Abstract
Mixed complexes of the type: Zn(Hsal)2(2-MeHim)2, Zn(Han)2(2-MeHim)2, Cd(Hsal)2(2-MeHim)2, Cd(Han)2(2-MeHim)2, where Hsal=OHC6H4COO−, Han=NH2C6H4COO−, 2-MeHim=2-methylimidazol) have been synthesized and characterized by IR spectroscopic and X-ray diffraction studies. Single-crystal X-ray structure of Cd(Hsal)2(2-MeHim)2 has been obtained. Thermal behaviour of the compounds was investigated by thermal analysis (TG, DTG, DTA). A coupled TG-MS system was used to analyse the principal volatile products of complexes. Thermal decomposition pathways have been postulated.
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Olczak-Kobza, M., Mrozek, A. Zinc(II) and cadmium(II) complexes with o-hydroxybenzoic acid or o-aminobenzoic acid and 2-methylimidazole. J Therm Anal Calorim 96, 553–560 (2009). https://doi.org/10.1007/s10973-008-9048-5
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DOI: https://doi.org/10.1007/s10973-008-9048-5