Abstract
The oxidative azidation reactions of C-nitro-substituted saturated heterocyclic compounds, viz., the nitro derivatives of oxetane, azetidine, 1,3-dioxane, tetrahydro-1,3-oxazine, and hexahydropyrimidine, were investigated. A novel representatives of the geminal nitro azides were prepared and their physicochemical properties were studied. The process of the formation of the geminal dinitro compounds upon oxidative azidation was analyzed.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2240–2246, November, 2009.
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Katorov, D.V., Rudakov, G.F. & Zhilin, V.F. Synthesis of heterocyclic geminal nitro azides. Russ Chem Bull 58, 2311–2317 (2009). https://doi.org/10.1007/s11172-009-0323-9
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DOI: https://doi.org/10.1007/s11172-009-0323-9