Abstract
Vibrational and 17O NMR spectroscopy in combination with quantum chemical calculations are used to investigate the hydrolysis of antimony(III) fluoride complexes. A hydrolytic decomposition of SbF3 and [SbF4]− is accompanied by oligomerization with the formation of edge-and corner-connected dimers ([Sb2O2F4]2−, [Sb2OF8]4−) and trimers ([Sb3O3F6]3−, [Sb3OF9]2−) with bridging oxygen atoms. The hydrolysis of [SbF4]− is also characterized by the presence in the solution of a discrete cation of [SbF5]2− which is least hydrolized. Only a partial isomorphic substitution of fluoride ion by hydroxide one is possible, which is reflected in the composition of K2Sb(OH)xF5−x (x = 0.3) crystals isolated from the fluoride aqueous solution.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
L. A. Zemnukhova, E. V. Kovaleva, V. A. Mamontova, and G. A. Fedorishcheva, RF Patent Decision on Claim No. 2004106811 [in Russian], 21.11.06.
I. G. Ryss, Chemistry of Fluorine and Its Inorganic Compounds [in Russian], Goskhimizdat, Moscow (1956).
Yu. A. Buslaev and V. V. Peshkov, Zh. Neorg. Khim., 18, No. 6, 1523–1526 (1973).
R. L. Davidovich and L. A. Zemnukhova, Koordinats. Khim., 1, No. 4, 477–481 (1975).
M. J. Frish, G. M. Trucks, H. B. Schlegel, et al., Gaussian-03, Revision B. 03, Gaussian, Inc., Pittsburgh PA (2003).
G. V. Yukhnevich, Infrared Spectroscopy of Water [in Russian], Nauka, Moscow (1973).
V. D. Sokolov (ed.), Hydrogen Bond [in Russian], Nauka, Moscow (1981).
E. V. Kovaleva, L. A. Zemnukhova, and V. V. Kon’shin, Koordinats. Khim., 28, No. 11, 809–811 (2002).
A. A. Udovenko, L. A. Zemnukhova, E. V. Kovaleva, and G. A. Fedorishcheva, ibid., 30, No.8, 1–8 (2004).
E. V. Kovaleva, L. A. Zemnukhova, N. Sh. Lebedeva, and G. A. Fedorishcheva, ibid., 31, No. 3, 168–171 (2005).
C. J. Adams and A. J. Downs, J. Chem. Soc. (A), 1534–1542 (1971).
A. A. Udovenko and L. M. Volkova, Koordinats. Khim., 7, No. 12, 1763–1813 (1981).
V. E. Ovchinnikov, A. A. Udovenko, L. P. Solov’eva, et al., ibid., 8, No. 5, 697–701 (1982).
E. G. Il’in, A. N. Zozulin, and Yu. A. Buslaev, Dokl. Akad. Nauk, 384, No. 3, 355–358 (2002).
N. M. Laptash, M. A. Fedotov, and I. G. Maslennikova, J. Struct. Chem., 45, No. 1, 74–82 (2004).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text Copyright © 2007 by N. M. Laptash, E. V. Kovaleva, A. A. Mashkovskii, A. Yu. Beloliptsev, and L. A. Zemnukhova
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 48, No. 5, pp. 907–913, September–October, 2007.
Rights and permissions
About this article
Cite this article
Laptash, N.M., Kovaleva, E.V., Mashkovskii, A.A. et al. Hydrolysis of antimony(III) fluoride complexes. J Struct Chem 48, 848–854 (2007). https://doi.org/10.1007/s10947-007-0126-5
Received:
Issue Date:
DOI: https://doi.org/10.1007/s10947-007-0126-5