifers (Chang et al. 2016; Cheng et al. 2015). In this study, the TEM was used to detect the areas of anomalous water occurrence for panel F6204. The measuring points were arranged in the main transportation roadway and auxiliary transportation roadway of panel F6204, from the cut-hole to the stopping line, with a measuring point every 10 m, as shown in Fig. 5. The horizontal axis in Fig. 6 indicates the position along the gateway direction, while the vertical axis represents the distance along the direction of detection. The curve shows the apparent resistivity, with a unit of ohm meter. The TEM survey indicated two areas of low resistivity: from 130 to 270 m and from 600 to 780 m. The former shows low resistance in the transport gateway but not in the auxiliary gateway. As the elevation of the coal seam floor in this range was below the water level of A3, this range coincided with the location of the point of water inrush; this area was designated anomaly area I.
The latter showed a strong, low resistivity in both gateways and corresponded to the location of DF28 and Y0808 in the panel; this area was designated anomaly area II. Figure 6a shows the result of anomaly area I, and Fig. 6b shows the result for anomaly area II. Anomaly area I had a half-open boundary, which indicated that the detected area had a large volume of water. Anomaly area II had a closed boundary, and the volume of water was greater than that of anomaly area I, which was supposed to be affected by the faults and the improperly sealed drill hole.
To further evaluate the degree of water in the anomaly area, five drill holes were created to detect the water in anomaly area II, as shown in Fig. 7 and Table 4. Drill hole Z5 had a maximum water pressure of 0.16 MPa, whereas the water pressure could not be detected in the other drill holes. The drilling grouting pressure was expected to be 0.3 MPa if the water was derived from the A3 aquifer. The results show that the supply of water in anomaly area II was limited.
Water channel exploration
The radio wave perspective method is a geophysical technique that uses electromagnetic waves to characterize coal seam waveguides, through which the geological structure of coal seams can be examined (Xiao et al. 2016). An area K1, with mainly vertical fissures, was discovered, as shown in Fig. 8.
The huge fissure network provides a good space for groundwater movement and storage. Two positions of water inrush were found in the K1 area on both sides, which overlap with anomaly area I. This indicated that the source of inrush at panel F6204 was the A2 aquifer.
Further discussion
SCA has been used to find the significant parameters that affect the hydrochemical characteristics of groundwater in each aquifer. In addition, HCA led to classification of the water samples into three groups. However, the results might not reflect the real hydrochemical characteristics due to mixture of the water samples and the use of different testing equipment. In this study, the hydrochemical characteristics of sample 11 were similar to those of sample 10, with the two samples originating from different aquifers. Even if the results of the hydrochemical methods were consistent, they might only result in a reference conclusion because of the severe threat of disaster. To avoid incorrect conclusions and reduce the chance of sample misplacement, other detection means are introduced.
The factors resulting in water hazards mainly include the yield of water sources and the scale of water channels. In the third stage, water source detection based on the TEM and drilling technique indicates that the occurrence of water in the anomaly area around the water inrush location is minimal. The limited water recharge contradicts the phenomenon of water inrush. Water channel exploration was carried out, with an anomaly area with massive fissures that have the capacity for water storage being revealed. The combined water source detection and water channel exploration indicates that the water of the A2 aquifer conserved in these fissures flows out over short time but does not result in stable recharge. When the cation exchange reaction between the Ca2+, Mg2+, and Na+ occurring on the surface of particle, the average concentration of Ca2+ and Mg2+ reduced by 24 and 7%, respectively, while that of Na+ increased by 53%. Due to the abundant Cl− in the sandstone, the Cl− in the groundwater raised by four times after filtration. Then, the water quality type changed from “Ca2+ + Mg2+—HCO3−” to “Na+ + Ca2+ + Mg2+—HCO3− + Cl−,” which can represent the characteristics of water from A2. Water inrush in the A2 aquifer flowed through the fracture and did not involve other aquifers; thus, the main ion characteristics were kept stable. HCA is suitable for analyzing the sources of water inrush in the Buliangou coal mine. The comprehensive discrimination model has complementary advantages and improves the water inrush prediction efficiency.
Conclusions
Based on hydrochemical analyses of the major ion concentrations of groundwater samples from the Buliangou coal mine, a comprehensive identification model combining hydrochemistry analysis, water source detection, and water channel exploration is proposed and applied to identify the water inrush sources of the Buliangou coal mine. The following conclusions are obtained:
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(1)
The groundwater samples from A1, A2, and A3 are different from each other. The hydrochemical types of water inrush samples 8 and 9 were all Na+ + Ca2+ + Mg2+—HCO3− + Cl−, being the same as that of the A2 aquifer. The possibility of water recharge from panel F6203 and the A3 aquifer was eliminated.
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(2)
The ion characteristics of water samples determine the results of HCA. The occurrence (water sources) and runoff conditions (water channel) are the basis for the evolution of the ion characteristics of groundwater.
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(3)
The results show that the water of the A2 aquifer conserved in the fissures flows out over a short time but without stable recharge. The hydrochemistry analysis is reliable and accurate for water inrush prediction and can be used preferentially in emergency conditions for this coal mine. When the comprehensive identification model has been applied successfully, HCA would be enough for identification of water source. The use of the comprehensive identification model can be helpful for methods complementary and improving the prediction efficiency.
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Funding
The authors acknowledge the financial support from the National Basic Research Program of China (973) Funded Project (Grant No. 2013CB227900) and the National Key R&D Program of China (Grant No. 2017YFC0804101).
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Liu, Q., Sun, Y., Xu, Z. et al. Application of the comprehensive identification model in analyzing the source of water inrush. Arab J Geosci 11, 189 (2018). https://doi.org/10.1007/s12517-018-3550-2
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DOI: https://doi.org/10.1007/s12517-018-3550-2