Abstract
The specific features of the formation of metal nanoparticles under X-ray radiation in interpolyelectrolyte complex (IPEC) films based on polyacrylic acid and polyethyleneimine with different silver ion content were studied. IPEC films were irradiated in aqueous-alcoholic medium. Electron microscopy demonstrated that the formation of silver nanoparticles occurred in zones regularly located by film thickness. It was found that nanoparticle size and spatial distribution in IPEC films depended on the initial concentration of silver ions within the sample and on the absorbed dose of radiation. The obtained film nanocomposites are promising objects for application as antibacterial and catalytic materials.
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Based on the materials of the XXI Mendeleev Congress on General and Applied Chemistry (September 9–13, 2019, St. Petersburg, Russia).
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. pp. 1731–1739, September, 2020.
This work was financially supported by the Russian Foundation for Basic Research (Project No. 18-03-00608).
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Mkrtchyan, K.V., Zezin, A.A., Zezina, E.A. et al. Formation of metal nanostructures under X-ray radiation in films of interpolyelectrolyte complexes with different silver ion content. Russ Chem Bull 69, 1731–1739 (2020). https://doi.org/10.1007/s11172-020-2956-7
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DOI: https://doi.org/10.1007/s11172-020-2956-7