Abstract
The crystal structure of a manganese(II) 1-allylimidazole complex ([Mn(1-AIm)3(NO3)2], where 1-Aim=1-allylimidazole), was characterized by X-ray diffraction (XRD) using SHELX-97. The thermal behaviour of the complex was investigated by thermogravimetry (TG) coupled with an FTIR unit. The complex showed a multi-step decomposition related to the release of the ligand molecules, followed by oxidation. The final residue at 1073 K was found to be manganese(II) oxide. Evolved gas analysis allowed to prove the oxidative decomposition pattern of the examined complex, initially proposed by the percentage mass loss data. Finally, a kinetic analysis of the oxidative decomposition steps was made using the Kissinger equation, while the complex nature of the decomposition kinetics was revealed by the isoconversional Ozawa-Flynn-Wall method.
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References
V. I. Kalmykov and V. A. Ivanov, Zh. Prikl. Khim., 52 (1979) 889
K. Kurdziel and T. J. Glowiak, Coord. Chem., 55 (2002) 327.
W. Ferenc, B. Bocian and J. Sarzynski, J. Therm. Anal. Cal., 84 (2006) 377.
Q. Yang, S. Chen and S. Gao, J. Therm. Anal. Cal., 89 (2007) 567.
R. Olar, M. Badea, E. Cristurean, C. Parnau and D. Marinescu, J. Therm. Anal. Cal., 84 (2006) 53.
V. Logvinenko, D. Dybtsev, V. Fedin, V. Drebushchak and M. Yutkin, J. Therm. Anal. Cal., 90 (2007) 463.
D. Das, B. G. Chand, J. S. Wu, T.-H. Lu and C. Sinha, J. Mol. Struct., 842 (2007) 17.
G. Mago, M. Hinago, H. Miyasaka, N. Matsumoto and H. Okawa, Inorg. Chem. Acta, 254 (1997) 145.
O. Z. Yesilel, H. Olmez and H. Icbudak, J. Therm. Anal. Cal., 89 (2007) 555.
P. Naumov, G. Jovanovski and A. Todorovska, J. Mol. Struct., 563–564 (2001) 341.
K. Kurdziel, T. Glowiak, S. Materazzi and J. Jezierska, Polyhedron, 22 (2003) 3123.
M. Olczak-Kobza, R. Czylkowski and J. Karolak-Wojciechowska, J. Therm. Anal. Cal., 74 (2003) 895.
W. Wolodkiewicz, J. Therm. Anal. Cal., 68 (2002) 141.
S. Materazzi, S. Aquili, S. De Angelis Curtis, S. Vecchio, K. Kurdziel and F. Sagone, Thermochim. Acta, 421 (2004) 19.
S. Vecchio, S. Materazzi and K. Kurdziel, Int. J. Chem. Kin., 37 (2005) 667.
S. Materazzi, S. Aquili, S. Vecchio and K. Kurdziel, Thermochim. Acta, 457 (2007) 7.
G. M. Sheldrick, SHELXS 97, Program for Solution of Crystal Structure, University of Göttingen, Germany, 1997.
G. M. Sheldrick, SHELXL 97, Program for Refinement of Crystal Structure, University of Göttingen, Germany, 1997.
X. Gao, D. Chen and D. Dollimore, Thermochim. Acta, 223 (1993) 75.
S. Vyazovkin and C. A. Wight, Ann. Rev. Phys. Chem., 48 (1997) 119.
A. K. Galwey and M. E. Brown, Thermal Decomposition of Ionic Solids, Elsevier, Amsterdam, 1999.
H. E. Kissinger, Anal. Chem., 29 (1957) 1702.
J. H. Flynn and L. A. Wall, J. Polym. Sci. B: Polym. Lett., 4 (1966) 323.
T. Ozawa, Bull. Chem. Soc. Jpn., 38 (1965) 1881.
C. D. Doyle, J. Appl. Polym. Sci., 6 (1962) 639.
K. Kurdziel and T. Głowiak, J. Mol. Struct., 516 (2000) 1.
A. F. Cameron, D. W. Taylor and R. H. Nuttal, J. Chem. Soc. Dalton Trans., (1972) 1603.
S. Materazzi, K. Kurdziel, U. Tentolini, A. Bacaloni and S. Aquili, Thermochim. Acta, 395 (2003) 133.
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De Angelis Curtis, S., Kurdziel, K., Materazzi, S. et al. Crystal structure and thermoanalytical study of a manganese(II) complex with 1-allylimidazole. J Therm Anal Calorim 92, 109–114 (2008). https://doi.org/10.1007/s10973-007-8747-7
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DOI: https://doi.org/10.1007/s10973-007-8747-7