Abstract
A technique for the synthesis of bismuth orthoferrite nanopowder doped with cobalt ions activated using microwave radiation is proposed. Exposure to microwave radiation followed by ultrasonic treatment of the synthesized BiFeO3 samples using sodium hydroxide as a precipitant makes it possible to obtain spherical BiCoxFe1-xO3 particles with a narrow particle-size distribution in the range of 35–60 nm. Bismuth ferrite doped with cobalt ions has a considerably higher magnetization and magnetic susceptibility than an undoped BiFeO3.
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The research results were partially obtained on the equipment of The Collective Use Center of Voronezh State University; URL: http://ckp.vsu.ru.
This work was financially supported by the Russian Foundation for Basic Research (Project No. 18-03-00354a).
Based on the materials of the XXI Mendeleev Congress on General and Applied Chemistry (September 9–13, 2019, St. Petersburg, Russia).
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 0941–0946, May, 2020.
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Tomina, E.V., Perov, N.S., Mittova, I.Y. et al. Microwave synthesis and magnetic properties of bismuth ferrite nanopowder doped with cobalt. Russ Chem Bull 69, 941–946 (2020). https://doi.org/10.1007/s11172-020-2852-1
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DOI: https://doi.org/10.1007/s11172-020-2852-1