Abstract
Deuterium-substituted and 13C-substituted octadecanoic acids were applied to study tribo-chemistry of binary-component Langmuir–Blodgett film deposited on Si(100) surfaces. Time-of-flight secondary ion mass spectroscopy was employed to study structure of the film. The isotopic tracers give typical fragment ions composed of the isotopes. Among these typical fragment ions, we paid attention to quasi-molecular ions and deuterium ion as “fingerprint region” of the film structure. The tribological properties of the binary-component film were evaluated by ball-on-plate type tribo-testers. The combination of octadecanol with octadecanoic acid affords good tribological properties, whereas the combination of octadecylamine with the acid gave poor results. The surface analysis of the plate after the tribo-test revealed that the alcohol and the acid were retained on the track even after the rubbing. On the other hand simultaneous removal of the acid and the amine from the surfaces were observed. Interactions between the acid and the amine were considered by the results of the tribo-tests and the surface analysis of the binary-component film.
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Minami, I., Kubo, T., Fujiwara, S. et al. Investigation of Tribo-chemistry by means of Stable Isotopic Tracers: TOF-SIMS Analysis of Langmuir–Blodgett Films and Examination of their Tribological Properties. Tribol Lett 20, 287–297 (2005). https://doi.org/10.1007/s11249-005-9068-2
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DOI: https://doi.org/10.1007/s11249-005-9068-2