Abstract
A series of aqueous polyurethane nanocomposites were prepared using various amounts (0.3-4.6 wt%) of a diol functionalized polyhedral oligomeric silsesquioxane (POSS) by the prepolymer mixing method. N,N-bis(2-hydroxy ethyl-2-amino ethane sulfonic acid sodium salt (BES sodium salt) was used as the anionic internal emulsifier and ionic center. The molecular structure of the samples was characterized by ATR-FTIR spectroscopy. We investigated the effect of the POSS contents on the properties of the specimens by particle size and viscosity measurements, X-ray diffractometry, mechanical behavior assessment, dynamic mechanical thermal analysis (DMTA), thermogravimetric analysis and morphological studies. The results showed that with increasing the POSS contents, particle size, viscosity, tensile strength, modulus, T g , and thermal stability of the synthesized samples were improved. Also, SEM and TEM images indicated that a homogeneous morphology was obtained in the 1.2 wt% POSS-based sample. AFM results showed that the surface roughness increased as the POSS amounts increased.
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References
K. N. Raftopoulos and K. Pielichowski, Prog. Polym. Sci., In Press (2015).
S. W. Kuo and F. C. Chang, Prog. Polym. Sci., 36, 1649 (2011).
D. B. Cordes, P. D. Lickiss and F. Rataboul, Chem. Rev., 110, 2081 (2010).
K. Pielichowski, J. Njuguna, B. Janowski and J. Pielichowski, Adv. Polym. Sci., 201, 225 (2006).
C. Sanchez, G. J. de A. A. Soler-Illia, F. Ribot, T. Lalot, C. R. Mayer and V. Cabuil, Chem. Mater., 13, 3061 (2001).
D. Neumann, M. Fisher, L. Tran and J. G. Matisons, J. Am. Chem. Soc., 124, 13998 (2002).
S. K. Yadav, S. S. Mahapatra, H. J. Ryu, H. J. Yoo and J. W. Cho, React. Funct. Polym., 81, 91 (2014).
A. Fina, D. Tabuani and G. Camino, Eur. Polym. J., 46, 14 (2010).
Y. Feng, Y. Jia, S. Guang and H. Xu, J. Appl. Polym. Sci., 115, 2212 (2010).
E. S. Cozza, O. Monticelli and E. Marsano, Macromol. Mater. Eng., 295, 791 (2010).
L. Ricco, S. Russo, O. Monticelli, A. Bordo and F. Bellucci, Polymer, 46, 6810 (2005).
R. Misra, R. D. Cook and S. E. Morgan, J. Appl. Polym. Sci., 115, 2322 (2010).
P. Iyer, G. Iyer and M. Coleman, J. Membr. Sci., 358, 26 (2010).
Z. Zhang, G. Liang, J. Wang and P. Ren, Polym. Compos., 28, 175 (2007).
S. Y. Soong, R. E. Cohen and M. C. Boyce, Polymer, 48, 1410 (2007).
E. T. Kopesky, G. H. McKinley and R. E. Cohen, Polymer, 47, 299 (2006).
Y. Zhao and D. A. Schiraldi, Polymer, 46, 11640 (2005).
H. Zhang, S. Kulkarni and S. L. Wunder, J. Phys. Chem. B., 111, 3583 (2007).
Z. Wang, S. Leng, Z. Wang, G. Li and H. Yu, Macromolecules, 44, 566 (2011).
Z. Wang, Z. Wang, H. Yu, L. Zhao and J. Qu, RSC Adv., 2, 2759 (2012).
Z. Zhou, N. Yin, Yo. Zhang and Yi. Zhang, J. Appl. Polym. Sci., 107, 825 (2008).
L. Song, S. Xuan, X. Wang and Y. Hu, Thermochim. Acta, 527, 1 (2012).
L. Liu, Y. Hu, L. Song, X. Gu and Z. Ni, Iran. Polym. J., 19, 937 (2010).
R. Jeziorska, B. Swierz-Motysia, A. Szadkowska, B. Marciniec, H. Maciejewski, M. Dutkiewicz and I. Leszczynska, Polimery, 56, 809 (2011).
E. Tegou, V. Bellas, E. Gogolides and P. Argitis, Microelectron. Eng., 73-74, 238 (2004).
M. Fiayyaz, K. M. Zia, M. Zuber, T. Jamil and M. K. Khosa, M. A. Jamal, Korean J. Chem. Eng., 31, 644 (2014).
M. Zuber, K. M. Zia, M. A. Iqbal, Z. T. Cheema, M. Ishaq and T. Jamil, Korean J. Chem. Eng., 32, 184 (2015).
Q. Zhang, X. Huang, X. Wang, X. Jia and K. Xi, Polymer, 55, 1282 (2014).
D. Gnanasekaran and B. S. Reddy, Polym. Int., 63, 507 (2014).
J. P. Lewicki, K. Pielichowski, M. Jancia, E. Hebda, R.L. F. Albo and R. S. Maxwell, Polym. Degrad. Stab., 104, 50 (2014).
