Abstract
The structures and spectroscopic properties of nickel(II), zinc(II), and copper(II) complexes with dibutyl- and diisobutyldithiocarbamate were studied by EPR and 13C and 15N CP/MAS NMR spectroscopy and X-ray diffraction analysis. According to the EPR data, copper(II) forms mononuclear [63/65Cu{S2CNR2}2] and heterobinuclear complexes [63/65CuZn{S2CNR2}4] under magnetic dilution conditions. The isomeric forms of nickel(II) and zinc(II) diisobutyldithiocarbamates were detected by 13C and 15N NMR spectroscopy. The crystalline zinc(II) diisobutyldithiocarbamate was found to have a unique structural organization with alternating mononuclear [Zn{S2CN(i-C4H9)2}2] and binuclear molecular forms [Zn2{ S2CN(i-C4H9)2}4] in the 1 : 1 ratio.
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REFERENCES
Byr'ko, V.M., Ditiokarbamaty (Dithiocarbamates), Moscow: Nauka, 1984.
Lokaj, J., Garaj, J., Kettmann, V., and Vrabel, V., Collect. Czech. Chem. Commun., 1980, vol. 45, p. 2147.
Bonamico, M., Dessy, G., Mariani, C., et al., Acta Crystallogr., 1965, vol. 19, no.4, p. 619.
Khan, M.N.I., Fackler, J.P., Murray, H.H., and Heinrich, D.D., Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 1987, vol. 43, no.10, p. 1917.
Selvaraju, R., Panchanatheswaran, K., Thiruvalluvar, A., and Parthasarathi, V., Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 1995, vol. 51, no.4, p. 606.
Peyronel, G. and Pignedoli, A., Acta Crystallogr., 1967, vol. 23, no.3, p. 398.
Ivanov, A.V., Ivakhnenko, E.V., Forshling, V., et al., Zh. Neorg. Khim., 2002, vol. 47, no.3, p. 468 [Russ. J. Inorg. Chem. (Engl. Transl.), vol. 47, no. 3, p. 410].
Newman, P.W.G. and White, A.H., J. Chem. Soc., Dalton Trans., 1972, no. 20, p. 2239.
Cox, M.J. and Tiekink, E.R.T., Z. Kristallogr., 1999, vol. 214, no.4, p. 242.
Lokaj, J., Vrabel, V., and Kello, E., Chem. Zvesti, 1984, vol. 38, p. 313.
Raston, C.L. and White, A.H., Aust. J. Chem., 1976, vol. 29, no.3, p. 523.
Ramalingam, K., Radha A., Aravamudan G., et al., Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 1984, vol. 40, no.11, p. 1838.
Newman, P.W.G., Raston, C.L., and White, A.H., J. Chem. Soc., Dalton Trans., 1973, no. 13, p. 1332.
Radha, A., Seshasayee, M., and Aravamudan, G., Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 1988, vol. 44, no.8, p. 1378.
Starikova, Z.A., Shugam, E.A., Agre, V.M., and Oboznenko, Yu.V., Kristallografiya, 1972, vol. 17, no.1, p. 111.
Agre, V.M., Shugam, E.A., and Rukhadze, E.G., Zh. Strukt. Khim., 1966, vol. 7, no.6, p. 897.
Christidis, P.C., Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 1986, vol. 42, no.7, p. 781.
Martin, J.M., Newman, P.W.G., Robinson, B.W., and White, A.H., J. Chem. Soc., Dalton Trans., 1972, no. 20, p. 2233.
Klug, H.P., Acta Crystallogr., 1966, vol. 21, no.4, p. 536.
Ramalingam, K., Bin Shawkataly O., Fun H.-K., and Abdul Razak I, Z. Kristallogr., 1998, vol. 213, no.2, p. 371.
Bonamico, M., Mazzone, G., Vaciago, A., and Zambonelli, L., Acta Crystallogr., 1965, vol. 19, no.6, p. 898.
Bonamico, M., Dessy, G., Mazzone, G., et al., Atti Accad. Naz. Linc. Rend. Cl. Sci. Fis. Mat. Natur., 1963, vol. 35, p. 338.
Zvonkova, Z.V., Khvatkina, A.N., and Ivanova, N.S., Kristallografiya, 1967, vol. 12, no.6, p. 1065.
Sreehari, N., Varghese, B., and Manoharan, P.T., Inorg. Chem., 1990, vol. 29, no.20, p. 4011.
Miyamae, H., Ito, M., and Iwasaki, H., Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem., 1979, vol. 35, no.6, p. 1480.
Ivanov, A.V., Ivakhnenko, E.V., Gerasimenko, A.V., and Forsling, W., Zh. Neorg. Khim., 2003, vol. 48, no.1, p. 52 [Russ. J. Inorg. Chem. (Engl. Transl.), vol. 48, no. 1, p. 45].
