Abstract
A new tetraoxime ligand, (2E, 3E, 9E, 10E)-1, 4, 8, 11-tetraazacyclotetradecane-2, 3, 9, 10-tetrone tetraoxime has been prepared by the template condensation of 1,3-propanediamine and cyanogen-di-N-oxide, obtained by treating (E, E)-dichloroglyoxime in CH2Cl2 with Na2CO3 at −10 °C. The coordination chain polymers {[(pnngH2)2Ni]n (5) and [(pncgH2)2Cu]n(6)} of two transition metal ions, [Ni(II) and Cu(II)] with the vic-dioxime ligand have been prepared. The oxime ligand acts as a polydentate ligand bending through nitrogen atoms in the presence of a base, as do most of the vic-dioximes. In the complexes, the chloride ions coordinate to the nickel and copper ions. The structures of these novel vic-dioxime compounds are proposed on the basis of the elemental analyses, molar conductance data, i.r., and U.v.–visible are presented. Elemental analyses indicate a ligand metal ratio of 1:1 in the coordination polymers. Conductivity measurements have shown that mono- and polynuclear complexes are non-electrolytes. In addition, anti-microbial activities of the compounds have been investigated.
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Kurtoğlu, M., İspir, E., Kurtoğlu, N. et al. New Soluble Coordination Chain Polymers of Nickel(II) and Copper(II) ions and their Biological Activity. Transition Met Chem 30, 765–770 (2005). https://doi.org/10.1007/s11243-005-6273-7
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DOI: https://doi.org/10.1007/s11243-005-6273-7