Abstract
In this paper, we report the modification of polyamide sample (PA) with different contents of chitosan (CS) using citric acid (CA) as a cross-linker [PA-CA-CS]. New materials were confirmed to be formed in PA using FT-IR spectrum. It is also checked in terms of the change in thermal stability event and decomposition behavior in thermogravimetry through TG-DTA instruments. Then, the ability of unmodified and modified supports was tested for the adsorption of two reactive dyes i.e. Cibacron Brilliant Yellow 3G-P and Cibacron Blue P-3R. Sorption experiments were performed under varying several experimental conditions such as pH, contact time, initial dye concentration, and temperature. The isotherm and kinetic models were undertaken to assess the dye removal mechanism. The applicability of Langmuir, Freundlich, Dubinin-Radushkevich, and Temkin equations was checked and data were fitted using Langmuir model. The second-order equation was shown to fit the adsorption kinetics. Data gleaned from both thermodynamic results and modeling data indicate that the adsorption follows a chemical and exothermic process.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
A. Mittal, D. Kaur, and J. Mittal, J. Colloid Interf. Sci., 326, 8 (2008).
M. Rinaudo, Prog. Polym. Sci., 31, 603 (2006).
R. Jayakumar, M. Prabaharan, R. L. Reis, and J. F. Mano, Carbohyd. Polym., 62, 142 (2005).
N. Sakkayawong, P. Thiravetyan, and W. Nakbanpote, J. Colloid Interf. Sci., 286, 36 (2005).
G. Annadurai, L. Y. Ling, and J. F. Lee, J. Hazard. Mater., 152, 337 (2008).
W. S. Wan Ngah, L. C. Teong, and M. A. K. M. Hanafiah, Carbohyd. Polym., 83, 1446 (2011).
M. Jabli, M. H. V. Baouab, S. N. Zydowicz, and B. Ben Hassine, J. Appl. Polym. Sci., 123, 3412 (2011).
M. Jabli, R. Touati, Y. Kacem, and B. Ben Hassine, J. Text. Inst., 103, 434 (2012).
C.-M. Shih, Y.-T. Shieh, and Y.-K. Twu, Carbohydr. Polym., 78, 169 (2009).
F. Lidija, R. Tijana, and T. Tina, J. Eng. Fibers Fabr., 7, 50 (2012).
Y. C. Nho and K. R. Park, J. Appl. Polym. Sci., 85, 1787 (2002).
W. S. Wan Ngah, K. Kamari, and Y. J. Koay, Int. J. Biol. Macromol., 34, 155 (2004).
M. Zeng, H. Xiao, X. Zhang, X. Sun, C. Qi, and B. Wang, J. Macromol. Sci., Part B: Phys., 50, 1413 (2011).
J.-T. Yeh, C.-L. Chen, K. S. Huang, Y. H. Nien, J. L. Chen, and P. Z. Huang, J. Appl. Polym. Sci., 101, 885 (2006).
B. G. Min and C. W. Kim, J. Appl. Polym. Sci., 84, 2505 (2002).
Y. Ma, T. Zhou, and C. S. Zhao, Carbohyd. Res., 343, 230 (2008).
C. Makhlouf, M. H. V. Baouab, and S. Roudesli, Adsorpt. Sci. Technol., 26, 433 (2008).
H.-J. Tseng, S.-H. Hsu, M.-W. Wu, T.-H. Hsueh, and P.-C. Tu, Fiber. Polym., 10, 53 (2009).
M. Jabli, M. H. V. Baouab, S. Roudesli, and A. Bartegi, J. Eng. Fibers Fabr., 6, 1 (2011).
M. Jabli, F. Aloui, and B. Ben Hassine, J. Eng. Fibers Fabr., 8, 1 (2013).
S. H. Hsieh, Z. K. Huang, Z. Z. Huang, and Z. S. Tseng, J. Appl. Polym. Sci., 94, 1999 (2004).
Y. Li, Z. M. Huang, and Y. D. Lu, Eur. Polym. J., 42, 1696 (2006).
N. Prakash, P. N. Sudha, and N. G. Renganathan, Environ. Sci. Pollut. Res., 19, 2930 (2012).
J. Junkasem, R. Rujiravanit, and R. P. Supaphol, Nanotechnology, 17, 4519 (2006).
T. Wang, M. Turhan, and S. Gunasekaran, Polym. Int., 53, 911 (2004).
Y. S. Ho and G. McKay, Water Res., 33, 578 (1999).
Y. S. Ho and G. McKay, Process Biochem., 34, 451 (1999).
A. Ornek, M. Ozacar, and A. Sengil, Biochem. Eng. J., 37, 192 (2007).
G. Grini, H. N. Peindy, F. Gimbert, and C. Robert, Sep. Purif. Technol., 53, 97 (2007).
K. K. Panday and V. N. Prasad, Environ. Technol. Lett., 50, 547 (1986).
I. Langmuir, J. Am. Chem. Soc., 40, 1361 (1918).
H. Freundlich, “Colloid and Capillary Chemistry”, p.523, Mateun & Co., Ltd., London, 1926.
A. U. Itodo and H. U. Itodo, Life Sci. J., 7, 31 (2010).
M. Horsfall and A. I. A. A. Abia, Bull. Korean Chem. Soc., 25, 969 (2004).
R. E. Treybal, “Mass Transfer Operations”, 3rd Ed., McGraw Hill, NewYork, 1980.
C. Li, H. Chen, and Z. Li, Proc. Biochem., 39, 541 (2004).
M. T. Ikhlass, Thèse de doctorat en chimie, Université Paris-Est Créteil ICMPE, 2012.
S. Rengaraja, J.-W. Yeon, Y. Kim, Y. Jung, Y.-K. Ha, and W.-H. Kim, J. Hazard. Mater., 143, 469 (2007).
Y. C. Sharma, G. Prasad, and D. C. Rupainwar, Int. J. Environ. Stud., 37, 183 (1991).
A. K. Jain, V. K. Gupta, A. Bhatnagar, and Suhas, J. Hazard. Mater., 101, 31 (2003).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Jabli, M., Hamdaoui, M., Marwa, R. et al. Modified polyamide 66 fibers for the removal of reactive dyes from aqueous suspension. Fibers Polym 15, 1810–1821 (2014). https://doi.org/10.1007/s12221-014-1810-7
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12221-014-1810-7