Abstract
Based on the experimental results and the published data, the enthalpies of formation of ethane and propane nitro derivatives were obtained for both the standard state and gas phase. The bond dissociation energies of the ethane and propane nitro derivatives were calculated using the enthalpies of atomization and the energies of nonvalent interactions of nitro groups. The calculated values were compared with the kinetic data on thermal decomposition. The bond dissociation energies in radicals of the ethane and propane nitro derivatives were also calculated using the enthalpies of atomization and the energies of nonvalent interactions of nitro groups. Regularities of changes in the bond dissociation energies of the ethane and propane nitro derivatives and their radicals were established.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
E. A. Miroshnichenko, T. S. Kon’kova, Ya. O. Inozemtsev, V. P. Vorobéva, Yu. N. Matyushin, S. A. Shevelev, Izv. Akad. Nauk, Ser. Khim., 2009, 755 [Russ. Chem. Bull., Int. Ed., 2009, 58, 772].
G. B. Manelis, G. M. Nazin, Yu. I. Rubtsov, V. A. Strunin, Termicheskoe razlozhenie i gorenie vzryvchatykh veshchestv i porokhov [Thermal Decomposition and Burning of Explosives and Powders], Nauka, Moscow, 1996, 223 pp. (in Russian).
E. A. Miroshnichenko, V. P. Vorobéva, Zh. Fiz. Khim., 1999, 73, 419 [Russ. J. Phys. Chem. A (Engl. Transl.), 1999, 73, 349].
RF Pat. 2334961, Byul. Izobret. [Invention Bulletin], 2008, 27 (in Russian).
Yu. A. Lebedev, E. A. Miroshnichenko, Termokhimiya paroobrazovaniya organicheskikh veshchestv [Thermochemistry of Vapor Formation of Organic Substances], Nauka, Moscow, 1981, 216 pp. (in Russian).
E. A. Miroshnichenko, T. S. Kon’kova, Ya. O. Inozemtsev, V. P. Vorob’eva, Yu. N. Matyushin, Khim. Fiz., 2008, 27, 829 [Russ. J. Phys. Chem. B (Engl. Transl.), 2008, 2, 595].
NIST-JANAF Thermochemical Tables, J. Phys. Chem. Ref. Data, Ed. M. W. Chase, Jr., 1998, 9.
Yu. A. Lebedev, E. A. Miroshnichenko, Yu. K. Knobel, Termokhimiya nitrosoedineniy [Thermochemistry of Nitro Compounds], Nauka, Moscow, 1970, 168 pp. (in Russian).
K. Baum, D. Tzeng, J. Org. Chem., 1985, 50, 2736.
Yu. D. Orlov, Yu. A. Lebedev, I. Sh. Sayfullin, Termokhimiya organicheskikh radicalov [Thermochemistry of Organic Radicals], Nauka, Moscow, 2001, 304 p. (in Russian).
J. Pedley, R. Nailor, C. Kirby, Thermochemical Data of Organic Compounds, Chapman and Hall, London-New York, 1986, p. 792.
Author information
Authors and Affiliations
Corresponding author
Additional information
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 870–874, May, 2010.
Rights and permissions
About this article
Cite this article
Miroshnichenko, E.A., Kon’kova, T.S., Inozemtsev, Y.O. et al. Bond energies and the enthalpies of formation of mono- and polyradicals in nitroalkanes 2. Nitro derivatives of ethane and propane. Russ Chem Bull 59, 890–895 (2010). https://doi.org/10.1007/s11172-010-0182-4
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11172-010-0182-4