Abstract
This paper provides a short review of recent progress in the design and synthesis of chiral organic–inorganic hybrid solids and their applications in heterogeneous asymmetric catalysis. Homochiral hybrid solids containing catalytic sites can be readily prepared by linking appropriately designed chiral bridging ligands with metal ion or metal cluster nodes. Heterogeneous asymmetric catalysts with enantioselectivity as high as 99.2 and turnover number (TON) as high as 20,000 have been obtained based on these hybrid organic–inorganic solids. The modular nature of the present approach promises to lead to a variety of practically useful heterogeneous asymmetric catalysts for many organic transformations.
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Ngo, H.L., Lin, W. Hybrid organic-inorganic solids for heterogeneous asymmetric catalysis. Top Catal 34, 85–92 (2005). https://doi.org/10.1007/s11244-005-3792-6
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DOI: https://doi.org/10.1007/s11244-005-3792-6