Abstract
A computer search for new photoactive compounds among indoline spiropyrans of coumarin series was carried out using DFT B3LYP/6-31G(d,p) method. Based on the data obtained, the spiropyrans containing a formylcoumarin fragment annulated to the 2H-pyran ring and possessing photochromic properties were synthesized. The structure and photochromism of these compounds were studied by 1H NMR, IR, and UV/Vis spectroscopy. The introduction of a formyl group into the coumarin moiety of spiropyrans led to a bathochromic shift of the long wavelength absorption maxima of merocyanine isomers, as well as to a considerable increase in their lifetime.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0944—0951, April, 2016.
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Nikolaeva, O.G., Metelitsa, A.V., Cheprasov, A.S. et al. Synthesis and studies of new photochromic spiropyrans containing a formylcoumarin fragment. Russ Chem Bull 65, 944–951 (2016). https://doi.org/10.1007/s11172-016-1396-x
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DOI: https://doi.org/10.1007/s11172-016-1396-x