D. Przadka, J. Jeczalik, E. Andrzejewska, B. Marciniec, M. Dutkiewicz and M. Szlapka, React. Funct. Polym., 73, 114 (2013).
A. Solouk, M. Solati-Hashjin, S. Najarian, H. Mirzadeh and A. M. Seifalian, Iran. Polym. J., 20, 91 (2011).
B. Janowski and K. Pielichowski, Thermochim. Acta, 478, 51 (2008).
M. Barikani, H. Honarkar and Me. Barikani, Monatsh. Chem., 141, 653 (2010).
F. Mumtaz, M. Zuber, K. M. Zia, T. Jamil and R. Hussain, Korean J. Chem. Eng., 30, 2259 (2013).
M. Sultan, H. N. Bhatti, M. Zuber and M. Barikani, Korean J. Chem. Eng., 30, 488 (2013).
A. K. Nanda, D. A. Wicks, S. A. Madbouly and J. U. Otaigbe, Macromolecules, 39, 7037 (2006).
S. Turri and M. Levi, Mocromol. Rapid Commun., 26, 1233 (2005).
X. Wang, Y. Hu, L. Song, W. Xing, H. Lu, P. Lv and G. Jie, J. Polym. Res., 18, 721 (2011).
K. Lewandowski, L. R. Krepski, D. E. Mickus, R. R. Roberts, S. M. Heilmann, W. K. Larson, M. D. Purgett, S. D. Koecher, S. A. Johnson, D. J. Mcgurran, C. J. Rueb, S. V. Pathre and K. A. M. Thakur, J. Polym. Sci. Part A: Polym. Chem., 40, 3037 (2002).
G. Socrates, Infrared and raman characteristic group frequencies, 3rd Ed., Wiley, London (2004).
H. T. Lee, S. Y. Wu and R. J. Jeng, Colloids Surf., A: Physicochem. Eng. Aspects, 276, 176 (2006).
A. Barni and M. Levi, J. Appl. Polym., Sci., 88, 716 (2003).
B. X. Fu, W. Zhang, B. S. Hsiao, M. Rafailovich, J. Sokolov, G. Johansson, B. B. Sauer, S. Phillips and R. Balnski, High Perform. Polym., 12, 565 (2000).
C. Hepburn, Polyurethane elastomers, Applied Science, England (1982).
L. Zheng, R. J. Farris and E. B. Coughlin, Macromolecules, 34, 8034 (2001).
H. Xu, S. W. Kuo, J. S. Lee and F. C. Chang, Macromolecules, 35, 8788 (2002).
M. G. Lu, J. Y. Lee, M. J. Shim and S. W. Kim, J. Appl. Polym. Sci., 85, 2552 (2002).
N. Grassie and G. Scott, Polymer degradation and stabilisation, Cambridge University, London (1985).
H. Liu and S. Zheng, Macromol. Rapid Commun., 26, 196 (2005).
S. Zhang, Q. Zou and L. Wu, Macromol. Mater. Eng., 291, 895 (2006).
Th. Kourkoutsaki, E. Logakis, I. Kroutilova, L. Matejka, J. Nedbal and P. Pissis, J. Appl. Polym. Sci., 113, 2569 (2009).
W. Zhang, B. X. Fu, Y. Seo, E. Schrag, B. Hsiao, P. T. Mather, N. L. Yang, D. Xu, H. Ade, M. Rafailovich and J. Sokolov, Macromolecules, 35, 8029 (2002).
W. P. Dong, P. J. Sullivan and K. J. Stout, Wear, 178, 29 (1994).
A. Aneja and G. L. Wilkes, Polymer, 44, 7221 (2003).
V. N. Bliznyuk, T. A. Tereshchenko, M. A. Gumenna, Yu P. Gomza, A. V. Shevchuk, N. S. Klimenko and V. V. Shevchenko, Polymer, 49, 2298 (2008).
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Honarkar, H., Barmar, M., Barikani, M. et al. Synthesis and characterization of polyhedral oligomeric silsesquioxane-based waterborne polyurethane nanocomposites. Korean J. Chem. Eng. 33, 319–329 (2016). https://doi.org/10.1007/s11814-015-0102-2
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DOI: https://doi.org/10.1007/s11814-015-0102-2