Abstract
Cobalt(iii) complexes with different 4,6-di-tert-butyl-N-(aryl)-o-iminobenzosemiquinone ligands were synthesized. Four-, five-, or six-coordinate cobalt(iii) derivatives can be prepared using various starting metal compounds (CoCl2•6H2O, (acac)2Co•2H2O) and varying substituents in the N-aryl moiety of the organic ligand. The structures of five synthesized compounds were determined by X-ray diffraction. The electronic and spin states of the five-coordinate cobalt(iii) complexes were studied in detail by DFT quantum chemical calculations.
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Based on the materials of the Russian National Cluster of Conferences on Inorganic Chemistry “Inorg Chem-2018” (September 17–21, 2018, Astrakhan, Russia).
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0757–0769, April, 2019.
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Piskunov, A.V., Pashanova, K.I., Ershova, I.V. et al. Synthesis of four-, five-, and six-coordinate cobalt(iii) bis-o-iminobenzosemiquinone complexes. Russ Chem Bull 68, 757–769 (2019). https://doi.org/10.1007/s11172-019-2483-6
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DOI: https://doi.org/10.1007/s11172-019-2483-6