Abstract
The effect of additives of copper azomethine complexes of different structure on the character of polycondensation and physicomechanical properties of the obtained metal-containing epoxy polymers was studied. It was shown by the DSC method that the thermal stability of the starting CuII azomethine complexes depended on their structure and nature of polar functional groups. The physicomechanical properties of the unmodified and modified epoxyamine polymers at different ratios of functional groups were compared. The additives of CuII azomethine complexes of 0.42–0.43 wt.% were shown to increase the impact strength of the polymers at the ratio [NH]/EG = 1.07–1.13 (EG is epoxy group).
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
A. D. Pomogailo, S. Singh, M. Singh, B. C. Yadav, P. Tandon, S. I. Pomogailo, G. I. Dzhardimalieva, K. A. Kydralieva, Inorg. Mater. (Engl. Transl.), 2014, 50, 296 [Neorg. Mater., 2014, 50, 320].
J. B. Beck, S. J. Rowan, J. Am. Chem. Soc., 2003, 125, 13922.
Q. G. Meng, P. Boutinaud, H. J. Zhang, R. Mahiou, J. Lumin., 2007, 124, 15.
S. Selvakumar, R. S. M. Kumar, K. Rajarajan, J. A. A. Pragasam, S. A. Rajasekar, K. Thamizharasan, P. Sagayaraj, Cryst. Growth. Des., 2006, 6, 2607.
M. E. Kosal, J. N. Chou, S. R. Wilson, K. S. Suslik, Nat. Mater., 2002, 1, 118.
K. L. Mulfort, J. T. Hupp, J. Am. Chem. Soc., 2007, 129, 9604.
T. K. Maji, R. Matsuda, S. Kitagawa, Nat. Mater., 2007, 6, 142.
B. Xing, M. F. Choi, B. Xu, Chem. Eur. J., 2002, 8, 5028.
A. D. Pomogailo, A. S. Rozenberg, I. E. Uflyand, Nanochastitsy metallov v polimerakh [Metal Nanoparticles in Polymers], Khimiya, Moscow, 2000 (in Russian).
D. Wohrle, A. D. Pomogailo, Metal Complexes and Metals in Macromolecules, Wiley-VCH, Weinheim, 2003.
Y. Savelyev, in New Smart Materials via Metal Mediated Macromolecular Engineering, Eds E. Khosravi, Y. Yagci, Y. Savelyev, Springer Science + Business Media B.V., Dordrecht, 2009, p. 375–391.
M. Islam, P. Mondal, S. Mukherjee, M. Mobarak, A. Sigha Roy, S. Mondal, S. Sarkar, J. Chem. Technol. Biotechnol., 2010, 85, 460.
K. C. Gupta, A. K. Sutar, C. C. Lin, Coord. Chem. Rev., 2009, 253, 1926.
S. M. Islam, A. S. Roy, P. Mondal, M. Mobarok, B. Roy, N. Salam, S. Paul, S. Mondal, Monatsh. Chem., 2012, 143, 815.
C. Demetgül, A. Delikanlý, O. Y. Sarýbýyýk, M. Karakaplan, S. Serin, Designed Monomers and Polymers, 2012, 15, 75.
N. Nishat, S. Ahmad, T. Ahamad, J. Appl. Polym. Sci., 2006, 101, 1347.
T. Ahamad, N. Nishat, J. Appl. Polym. Sci., 2008, 107, 2280.
A. M. Atta, N. O. Shaker, N. E. Maysour, Prog. Org. Coat., 2006, 56, 100.
T. Ahamad, S. M. Alshehri, J. Coat. Technol. Res., 2012, 9, 515.
A. S. Burlov, V. N. Ikorskii, S. A. Nikolaevskii, Yu. V. Koshchienko, V. G. Vlasenko, Ya. V. Zubavichus, A. I. Uraev, I. S. Vasil´chenko, D. A. Garnovskii, G. S. Borodkin, A. D. Garnovskii, Russ. J. Inorg. Chem. (Engl. Transl.), 2008, 53, 1566 [Zh. Neorg. Khim., 2008, 53, 1677].
A. D. Garnovskii, I. S. Vasil´chenko, D. A. Garnovskii, A. S. Burlov, A. I. Uraev, Ros. Khim. Zh. (Zh. Ros. Khim. o-va im. D. I. Mendeleeva) [Russian Chemical J. (Journal of D. I. Mendeleev Russ. Chem. Soc.], 2009, 53, 100 (in Russian).
S. A. Nikolaevskii, A. S. Burlov, A. S. Bogomyakov, V. G. Vlasenko, A. D. Garnovskii, A. G. Starikov, Ya. V. Zubavichus, I. S. Vasil´chenko, S. I. Levchenkov, A. I. Uraev, Russ. J. Gen. Chem. (Engl. Transl.), 2012, 82, 1770 [Zh. Obshch. Khim., 2012, 82, 1778].
A. S. Burlov, V. G. Vlasenko, Ya. V. Zubavichus, S. I. Levchenkov, Yu. V. Koshchienko, A. S. Bogomyakov, S. A. Nikolaevskii, D. A. Garnovskii, A. I. Uraev, T. V. Lifintseva, E. V. Korshunova, Russ. J. Coord. Chem. (Engl. Transl.), 2013, 39, 219 [Koord. Khim., 2013, 39, 238].
A. D. Pomogailo, A. S. Burlov, N. D. Golubeva, L. A. Petrova, S. A. Mashchenko, S. I. Pomogailo, G. I. Dzhardimalieva, A. D. Garnovskii, Inorg. Mater. (Engl. Transl.), 2011, 47, 876 [Neorg. Mater., 2011, 47, 969].
A. D. Pomogailo, G. I. Dzhardimalieva, Nanostructured Materials Preparation via Condensation Ways, Springer, Dodrecht—Heidelberg—New York—London, 2014, 460 pp.
A. D. Pomogailo, A. S. Rozenberg, G. I. Dzhardimalieva, Russ. Chem. Rev., 2011, 80, 257.
A. V. Kulichenko, V. P. Kurbatov, E. S. Kukharicheva, O. A. Osipov, J. Gen. Chem. USSR (Engl. Transl.), 1985, 55, 688 [Zh. Obshch. Khim., 1985, 55, 688].
T. V. Torgova, O. A. Osipov, V. P. Kurbatov, N. A. Belonog, J. Gen. Chem. USSR (Engl. Transl.), 1977, 47, 896 [Zh. Obshch. Khim., 1977, 47, 896].
Z. Arnold, Coll. Czech. Chem. Commun., 1961, 26, 3051.
B. A. Rozenberg, Macromol. Chem. Macromol. Symp., 1991, 41, 165.
Author information
Authors and Affiliations
Corresponding author
Additional information
For Part 73, see Ref. 1.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0936–0942, April, 2015.
Rights and permissions
About this article
Cite this article
Komarov, B.A., Kapasharov, A.T., Dzhavadyan, E.A. et al. Synthesis and reactivity of metal-containing monomers. Russ Chem Bull 64, 936–942 (2015). https://doi.org/10.1007/s11172-015-0958-7
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11172-015-0958-7