Abstract
Hybrid organic-inorganic materials, silica – polyols (ethylene-glycol – EG; 1,2 propane diol – 1,2PG; 1,3 propane diol – 1,3PG and glycerol – GL), were prepared by a sol-gel process starting from tetraethylorthosilicate (TEOS) and polyols, in acid catalysis. The resulting materials were studied by thermal analysis (in air and nitrogen), FTIR and solid state 29Si-NMR spectroscopy. These techniques evidenced the presence of polyols in the silica matrix both hydrogen bounded and chemically bounded in the silica network. The thermal analysis proves to be the most appropriate technique to evidence the organic chains linked in the matrix network and to follow the thermal evolution of the gels to the SiO2 matrix.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
T Higuchi K Kuramada S Nagamine AW Lothongkum M Tanigaki (2000) J. Mater. Sci. 35 3237 Occurrence Handle10.1023/A:1004811019300 Occurrence Handle1:CAS:528:DC%2BD3cXltFCqtbg%3D
O Shilova EV Tarasyuc VV Shevchenko NS Klimenko TG Movchan SV Hashkovsky VV Shilov (2003) Glass Phys. Chem. 29 378 Occurrence Handle10.1023/A:1025125010618 Occurrence Handle1:CAS:528:DC%2BD3sXmtFGhurk%3D
D Sternik P Staszczuk J Pekalska G Grodzicka B Gawdzik J Ospiuk-Tomasik P Witer (2006) J. Therm. Anal. Cal. 86 85 Occurrence Handle10.1007/s10973-006-7581-7 Occurrence Handle1:CAS:528:DC%2BD28XhtVWnsbnI
NN Khimich (2004) Glass Phys. Chem. 30 430 Occurrence Handle10.1023/B:GPAC.0000045925.84139.eb Occurrence Handle1:CAS:528:DC%2BD2cXovFaltbg%3D
V Castelvetro Cinzia De Vita (2004) Adv. Colloid Interface Sci. 108–109 167 Occurrence Handle10.1016/j.cis.2003.10.017
M Zaharescu A Jitianu A Braileanu J Madarász Cs Novák G Pokol (2003) J. Therm. Anal. Cal. 71 421 Occurrence Handle10.1023/A:1022883221776 Occurrence Handle1:CAS:528:DC%2BD3sXitVygur0%3D
M Zaharescu A Jitianu A Braileanu J Madarász G Pokol (2001) J. Therm. Anal. Cal. 64 689 Occurrence Handle10.1023/A:1011536209930 Occurrence Handle1:CAS:528:DC%2BD3MXkslWlur8%3D
CL Beaudry LC Klein RA McCauley (1996) J. Thermal Anal. 46 55 Occurrence Handle10.1007/BF01979947 Occurrence Handle1:CAS:528:DyaK28Xhs1Wku70%3D
RFS Lenza WL Wasconcelos (2001) Mater. Res. 4 175 Occurrence Handle1:CAS:528:DC%2BD3MXmvV2mtLw%3D
VK Parashar V Raman OP Bahl (1996) J. Mater. Sci. Lett. 15 1403 Occurrence Handle10.1007/BF00275289 Occurrence Handle1:CAS:528:DyaK28Xls1GhsLk%3D
N Uchida N Ishiyama Z Kato K Uematsu (1994) J. Mater. Sci. Lett. 29 5188 Occurrence Handle1:CAS:528:DyaK2cXmtlKrsLo%3D
CP Higginbotham RF Browner JD Jenkins JK Rice (2003) Mater. Lett. 57 3970 Occurrence Handle10.1016/S0167-577X(03)00249-0 Occurrence Handle1:CAS:528:DC%2BD3sXmtVSrurc%3D
M Laridjani E Lafontaine JP Bayyl P Judeinstein (1999) J. Mater. Sci. 34 5945 Occurrence Handle10.1023/A:1004711709642 Occurrence Handle1:CAS:528:DC%2BD3cXlt1Gisw%3D%3D
P Ågren JB Rosenhohn (1998) J. Colloid Interface Sci. 204 45 Occurrence Handle10.1006/jcis.1998.5523
AV Rao MM Kulkarni (2003) Mater. Chem. Phys. 77 819 Occurrence Handle10.1016/S0254-0584(02)00207-9 Occurrence Handle1:CAS:528:DC%2BD38XmvVCgtbk%3D
GM Neves RFS Lenza WL Vasconcelos (2002) Mater. Res. 5 447 Occurrence Handle1:CAS:528:DC%2BD3sXnsV2g
D Ravanie A Seminel Y Charbouillot MA Vincens (1986) J. Non-Cryst. Solids 82 210 Occurrence Handle10.1016/0022-3093(86)90133-X
M. Ştefănescu, M. Stoia and O. Ştefănescu, J. Sol-Gel Sci. Technol., (2006) in press.
M Ştefănescu C Caizer M Stoia O Ştefănescu (2006) Acta Mater. 54 1249 Occurrence Handle10.1016/j.actamat.2005.10.051
M Ştefănescu C Caizer M Stoia O Ştefănescu (2005) J. Optoelectron. Adv. Mater. 7 607
CJ Brinker GV Scherer et al. (1990) Sol-gel Science Academic Press San Diego 501
F Touati N Gharbi H Zarrouk (1997) J. Sol-Gel Sci. Technol. 8 595 Occurrence Handle1:CAS:528:DyaK2sXitlKqt7s%3D
CJ Brinker GV Scherer et al. (1990) Sol-gel Science Academic Press San Diego 552
V Jitchum S Chivin S Wongkasemjit H Ishida (2001) Tetrahedron 57 3997 Occurrence Handle10.1016/S0040-4020(01)00275-7 Occurrence Handle1:CAS:528:DC%2BD3MXjt1Whu7g%3D
RFS Lenza WL Vasconcelos (2003) J. Non-Cryst. Solids 330 216 Occurrence Handle10.1016/j.jnoncrysol.2003.07.001 Occurrence Handle1:CAS:528:DC%2BD3sXos1ansrg%3D
RFS Lenza WL Vasconcelos (2001) Mater. Res. 4 189 Occurrence Handle1:CAS:528:DC%2BD3MXmvV2mtLo%3D
Ch Voulgaris E Amanatide D Mataras DE Rapakoulies (2005) J. Phys.: Conference Series 10 206 Occurrence Handle10.1088/1742-6596/10/1/051 Occurrence Handle1:CAS:528:DC%2BD2MXhtVahsLrM
GM Neves RFS Lenza WL Vasconcelos (2002) Mater. Res. 5 447 Occurrence Handle1:CAS:528:DC%2BD3sXnsV2g
VA Maroni SJ Epperson (2001) Vibr. Sperctrosc. 27 43 Occurrence Handle10.1016/S0924-2031(01)00122-9 Occurrence Handle1:CAS:528:DC%2BD3MXotVantLc%3D
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Ştefănescu, M., Stoia, M., Ştefănescu, O. et al. The interaction between TEOS and some polyols. J Therm Anal Calorim 88, 19–26 (2007). https://doi.org/10.1007/s10973-006-8002-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10973-006-8002-7