Abstract
Excessive discharge of dye wastewater has brought serious harm to human health and the environment. In this paper, a magnetic absorbent, ferroferric oxide@β-cyclodextrin (Fe3O4@CD), was prepared for the efficient adsorption removal of basic fuchsin (BF) from dye wastewater, based on the special amphiphilicity of β-CD and the strong magnetism of Fe3O4. A series of influence factors including the initial dye concentration, adsorbent dosage, temperature and pH were investigated, as well as the adsorption mechanism. The results show that Fe3O4@CD has the best adsorption and removal effect on BF dye at room temperature and neutral pH, when the initial concentration of dye is 25 mg/L and the adsorbent dosage is 100 mg. The adsorption behavior conforms to the pseudo-second-order kinetics and the Langmuir adsorption isotherm, and the adsorption process is spontaneously endothermic. Fe3O4@CD adsorbed with BF dye can be rapidly separated under an external magnetic field and then easily regenerated by HCl treatment. After 5 times of recycling, the removal rate of the prepared magnetic composite on BF dye is kept above 75%. This work will provide an economic and eco-friendly technology for the treatment of the actual dye wastewater.
摘要
染料废水的过量排放给人类健康和环境带来了严重危害。本文基于β-CD的两亲性和纳米Fe3O4 的强磁性, 制备了磁性吸附剂Fe3O4@CD应用于染料废水中碱性品红的高效去除。考察了染料初始浓 度, 吸附剂用量, 温度, pH等系列因素对去除效果的影响及其吸附机理。研究表明, 在室温, 中性 pH值下, 当染料初始浓度为25 mg/L, 吸附剂用量为100 mg时, 所制备的Fe3O4@CD对BF的吸附去除 效果最佳; 其吸附行为符合准二级动力学和Langmuir 吸附等温模型, 且为自发吸热过程。Fe3O4@CD 吸附BF后在外加磁场下可快速分离再生, 循环使用5 次后碱性品红染料去除率保持在75%以上。研究 成果有望提供经济环保的实际染料废水处理新技术。
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Project(2017YFC1600306) supported by the National Key R&D Program of China; Project(21505005) supported by the National Natural Science Foundation of China; Project(2018JJ2424) supported by the Hunan Provincial Natural Science Foundation, China; Project(2019IC21) supported by the International Cooperative Project for “Double First-Class”, China
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NING Jing-heng designed the experiments and provided financial supports; CHEN Dong-er and HU Qiong-can performed the experiments; LIU Yong-le, HUANG Shou-en, WEI Jia-qian, WEI Rui and SUN Chang analyzed the data and contributed reagents/materials/analysis tools; NING Jing-heng and CHEN Dong-er wrote the paper; WANG Fa-xiang revised the paper; all authors read and approved the final manuscript.
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NING Jing-heng, CHEN Dong-er, LIU Yong-le, HUANG Shou-en, WANG Fa-xiang, WEI Rui, HU Qiong-can, WEI Jia-qian and SUN Chang declare that they have no conflict of interest.
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Ning, Jh., Chen, De., Liu, Yl. et al. Efficient adsorption removal and adsorption mechanism of basic fuchsin by recyclable Fe3O4@CD magnetic microspheres. J. Cent. South Univ. 28, 3666–3680 (2021). https://doi.org/10.1007/s11771-021-4845-0
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DOI: https://doi.org/10.1007/s11771-021-4845-0