Abstract
New styryl dyes containing azadithia-15-crown-5 fragments were synthesized. The complexation of these compounds with Ag+, Pb2+, Cu2+, Hg2+, and H+ cations was studied by 1H NMR spectroscopy, steady-state, and time-resolved spectroscopy. The stability constants of the complexes were calculated from the spectrophotometric titration data. The photophysical properties and E—Z photoisomerization of styryl dyes and their complexes with mercury and copper(II) cations in acetonitrile were examined.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 495–507, March, 2007.
Centre de Physique Moléculaire Optique et Hertzienne-UMR CNRS 5798, Bordeaux University I, 351 Cours de la Libération, 33405 Talence, France.
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Tulyakova, E.V., Fedorova, O.A., Fedorov, Y.V. et al. Synthesis, complexation, and E—Z photoisomerization of azadithiacrown-containing styryl dyes as new optical sensors for mercury cations. Russ Chem Bull 56, 513–526 (2007). https://doi.org/10.1007/s11172-007-0082-4
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DOI: https://doi.org/10.1007/s11172-007-0082-4