Summary
Reactive milling of Cu-hydroxycarbonate - powder aluminium mixture brings many complex chemical reactions such as decomposition, aluminothermic reduction and mechanical alloying resulting in the formation of nanometer size composites that contain intermetallic phases, γ-Cu9Al4 and θ-CuAl2, with aluminium oxide.
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Wieczorek-Ciurowa, K., Gamrat, K. & Sawłowicz, Z. Characteristics of CuAl2-Cu9Al4/Al2O3 nanocomposites synthesized by mechanical treatment. J Therm Anal Calorim 80, 619–623 (2005). https://doi.org/10.1007/s10973-005-0703-9
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DOI: https://doi.org/10.1007/s10973-005-0703-9