Abstract
A procedure for the photochemical chlorination of nanodiamond by molecular chlorine in the liquid phase was proposed. This process was studied quantitatively for the first time. Hydrolytic stability of the chlorinated nanodiamond surface in air and in a 0.05 M solution of NaOH was determined. A possibility of disintegration of the initial aggregates (<60 µm) to finer aggregates (<200 nm) was shown. The reactions of a series of C-nucleophiles (organolithium reagents, CN− ion) with the chlorinated surface were carried out.
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G. V. Lisichkin, A. Yu. Fadeev, A. A. Serdan, P. N. Nesterenko, P. G. Mingalev, and D. B. Furman, Khimiya privitykh poverkhnostnykh soedinenii [Chemistry of Grafted Surface Compounds], Fizmatlit, Moscow, 2003, 592 pp. (in Russian).
Y. Liu, Z. Gu, J. L. Margrave, and V. N. Khabashesku, Chem. Mater., 2004, 16, 3924.
Y. Liu, V. N. Khabashesku, and N. M. Halas, J. Am. Chem. Soc., 2005, 127, 3712.
T. Saito, Y. Ikeda, and S. Egawa, J. Chem. Soc., Faraday Trans. 1, 1998, 94, 929.
T. V. Talalaeva and K. A. Kocheshkov, in Metody elemento-organicheskoi khimii. Litii, natrii, kalii, rubidii, tsezii [Methods of Organoelement Chemistry. Lithium, Sodium, Potassium, Rubidium, Cesium], Ed. A. N. Nesmeyanov and K. A. Kocheshkov, Nauka, Moscow, 1971, Books 1-2, 1192 pp.
L. J. Bellami, The Infra-Red Spectra of Complex Molecules, Methuen and Co, Ltd., J. Wiley and Sons, Inc., London–New York, 1960, 462 pp.
E. Pretsch, P. Buhlmann, and C. Affolter, Structure Determination of Organic Compounds. Tables of Spectral Data, Springer, Berlin-Heiderberg, 2000, 421 pp.
I. I. Kulakova, B. N. Tarasevich, A. P. Rudenko, N. Dorzhpalamyn, and T. M. Gubarevich, Vestn. Mosk. Gos. Univ., Ser. 2. Khim., 1993, 34, 506 [Vestn. Mosk. Univ., Ser. Khim., 1993 (Engl. Transl.)].
T. Jiang and K. Xu, Carbon, 1995, 33, 1663.
T. Tsubota, S. Tanii, S. Ida, M. Nagata, and Y. Matsumoto, Diamond and Related Materials, 2004, 13, 1093.
Y. Ikeda, T. Saito, and K. Kusakabe, Diamond and Related Materials, 1998, 7, 830.
E. P. Smirnov and S. K. Gordeev, Almazy: poluchenie, svoistva, primenenie [Diamonds: Preparation, Properties, Application], Len. Tekhn. Inst. im. Lensoveta, Leningrad, 1984, 73 pp. (in Russian).
H. Becker, W. Berger, G. Domschke, E. Fanghänel, J. Faust, M. Fischer, F. Gentz, K. Gewald, R. Gluch, R. Mayer, K. Müller, D. Pavel, H. Schmidt, K. Schollberg, K. Schwetlick, E. Seiler, and G. Zeppenfeld, Organikum, Veb Deutscher Verlag Wissenschaften, Berlin, 1976.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2130–2137, December, 2006.
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Lisichkin, G.V., Korol’kov, V.V., Tarasevich, B.N. et al. Photochemical chlorination of nanodiamond and interaction of its modified surface with C-nucleophiles. Russ Chem Bull 55, 2212–2219 (2006). https://doi.org/10.1007/s11172-006-0574-7
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DOI: https://doi.org/10.1007/s11172-006-0574-7