Abstract
Transesterification of fatty acid using the application of ultrasound stirring and microwave irradiation has been used of late for biodiesel production from various vegetable oil and animal fats. However analysis on influence of these techniques on performance, combustion and emission aspects has received little attention. In this work, transesterification of mustard oil with methanol was performed using ultra sound stirring (42 kHz /170 W, 80 W) and microwave irradiation (230v AC, 50 Hz, 900 W). Reaction time, conversion rate, fuel properties, performance, emission and combustion characteristics were compared with conventional transesetrification. Results indicated that Mustard oil methyl ester subjected to ultrasonication and microwave irradiation (MOMESUM) has 5.71% more yield than conventional transesterification process. It was also observed that BTE for MOMESUM is improved by 5.84% with 5.14% reduction in BSFC when compared to MOME. CO, HC, NOx and Smoke emission was found to decrease by 11.39%, 3.81%, 7.99% and 5.3% respectively for MOMESUM.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
K. G. Georgogianni, M. G. Kontominasa, P. J. Pomonis, D. Avlonitis and V. Gergis, Conventional and in situ transesterification of sunflower seed oil for the production of biodiesel, Fuel Process. Technol., 89 (5) (2008) 503–509.
B. Singh, J. Kaur and K. Singh, Production of biodiesel from used mustard oil and its performance analysis in internal combustion engine, Journal of Energy Resources Technology, 132 (3) (2010) 1–4.
S. L. Dmytryshyn, A. K. Dalai, S. T. Chaudhari, H. K. Mishra and M. J. Reaney, Synthesis and characterization of vegetable oil derived esters: evaluation for their Diesel additive properties, Bioresour Technol., 92 (1) (2004) 55–64.
B. Anjan Kumar Prusty, R. Chandra and P. A. Azeez, Biodiesel: Freedom from dependence on fossil fuels, Nature Proceedings (2008) 1–27.
L. C. Meher, D. V. Sagar and S. N. Naik, Technical aspects of biodiesel production by transesterification -a review, Renew Sustain Energy Rev., 10 (3) (2006) 248–268.
H. Fukuda, A. Kondo and H. Noda, Biodiesel fuel production by transesterification of oils, J. Biosci. Bioeng., 92 (5) (2001) 405–416.
F. Ma and M. A. Hanna, Biodiesel production: a review, Biores. Technol., 70 (1-2) (1999) 1–15.
N. Saifuddin and K. H. Chua, Production of ethyl ester (biodiesel) from used frying oil: optimization of transesterification process using microwave irradiation, Malays J. Chem., 6 (1) (2004) 77–82.
C. Stavarache, M. Vinatoru, R. Nishmura and Y. Maeda, Fatty acids methyl esters from vegetable oil by means of ultrasonic energy, Ultrason. Sonochem., 12 (1) (2005) 367–372.
J. Ji, J. Wang, Y. Li, Y. Yu and Z. Xu, Preparation of biodiesel with the help of ultrasonic and hydrodynamic cavitation, Ultrasonics, 44 (1) (2006) 411–414.
N. Azcan and A. Danisman, Microwave assisted transesterification of rapeseed oil, Fuel, 87 (10) (2008) 1781–1788.
H. Aydin and H. Bayindir, Performance and emission analysis of cottonseed oil methyl ester in a diesel engine, Renewable Energy, 35 (3) (2010) 588–592.
Y. C. Lin, W. J. Lee and H. C. Hou, PAH emissions and energy efficiency of palm biodiesel blends fueled on diesel generator, Atoms Environ, 40 (21) (2006) 3930–3940.
H. Raheman and A. G. Phadatare, Diesel engine emissions from blends of karanja methyl ester and diesel, Biomass Bioenerg., 27 (39) (2004) 393–397.
S. Puhan, N. Vedaraman, G. Sankaranarayanan and B. V. Bharath Ram, Performance and emission study of Maua oil methyl ester in a 4-stroke natural aspirated direct injection diesel engine, Renew Energy, 30 (8) (2005) 1269–1278.
N. Usta, An experimental study on performance and exhaust emissions of a diesel engine fuelled with tobacco seed oil methyl ester, Energ. Convers. Manage, 46 (1) (2005) 2373–2386.
Y. Ullusoy, R. Arslan and C. Kaplan, Emission characteristics of sunflower oil methyl ester, Energ. Source Part A, 31 (11) (2009) 906–910.
M. Alam, J. Song, R. Acharya, A. Boehman and K. Miller, Combustion and emissions performance of low sulfur, ultra sulfur and biodiesel blends in a DI diesel engine, SAE Paper, 2004-01-3024 (2004).
N. SukumarPuhan, G. Saravanan, G. Nagarajan and N. Vedaraman, Effect of biodiesel unsaturated fatty acid on combustion characteristics of a DI compression ignition engine, Biomass and Bioenergy, 34 (8) (2010) 1079–1088.
A. N. Ozsezen, M. Canakci, A. Turkcan and C. Sayin, Performance and combustion characteristics of a DI diesel engine fueled with waste palm oil and conola oil methyl esters, Fuel, 88 (4) (2009) 629–636.
G. Lakshmi Narayana Rao, S. Sampath and K. Rajagopal, Experimental studies on the combustion and emission characteristics of a Diesel engine fuelled with used cooking oil methyl ester and its Diesel blends, World Academy of Science, Engineering and Technology, 37 (2) (2008) 1–7.
H. Hasar, Effects of biodiesel on a low heat loss diesel engine, Renewable Energy, 34 (6) (2009) 1533–37.
M. N. Nabi, M. S. Akhter and M. M. Z. Shahadat, Improvement of engine emissions with conventional diesel fuel and diesel-biodiesel blends, Bioresource Technol., 97 (3) (2006) 372–378.
V. Ganesan, Internal Combustion Engines, Third Ed., Tata McGraw Hill, India (2000).
J. B. Heywood, Internal combustion engine fundamentals, McGraw Hill Book Co., New York (1988).
Author information
Authors and Affiliations
Corresponding author
Additional information
D. Yuvarajan received his B.E degree in Mechanical engineering from Anna University, India in 2006 and M.E degree in Energy Engineering from College of Engineering, Anna University, India in 2009. He is currently an assistant professor in Jeppiaar Institute of Technology, India. He is currently perusing his Ph.D. degree in Anna University, India. His research area includes Performance, Combustion and Emissions characteristics in CI engines and Fuel additives.
M. Venkata Ramanan received his B.E degree in Mechanical engineering from University of Madras, India in 1998 and M. Tech degree in Energy conservation and Management from School of Energy, Tiruchirappalli, India in 2000. He received his Ph.D. in Biomass Gasification at Anna University, India in 2008. He is currently an Assistant Professor (Senior Grade) in Department of Mechanical Engineering, Anna University, India. He is an Energy Audit team member of Anna University, India. He is also a consultant to many industrial houses for energy conservation studies. His research area includes IC engines, gasification and Energy optimization in process utilities.
Rights and permissions
About this article
Cite this article
Yuvarajan, D., Venkata Ramanan, M. Experimental analysis on neat mustard oil methyl ester subjected to ultrasonication and microwave irradiation in four stroke single cylinder Diesel engine. J Mech Sci Technol 30, 437–446 (2016). https://doi.org/10.1007/s12206-015-1248-x
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12206-015-1248-x