The Co-Zn phase diagram in [Massalski2] was drawn based on several old data published before 1976.

Figure 1 shows the Co-Zn phase diagram calculated by [2004Vas]. The \({\upgamma_{1}, \upgamma_{2}}\), and \({\updelta}\) phases were assumed to be line compounds. ([Massalski2] showed ∼1 at.% solubility ranges for these phases.) New features in this phase diagram unknown in [Massalski2] are the formation of ferromagnetic + paramagnetic (\({\upalpha \hbox{Co}}\)) two-phase field and the (\({\upalpha \hbox{Co}) = (\upvarepsilon \hbox{Co}) + \upbeta_{1}}\) eutectoidal reaction. The locations of these reactions in the phase diagram must be confirmed experimentally.

Fig. 1
figure 1

Co-Zn phase diagram