Abstract
The formation of MV•+ radical cations was observed upon the laser flash photolysis of the iron(III) tartrate complex [FeIIITart]+ (1) in the presence of methyl viologen (MV2+). The rate constants of the reactions involving MV•+ were measured. The intramolecular electron trans-fer to form FeII and escape of the organic radical to the solvent bulk upon the photolysis of 1 were proposed.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 866–869, May, 2007.
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Feng, W., Nansheng, D., Glebov, E.M. et al. Kinetics and mechanism of photolysis of the iron(III) complex with tartaric acid. Russ Chem Bull 56, 900–903 (2007). https://doi.org/10.1007/s11172-007-0136-7
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DOI: https://doi.org/10.1007/s11172-007-0136-7