Abstract
Transition metal complexes (NiII, CoII, and CuII) with tetradentate N2S2-type ligands (L), which are reaction products of 2-thio-substituted benzaldehydes with aromatic amines (3-aminopyridine or 2-aminothiophenol), were synthesized for the first time. The complexes have the composition L·MX2 or L·2MX2 (X = Cl or ClO4). The electrochemical behavior of the ligands and complexes was studied by cyclic voltammetry and rotating disk electrode voltammetry. Depending on the structure of the complexes, the metal atom in the latter is initially reduced in a one-or two-electron process.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2115–2124, November, 2007.
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Beloglazkina, E.K., Shimorsky, A.V., Majouga, A.G. et al. Synthesis and electrochemical characterization of CoII, NiII, and CuII complexes with organic N2S2-type ligands derived from 2-thio-substituted benzaldehydes and aromatic amines. Russ Chem Bull 56, 2189–2199 (2007). https://doi.org/10.1007/s11172-007-0344-1
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DOI: https://doi.org/10.1007/s11172-007-0344-1