Kello, E., Vrabel, V., Kettmann, V., and Garaj, J., Collect. Czech. Chem. Commun., 1983, vol. 48, p. 1272.
Francetic, V. and Leban, I., Vestn. Slov. Kem. Drus., 1979, vol. 26, p. 113.
Agre, V.M. and Shugam, E.A., Zh. Strukt. Khim., 1972, vol. 13, no.4, p. 660.
Motevalli, M., O'Brien, P., Walsh, J.R., and Watson, I.M., Polyhedron, 1996, vol. 15, no.16, p. 2801.
Cox, M.J. and Tiekink, E.R.T., Z. Kristallogr., 1999, vol. 214, no.3, p. 184.
Pines, A., Gibby, M.G., and Waugh, J.S., J. Chem. Phys., 1972, vol. 56, no.4, p. 1776.
Earl, W.L. and VanderHart, D.L., J. Magn. Reson., 1982, vol. 48, no.1, p. 35.
Ratcliffe, C.I., Ripmeester, J.A., and Tse, J.S., Chem. Phys. Lett., 1983, vol. 99, no.2, p. 177.
Mason, J., Encyclopedia of Nuclear Magnetic Resonance, Grant, D.M. and Harris, R.K.N.Y., Eds., New York: Wiley, 1966, vol. 5, p. 3222.
Flack, H.D., Acta Crystallogr., Sect. A: Found. Crystallogr., 1983, vol. 39, no.6, p. 876.
SMART and SAINT-Plus. Versions 5.0. Data Collection and Processing Software for the SMART System. Bruker AXS Inc., Madison, WI, USA, 1998.
SHELXTL/PC. Versions 5.10. An Integrated System for Solving, Refining and Displaying Crystal Structures From Diffraction Data. Bruker AXS Inc., Madison, WI, USA, 1998.
Ovchinnikov, I.V. and Konstantinov, V.N., J. Magn. Reson., 1978, vol. 32, p. 179.
Rieger, Ph.H., Electron Spin Resonance (Senior Reporter Symons M.C.R.), vol. 13, 1993, p. 178.
Bonamico, M., Dessy, G., Mugnoli, A., et al., Acta Crystallogr., 1965, vol. 19, no.6, p. 886.
O'Connor, B.H. and Maslen, E.N., Acta Crystallogr., 1966, vol. 21, no.5, p. 828.
Boyd, P.D.W., Mitra, S., Raston, C.L., et al., J. Chem. Soc., Dalton Trans., 1981, no. 1, p. 13.
Einstein, F.W.B. and Field, J.S., Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem., 1974, vol. 30, no.12, p. 2928.
Solozhenkin, P.M., Ivanov, A.V., Mukhammad Zafar Khamkar, and Klyashtornyi, V.B, Zh. Neorg. Khim., 1987, vol. 32, no.11, p. 2711.
Ivanov, A.V. and Solozhenkin, P.M., Zh. Neorg. Khim., 1990, vol. 35, no.6, p. 1537.
Ivanov, A.V., Solozhenkin, P.M., and Mukhammad Zafar Khamkar, Koord. Khim., 1988, vol. 14, no.6, p. 754.
Ivanov, A.V., Solozhenkin, P.M., and Mukhammad Zafar Khamkar, Dokl. Akad. Nauk SSSR, 1987, vol. 297, no.4, p. 878.
Ivanov, A.V., Koord. Khim., 1991, vol. 17, no.3, p. 382.
Ivanov, A.V. and Solozhenkin, P.M., Dokl. Akad. Nauk SSSR, 1990, vol. 311, no.2, p. 392.
Ivanov, A.V., Mitrofanova, V.I., and Rodina, T.A., Zh. Neorg. Khim., 1997, vol. 42, no.4, p. 644 [Russ. J. Inorg. Chem. (Engl. Transl.), vol. 42, no. 4, p. 570].
Ivanov, A.V., Rodyna, T., and Antzutkin, O.N., Polyhedron, 1998, vol. 17, no.18, p. 3101.
Bondi, A., J. Phys. Chem., 1964, vol. 68, no.2, p. 414.
Addison, A.W., Rao, T.N., Reedijk, J., et al., J. Chem. Soc., Dalton Trans., 1984, p. 1349.
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Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 10, 2005, pp. 733–745.
Original Russian Text Copyright © 2005 by Ivanov, Korneeva, Gerasimenko, Forsling.
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Ivanov, A.V., Korneeva, E.V., Gerasimenko, A.V. et al. Structural Organization of Nickel(II), Zinc(II), and Copper(II) Complexes with Diisobutyldithiocarbamate: EPR, 13C and 15N CP/MAS NMR, and X-Ray Diffraction Studies. Russ J Coord Chem 31, 695–707 (2005). https://doi.org/10.1007/s11173-005-0157-4
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DOI: https://doi.org/10.1007/s11173-005-0157-4