Abstract
The cellulose based solid polymer electrolytes (SPEs) containing carboxymethyl cellulose doped with ammonium carbonate (AC) have been prepared via solution casting techniques. The XRD analysis shows that the SPE films are amorphous in nature. FTIR spectroscopy shows that the occurrence of interaction between AC salt and the polymer matrix at wavenumber range of 800-1800 cm-1. Impedance measurement shows that the highest ionic conductivity was achieved at 7.71×10−6 S cm−1 (7 wt% AC) obtained at 303 K. The ionic conductivity of SPE films at different salt concentration were revealed to follow Arrhenius law and thermally assisted.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
S. Goriparti, E. Miele, F. D. Angelis, E. D. Fabrizio, R. P. Zaccaria, and C. Capiglia, J. Power Sources, 257, 421 (2014).
M. N. Chai and M. I. N. Isa, Int. J. Polym. Anal. Charact., 18, 280 (2013).
M. L. Verma, M. Minakshib, and N. K. Singh, Electrochim. Acta, 137, 497 (2014).
Y. Zhang, M. Zuo, Y. Song, X. Yan, and Q. Zheng, Compos. Sci. Technol., 106, 39 (2015).
N. N. Mobarak, A. Ahmad, M. P. Abdullah, N. Ramli, and M. Y. A. Rahman, Electrochim. Acta, 92, 161 (2013).
O. A. Ileperuma, G. R. A. Kumara, H. S. Yang, and K. Murakami, J. Photochem. Photobiol. A-Chem., 217, 308 (2011).
M. M. A. Khan, Rafiuddin, and Inamuddin, Ind. Eng. Chem. Res., 19, 1365 (2013).
P. M. Adinugraha and W. D. Marseno, Carbohydr. Polym., 62, 164 (2005).
M. N. Chai and M. I. N. Isa, J. Cryst. Proc. Technol., 3, 1 (2013).
H. D. Heydarzadeh, G. D. Najafpour, and A. A. Nazari-Moghaddam, World Appl. Sci. J., 6, 564 (2009).
C. Sassoa, D. Beneventia, E. Zeno, M. P. Conil, D. Chaussya, and M. N. Belgacema, Synth. Met., 161, 397 (2011).
A. S. Samsudin, W. M. Khairul, and M. I. N. Isa, J. Non- Cryst. Solids, 358, 1104 (2012).
R. Lan and S. Tao, ECS Electrochem. Lett., 2, F37 (2013).
N. E. A. Shuhaimi, L. P. Teo, S. R. Majid, and A. K. Arof, Synth. Met., 160, 1040 (2010).
S. Rajendrana and P. Sivakumar, Physica B, 403, 509 (2008).
K. H. Kamarudin and M. I. N. Isa, Int. J. Phys. Sci., 8, 1581 (2013).
M. S. A. Rani, S. Rudhziah, A. Ahmad, and N. S. Mohamed, Polymers, 6, 2371 (2014).
M. H. Buraidah, L. P. Teo, S. R. Majid, and A. K. Arof, Physica B, 404, 1373 (2009).
M. R. Johan, S. O. Hooi, S. Ibrahim, S. M. M. Yassin, and H. T. Yin, Solid State Ion, 196, 41 (2011).
A. S. Samsudin, H. M. Lai, and M. I. N. Isa, Electrochim. Acta, 129, 1(2014).
M. N. Hafiza, A. N. A. Bashirah, N. Y. Bakar, and M. I. N. Isa, Int. J. Polym. Anal. Charact., 19, 151 (2014).
S. K. Tripathi, A. Gupta, A. Jain, and M. Kumari, Indian J. Pure Ap. Phy., 51, 358 (2013).
M. I. H. Sohaimy and M. I. N. Isa, Appl. Mech. Mater., 67, 719 (2015).
R. Baskaran, S. Selvasekarapandian, N. Kuwata, J. Kawamura, and T. Hattori, Solid State Ion, 177, 2679 (2006).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Sohaimy, M.I.H., Isa, M.I.N. Effect of ammonium carbonate salt concentration on structural and ionic conductivity of cellulose based solid polymer electrolytes. Fibers Polym 16, 1031–1034 (2015). https://doi.org/10.1007/s12221-015-1031-8
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12221-015-1031-8