Abstract
Cycloaddition of CO2 with aziridines is an important reaction to obtain high-value products. Porous MOFs can catalyze this reaction, but co-catalysts are still necessary to improve the catalytic performance. Such a reaction catalyzed by MOFs-based materials without co-catalyst has not been reported hitherto. Herein, a porous and stable three-dimensional (3D) framework {[Ni(DCTP)]·6.5DMF}n (1) with a large Langmuir surface area of 3,789 m2/g was synthesized, which displayed high I2 adsorption ability up to 731.0 mg/g and could release it reversibly. Additionally, it exhibited a high CO2 adsorption capacity of 104.0 cm3/g at 273 K. The investigation results revealed 1 could effectively catalyze the cycloaddition of CO2 and aziridines in the absence of additional co-catalyst, and it could maintain the catalytic activity after five cycles. Furthermore, 1 also exhibited high catalytic activity for the gram-scale experiment. Importantly, it is the first MOF material as a heterogeneous catalyst for the conversion of CO2 and aziridines without co-catalyst.
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Acknowledgements
This work was supported by the Natioanl Natrual Sciencce Foundation of China (21625103, 21971125, 21801183), China Postdoctoral Science Foundation (2019M660978, 2020T130319), and the 111 Project (B12015).
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Shi, Y., Zhao, J., Xu, H. et al. Eco-friendly co-catalyst-free cycloaddition of CO2 and aziridines activated by a porous MOF catalyst. Sci. China Chem. 64, 1316–1322 (2021). https://doi.org/10.1007/s11426-021-1006-9
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DOI: https://doi.org/10.1007/s11426-021-1006-9