Abstract
Solid solution phases of a formula Fe8V10W16–xMoxO85 where 0≤x≤4, have been obtained, possessing a structure of the compound Fe8V10W16O85. It was found on the base of XRD and DTA investigations that these solution phases melted incongruently, with increasing the value of x, in the temperature range from 1108 (x=0) to 1083 K (x=4) depositing Fe2WO6 and WO3. The increase of the Mo6+ ions content in the crystal lattice of Fe8V10W16O85 causes the lattice parameters a=b contraction with cbeing almost constant. IR spectra of the Fe8V10W16–xMoxO85 solid solution phases have been recorded.
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Tabero, P. Formation and properties of the Fe8V10W16–xMoxO85 type solid solution. J Therm Anal Calorim 88, 37–41 (2007). https://doi.org/10.1007/s10973-006-8047-7
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DOI: https://doi.org/10.1007/s10973-006-8047-7