Abstract
The first representative of chiral P-monodentate phosphite ligands containing quaternary ammonium substituents and its rhodium complex [Rh(COD)(L)2]BF4 (COD is 1,5-cycloctadiene) were obtained. The use of this ligand in Rh-catalyzed asymmetric hydrogenation of prochiral methyl esters of unsaturated acids allowed one to achieve optical yields up to 99%.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1395–1398, August, 2006.
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Lyubimov, S.E., Davankov, V.A., Valetskii, P.M. et al. First chiral phosphite with a quaternary ammonium fragment: Synthesis and use in Rh-catalyzed asymmetric hydrogenation. Russ Chem Bull 55, 1448–1451 (2006). https://doi.org/10.1007/s11172-006-0438-1
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DOI: https://doi.org/10.1007/s11172-006-0438-1