Abstract
Thermal decomposition of transition metal malonates, MCH2C2O4⋅xH2O and transition metal succinates, M(CH2)2C2O4⋅xH2O (M=Mn, Fe, Co, Ni, Cu, Zn) has been studied employing TG, DTG, DTA, XRD, SEM, IR and Mössbauer spectroscopic techniques. After dehydration, the anhydrous metal malonates and succinates decompose directly to their respective metal oxides in the temperature ranges 310–400 and 400–525°C, respectively. The oxides obtained have been found to be nanosized. The thermal stability of succinates have been found to be higher than that of the respective malonates.
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References
E. Markowicz, Farben-Ztg., (1928) 34,336,414,503.
K. N. Mehrotra and S. C. Bhargav, Z. Phys. Chem., 237 (1968) 327; Chem. Abst., 69 (1968) 37364.
A-S Malik MJ Duncan PG Bruce (2003) J.Mater.Chem. 13 2123 Occurrence Handle1:CAS:528:DC%2BD3sXmsFWiu74%3D Occurrence Handle10.1039/b303551d
VE Henrich PA Cox et al. (1994) The Surface Science of Metal Oxides Cambridge University Press Cambridge
RC Mehrotra R Bohra et al. (1983) Metal Carboxylates Academic Press New York
D Dollimore DL Griffiths (1970) J. Thermal Anal. 2 229 Occurrence Handle1:CAS:528:DyaE3MXntFWmsQ%3D%3D Occurrence Handle10.1007/BF01911405
AI Vogel et al. (1973) Quantitative Inorganic Analysis, 3rd Ed. Longman Group Ltd. England
K Nakamoto et al. (1970) Infrared Spectra of Inorganic and Coordination Compounds, 2nd Ed. John Wiley Intersci. New York
ASTM Card Number 7-230.
RA Nyguist RO Kagel et al. (1971) Infrared Spectra of Inorganic Compounds Academic Press New York
DA Edwards RN Hayward (1968) Can. J. Chem. 46 3443 Occurrence Handle1:CAS:528:DyaF1MXhs1KqsA%3D%3D Occurrence Handle10.1139/v68-186
ASTM Card Number 13-534.
SS Bellad CD Lokhande CH Bhosale (1997) Indian J. Pure Appl. Phys. 35 565 Occurrence Handle1:CAS:528:DyaK2sXotV2ju7s%3D
BS Randhawa PS Bassi (1983) Radiochem. Radioanal. Letts. 59 171 Occurrence Handle1:CAS:528:DyaL2cXivVymtA%3D%3D
ASTM Card Number 9-402.
JCPDS Card Number 4-0835.
ASTM Card Number 5-0661.
ASTM Card Number 5-0664.
O Carp L Patron G Marinescu G Pascu P Budrugeac (2003) J. Therm. Anal. Cal. 72 263 Occurrence Handle1:CAS:528:DC%2BD3sXktVymtbg%3D Occurrence Handle10.1023/A:1023944425237
BS Randhawa KJ Sweety Manpreet Kaur JM Greneche (2004) J. Therm. Anal. Cal. 75 101 Occurrence Handle1:CAS:528:DC%2BD2cXhsFaisL4%3D Occurrence Handle10.1023/B:JTAN.0000017333.38139.ff
AK Galway MA Mohamed (1985) J. Chem. Soc. Faraday 81 2503 Occurrence Handle10.1039/f19858102503
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Randhawa, B.S., Gandotra, K. A comparative study on the thermal decomposition of some transition metal carboxylates. J Therm Anal Calorim 85, 417–424 (2006). https://doi.org/10.1007/s10973-005-7120-y
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DOI: https://doi.org/10.1007/s10973-005-7120-y